Redox Reactions and Oxidation States Quiz

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Questions and Answers

In the reaction: Zn(s) + CuSO4(aq) → ZnSO4(aq) + Cu(s), which species is the reducing agent?

  • Cu(s)
  • Zn(s) (correct)
  • CuSO4(aq)
  • ZnSO4(aq)

According to the half-reaction for the reduction of hydrogen ions, 2 H+ + 2 e- → H2 , where do the electrons appear?

  • They are not shown in the equation
  • On the right side of the equation
  • On the left side of the equation (correct)
  • On both sides of the equation

Which of the following is a correct description of the change in oxidation state of magnesium in the reaction: Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)?

  • Magnesium is reduced from 0 to +2.
  • Magnesium is oxidized from +2 to 0.
  • Magnesium is reduced from +2 to 0.
  • Magnesium is oxidized from 0 to +2. (correct)

In the disproportionation reaction: 2CuI(aq) → CuI2(aq) + Cu(s), which species is being oxidized?

<p>Cu+(aq) (A)</p> Signup and view all the answers

What is the net ionic equation for the reaction between magnesium and hydrochloric acid?

<p>Mg(s) + 2H+(aq) → Mg2+(aq) + H2(g) (B)</p> Signup and view all the answers

The reaction 2H2(g) + O2(g) → 2H2O(l) is a redox reaction. Which reactant undergoes reduction?

<p>O2 (C)</p> Signup and view all the answers

Which of these is considered a redox reaction?

<p>All of the above (D)</p> Signup and view all the answers

In the reaction 2Mg(s) + O2(g) → 2MgO(s), what is the oxidation state of oxygen in MgO?

<p>-2 (A)</p> Signup and view all the answers

Referring to the provided example of the galvanic cell, why is the standard reduction potential of copper (Cu) assigned a positive value in the calculation of E°cell using Method 2?

<p>It is assigned a positive value because it is the oxidation half-reaction, the opposite of the reduction potential shown on the standard reduction potential table. (A)</p> Signup and view all the answers

Which of the following statements correctly describes the role of the copper rod in the observed reaction setup?

<p>The copper rod acts as an anode, losing electrons and undergoing oxidation. (B)</p> Signup and view all the answers

In the observed reaction setup, where does the reduction half-reaction take place?

<p>At the silver electrode. (D)</p> Signup and view all the answers

Considering the provided example, what does the observed value of 0.460 V represent?

<p>The potential difference between the copper and silver electrodes. (E)</p> Signup and view all the answers

Referring to the reactions of the galvanic cell, why is the reaction considered 'spontaneous'?

<p>The reaction proceeds without any external energy input. (C), The reaction involves the transfer of electrons from a strong reducing agent to a strong oxidizing agent. (D)</p> Signup and view all the answers

The provided information states that 'copper metal is a strong reducing agent.' What is the relationship between the strength of reducing agents and their standard reduction potentials?

<p>Stronger reducing agents have lower standard reduction potentials, making them more likely to lose electrons. (E)</p> Signup and view all the answers

In Method 1, the equation E°cell = E°r cathode – E°r anode, why are the standard reduction potentials for the cathode and anode subtracted?

<p>The cathode potential is subtracted from the anode potential because the cathode is the site where electrons are being consumed. (C)</p> Signup and view all the answers

How does the chemical reaction of the provided example lead to the observable loss of mass from the copper rod?

<p>The copper atoms are converted into copper(II) ions, which dissolve into solution. (B)</p> Signup and view all the answers

In the hybridization of ethene, how many hybrid orbitals are involved in forming sigma bonds with hydrogen atoms?

<p>2 (D)</p> Signup and view all the answers

In the hybridization of ethyne, how many pi bonds are formed between the two carbon atoms?

<p>2 (D)</p> Signup and view all the answers

What is the primary reason for the formation of hybrid orbitals in molecules like ethene and ethyne?

<p>To achieve a more stable electronic configuration. (C)</p> Signup and view all the answers

Which of the following statements is TRUE regarding the relationship between bond angles and hybridization in molecules?

<p>Hybrid orbitals with more s character lead to larger bond angles. (C)</p> Signup and view all the answers

Which of the following statements regarding the hybridization of oxygen in a water molecule is TRUE?

<p>Oxygen's hybridization involves electron promotion to form four equivalent sp3 hybrid orbitals. (D)</p> Signup and view all the answers

Consider the hybridization of nitrogen in ammonia (NH3). Which of the following statements is CORRECT regarding the process?

<p>Hybridization in nitrogen forms four equivalent sp3 hybrid orbitals, with one of these orbitals occupied by a lone pair. (D)</p> Signup and view all the answers

Why is hybridization a necessary process for forming methane (CH4)?

<p>Hybridization allows for the formation of four equivalent C-H bonds, resulting in a tetrahedral geometry. (D)</p> Signup and view all the answers

Compared to the bond angle in methane (CH4), the bond angle in water (H2O) is smaller. Which of the following is the most likely explanation for this difference?

<p>The presence of two lone pairs on the oxygen atom in water creates greater electron-electron repulsion, pushing the hydrogen atoms closer together. (A)</p> Signup and view all the answers

In the context of hybridization, why is there no electron promotion in ammonia (NH3)?

<p>Nitrogen, in its ground state, already possesses the required three unpaired electrons for forming three bonds with hydrogen atoms. (D)</p> Signup and view all the answers

In the hybridization process of nitrogen in ammonia (NH3), what role do the resulting hybrid orbitals play?

<p>The hybrid orbitals form the base of the ammonia molecule, while the unhybridized p orbitals are responsible for the lone pair. (B)</p> Signup and view all the answers

Based on the hybridization of the central atom in each molecule, what can be deduced about the bond angles in methane (CH4), ammonia (NH3), and water (H2O)?

<p>The bond angles decrease progressively from methane to ammonia to water due to the increasing number of lone pairs on the central atom. (A)</p> Signup and view all the answers

Consider the formation of four equivalent sp3 hybrid orbitals in the hybridization process. Which of the following statements BEST describes the nature of these orbitals?

<p>The sp3 orbitals are formed by combining one s orbital and three p orbitals, resulting in four identical orbitals with a specific direction. (C)</p> Signup and view all the answers

In a redox reaction, which of these would be a strong indicator that a reaction will not occur?

<p>The reducing agent is weaker than the oxidizing agent. (B), The oxidizing agent is weaker than the reducing agent. (D)</p> Signup and view all the answers

What is the most likely reason for balancing the number of electrons lost and gained in the half-reactions during the balancing process of a redox reaction?

<p>To ensure the conservation of charge. (A)</p> Signup and view all the answers

If a reaction involves a strong reducing agent and a weak oxidizing agent, what would be a probable outcome?

<p>No reaction at all. (D)</p> Signup and view all the answers

In a redox reaction, which of the following must be balanced when balancing the half-reactions?

<p>The number of electrons lost and gained. (A)</p> Signup and view all the answers

Why are unbalanced half-reactions written first when balancing a redox reaction?

<p>To see the reactant and product species before balancing. (B)</p> Signup and view all the answers

When a reaction is balanced using the half-reaction method, what is the final step typically involved?

<p>Combining the balanced half-reactions, ensuring no electrons appear. (C)</p> Signup and view all the answers

What is the key factor in determining which half-reactions to combine when balancing a redox reaction?

<p>The number of electrons involved in each half-reaction. (C)</p> Signup and view all the answers

Why are oxygen and hydrogen atoms typically balanced last in the half-reaction method?

<p>To accommodate the use of H+ and OH- in acidic and basic solutions. (C)</p> Signup and view all the answers

Which molecule has the strongest dipole-dipole interactions?

<p>HCâ„“ (D)</p> Signup and view all the answers

Which molecule is nonpolar due to symmetrical bond dipoles?

<p>SiF4 (B)</p> Signup and view all the answers

Which of the following is a correct statement about the intermolecular forces (IMFs) present in H2O?

<p>H2O exhibits hydrogen bonding, dipole-dipole, and London dispersion forces. (D)</p> Signup and view all the answers

What is the hybridization of the central atom in AsCâ„“3?

<p>sp3 (B)</p> Signup and view all the answers

Why does the shape of SiF4 affect its polarity?

<p>The tetrahedral shape of SiF4 results in a symmetrical distribution of electron density, leading to a cancellation of individual bond dipoles. (C)</p> Signup and view all the answers

Predict the intermolecular forces present in a molecule with a nonpolar covalent bond and a tetrahedral shape.

<p>London dispersion forces (A)</p> Signup and view all the answers

Which molecule has a larger difference in electronegativity?

<p>HCâ„“ (C)</p> Signup and view all the answers

Which of the following statements is TRUE regarding the hybridization of carbon in methane (CH4)?

<p>The carbon atom in CH4 uses 4 sp3 orbitals to form bonds. (B)</p> Signup and view all the answers

Which molecule has the lowest dipole moment?

<p>CH4 (B)</p> Signup and view all the answers

Based on the information provided, which molecule would be expected to have the highest boiling point?

<p>H2O (B)</p> Signup and view all the answers

Which molecule has the most polar covalent bonds?

<p>SiF4 (A)</p> Signup and view all the answers

The molecular shape of AsCâ„“3 is best described as:

<p>Trigonal pyramidal (B)</p> Signup and view all the answers

Why is the dipole moment of a molecule with two lone pairs on the central atom NOT always zero?

<p>Lone pairs occupy space and have an electron density that creates a negative charge, which is not symmetrical with the bonding pairs leading to an asymmetric distribution of electron density. (C)</p> Signup and view all the answers

Which scenario is BEST supported by the text, given only the information provided?

<p>The strength of London dispersion forces is determined by the size of the molecule. Molecules with more electrons, which translates to larger electron clouds, experience stronger London dispersion forces. (D)</p> Signup and view all the answers

Flashcards

Redox Reaction

A chemical reaction where electrons are transferred from one reactant to another.

Electric Current

The flow of electrons through a circuit.

Electrochemistry

The study of how chemical energy is converted to electrical energy.

Anode

The part of an electrochemical cell where oxidation occurs.

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Cathode

The part of an electrochemical cell where reduction occurs.

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Galvanic Cell

A device that generates electrical energy from a chemical reaction.

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Cell Potential (Ecell)

The potential difference between the anode and cathode in an electrochemical cell.

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Reduction Potential (Ered)

A measure of the tendency of a substance to gain electrons.

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Oxidation

A reaction in which a species loses electrons and increases its oxidation state.

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Reduction

A reaction in which a species gains electrons and decreases its oxidation state.

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Oxidizing Agent (OA)

A species that gains electrons in a redox reaction, causing another species to be oxidized.

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Reducing Agent (RA)

A species that loses electrons in a redox reaction, causing another species to be reduced.

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Spontaneity Rule

A redox reaction occurs only when a strong oxidizing agent reacts with a strong reducing agent.

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Single Displacement Reaction

A reaction in which a metal displaces another metal from its salt solution.

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Half-reaction Method

A method for balancing redox reactions by balancing each half-reaction separately and ensuring that the number of electrons lost in the oxidation half-reaction is equal to the number of electrons gained in the reduction half-reaction.

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Total Ionic Equation

A chemical equation showing the ionic species involved in a reaction.

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Net Ionic Equation

A chemical equation showing only the species that directly participate in the reaction.

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Disproportionation Reaction

A reaction where the same element is both oxidized and reduced.

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Reaction between a metal and a non-metal

A reaction between a metal and a non-metal, forming an ionic substance.

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Hybridization

The process of forming new hybrid orbitals by mixing atomic orbitals. This allows for more effective bonding, resulting in stable molecules.

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Sigma Bond

A type of covalent bond formed by the overlap of two atomic orbitals along the axis connecting the two atoms.

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Pi Bond

A type of covalent bond formed by the sideways overlap of two atomic orbitals above and below the plane of the sigma bond.

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Molecular Shape

The three-dimensional arrangement of atoms in a molecule, determined by the spatial orientation of bonds around a central atom in a molecule.

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Bond Angle

The angle between two adjacent bonds in a molecule.

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Electron Promotion in Hybridization

Hybridization occurs when an atom's electron promotion is necessary to obtain the required number of unpaired electrons for bonding. This happens when there are fewer than four unpaired electrons in the valence shell.

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Type of Hybridization

The type of hybridization depends on the number of unpaired electrons in the central atom. For example, carbon's four hybrid orbitals are called sp3, indicating one s and three p orbitals combined.

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Hybridized Orbitals

The orbitals in hybridized atoms change their shape to create hybrid orbitals suitable for bonding. For example, sp3 orbitals are tetrahedral in shape.

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Lone Pair Effect on Bond Angles

The presence of lone pairs on the central atom influences the bond angles in the molecule due to repulsion. For example, the bond angle in water is 104.5° due to two lone pairs on the oxygen atom.

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Bonding and Molecular Diversity

The ability of atoms to form bonds, especially with the same atom, allows for the formation of chains, rings, and diverse molecules.

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Role of Hybridization in Bonding

Hybridization helps atoms form stable bonds with other atoms and allows molecules to adopt specific shapes.

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Hybridization in Methane

The central atom in methane (CH4) undergoes hybridization because it requires four valence electrons to form four bonds. The hybridization of the carbon atom in methane is sp3 and results in a tetrahedral shape.

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VSEPR Theory

A model that predicts the geometric shape of molecules based on the number of electron pairs around the central atom.

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Electronegativity Difference (ΔEN)

A measure of the difference in electronegativity between two bonded atoms. It determines the polarity of a bond, ranging from 0 (nonpolar) to 4 (ionic).

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Electronegativity

The tendency of an atom in a molecule to attract shared electrons towards itself, influenced by factors like nuclear charge and shielding.

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Polar Molecule

A molecule with a positive end and a negative end due to unequal sharing of electrons, leading to an overall dipole moment.

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Nonpolar Molecule

A molecule where the electron distribution is even, resulting in no overall dipole moment.

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London Dispersion Forces (LDF)

Weak forces of attraction between molecules due to temporary fluctuations in electron distribution, present in all molecules.

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Dipole-Dipole Forces

Forces of attraction between polar molecules due to the attraction of oppositely charged ends of the dipoles, stronger than LDF.

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Hydrogen Bonding

A special type of dipole-dipole interaction between a hydrogen atom bonded to a highly electronegative atom (O, N, or F) and an electron pair on an adjacent molecule, the strongest intermolecular force.

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Intermolecular Forces (IMFs)

Forces of attraction between molecules, responsible for physical properties like boiling point, melting point, and viscosity. They are weaker than intramolecular forces that hold atoms together within a molecule.

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Bond Polarity

Describes how strong a bond is between two atoms, based on how much of its valence electrons it shares with the other atom to reach a stable state.

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sp³ Hybridization

The type of hybridization where an atom's atomic orbitals combine to form four equivalent sp³ hybrid orbitals, resulting in a tetrahedral shape.

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sp Hybridization

The type of hybridization where an atom's atomic orbitals combine to form two equivalent sp hybrid orbitals, resulting in a linear shape.

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Molecular Geometry

The process of determining the molecular shape by considering the number of electron pairs around the central atom and using the VSEPR theory to predict the repulsion of electrons.

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