Redox Reactions and Electrode Potential

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Questions and Answers

What role does a reducing agent play in a chemical reaction?

  • It accepts electrons from another substance.
  • It maintains the oxidation state of substances.
  • It prevents oxidation from occurring.
  • It gives electrons to another substance. (correct)

Which of the following describes an oxidizing agent?

  • It accepts electrons and gets reduced itself. (correct)
  • It accelerates the rate of a chemical reaction.
  • It can only exist in ionic form.
  • It donates electrons to reduce another substance.

Which statement correctly identifies the function of a reductant in a reaction?

  • It supplies electrons to another reactant. (correct)
  • It increases its own oxidation state.
  • It is always a metal.
  • It does not participate in the reaction.

In a redox reaction, the oxidizing agent is responsible for which of the following?

<p>Gaining electrons and facilitating oxidation. (A)</p> Signup and view all the answers

What is a primary characteristic of a reducing agent?

<p>It reduces the oxidation state of itself. (A)</p> Signup and view all the answers

What is the primary function of the enzymes mentioned in the context of repair mechanisms?

<p>They catalyze the repair mechanisms. (A)</p> Signup and view all the answers

What does the solution pressure refer to when a metal rod is placed in a salt solution?

<p>The tendency of the metal to dissolve in its salt solution. (A)</p> Signup and view all the answers

What is the effect of dipping a metal rod into a solution of its salts on the electrode potential?

<p>It can alter the tendency for the metal to dissolve. (D)</p> Signup and view all the answers

Which of the following is an implication of the electrode potential concerning metals in solution?

<p>It can determine whether a metal remains solid or dissolves. (B)</p> Signup and view all the answers

Which statement regarding the relationship between repair mechanisms and electrode potential is accurate?

<p>A higher electrode potential enhances repair efficiency. (D)</p> Signup and view all the answers

What does ionic pressure refer to in the context of metal cations?

<p>The tendency of metal cations to deposit on a metal immersed in a solution. (C)</p> Signup and view all the answers

In a Cu/Cu2+ system, which pressure is greater?

<p>Ionic pressure is greater than solution pressure. (B)</p> Signup and view all the answers

What primarily drives the ionic pressure in metal cations?

<p>The concentration of metal cations in the solution. (D)</p> Signup and view all the answers

Which of the following scenarios best illustrates the concept of ionic pressure?

<p>Metal ions forming a solid layer on the surface of a metal immersed in its ion solution. (C)</p> Signup and view all the answers

How might the concept of ionic pressure be relevant in electrochemistry?

<p>It relates to the deposition and corrosion processes of metals. (B)</p> Signup and view all the answers

What does the symbol E° represent in electrochemistry?

<p>Standard electrode potential (A)</p> Signup and view all the answers

Which of the following variables influences the electrode potential according to the provided content?

<p>Gas constant R (D)</p> Signup and view all the answers

What does the variable T denote in the context of electrode potential?

<p>Absolute temperature (C)</p> Signup and view all the answers

In electrochemistry, what aspect does the electrode potential indicate?

<p>The tendency of a species to gain or lose electrons (D)</p> Signup and view all the answers

Which term is used to describe the constant potential for a given system in electrochemical reactions?

<p>Standard electrode potential E° (C)</p> Signup and view all the answers

Which system has the most negative standard oxidation potential?

<p>Li / Li+ (D)</p> Signup and view all the answers

Which of the following systems has a positive standard oxidation potential?

<p>Hg / Hg2+ (C)</p> Signup and view all the answers

Which standard oxidation potential is closest to zero?

<p>H2 (pt) / H+ (C)</p> Signup and view all the answers

Which of these systems has the highest standard oxidation potential?

<p>Ag / Ag+ (B)</p> Signup and view all the answers

What is the standard oxidation potential of Zn / Zn2+?

<p>–0.76 volts (C)</p> Signup and view all the answers

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Study Notes

Redox Reactions

  • A reducing agent or reductant is a substance that gives electrons.
  • An oxidizing agent or oxidant is a substance that accepts electrons.

Electrode Potential

  • The potential difference that arises when a metal rod is dipped into a solution of its salts is called electrode potential.
  • The tendency of the metal to dissolve in a solution of its salt is called solution pressure.
  • The tendency of the metal cations to deposit on its metal dipped into its solution is called ionic pressure.

Standard Electrode Potential (E°)

  • The standard electrode potential is the electrode potential measured under standard conditions: 298 K (25°C), 1 atmosphere pressure, and 1 M concentration of ions in solution.
  • E° is a constant that depends on the specific system.

Standard Oxidation Potential (E°)

  • The standard oxidation potential is the tendency of a substance to lose electrons and get oxidized under standard conditions.
  • The more negative the value of E°, the stronger the reducing agent.
  • The more positive the value of E°, the stronger the oxidizing agent.

Electrolysis

  • The process of using an electric current to drive a non-spontaneous chemical reaction is called electrolysis.
  • The electrical energy supplied to the system is used to overcome the energy barrier of the reaction and drive the process forward.
  • The direction of electron flow is determined by the relative values of the standard electrode potentials (E°) of the species involved.

Factors Affecting Electrode Potential

  • The electrode potential is influenced by several factors, including:
    • Temperature
    • Concentration of ions in solution
    • Presence of other electrolytes
    • Nature of the electrode material
    • Surface area of the electrode

Applications of Electrode Potential

  • Electrode potential measurements are used in various fields, including:
    • Corrosion prevention
    • Battery design
    • Analytical chemistry
    • Electrochemical sensors
    • Electroplating and electrorefining

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