Spontaneity of Redox Reactions

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Questions and Answers

What does a positive standard electrode potential ($E^ullet$) indicate about a reaction?

  • The reverse reaction is spontaneous.
  • The reaction is non-spontaneous.
  • The reaction will not occur.
  • The reaction is spontaneous in the written direction. (correct)

What occurs when the standard electrode potential ($E^ullet$) is negative?

  • The reaction proceeds in the written direction.
  • The reaction is spontaneous.
  • The reaction is non-spontaneous. (correct)
  • The reverse reaction is non-spontaneous. (correct)

In the reaction $Ni(s) + Mn^{2+}(aq) \rightarrow Ni^{2+}(aq) + Mn(s)$, what is needed to determine if the reaction is spontaneous?

Standard electrode potential ($E^ullet$) values for the half-reactions.

A voltaic cell will proceed in the direction that results in a positive cell potential ($E_{cell}^ullet$), which indicates __________ reactions are favored.

<p>spontaneous</p> Signup and view all the answers

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Study Notes

Determining Spontaneity of a Reaction

  • Standard electrode potential ($E^\circ$) values can be used to predict whether a redox reaction will occur spontaneously.
  • A voltaic cell will proceed in the direction that results in a positive cell potential ($E_{cell}^\circ$).
  • If $E^\circ$ is positive, the reaction is spontaneous in the written direction.
  • If $E^\circ$ is negative, the reaction is non-spontaneous in the written direction, and the reverse reaction is spontaneous.

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