Reactions of Alcohols and Carbonyl Compounds Quiz
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Questions and Answers

What is the purpose of the 'alcohol breath test' used by the Federal Road Safety Corps?

  • To detect the presence of alcohol in a person's breath (correct)
  • To determine if a person has consumed esters
  • To measure the amount of alcohol in the bloodstream
  • To test for the level of carbon dioxide in the breath

What is the chemistry behind the 'alcohol breath test'?

  • Oxidation of alcohols (correct)
  • Enzymatic hydrolysis
  • Reduction of aldehydes
  • Esterification reaction

In esterification of alcohols, what are the typical reactants and conditions involved?

  • Alcohol and carboxylic acid under basic conditions
  • Alcohol and amine under acidic conditions
  • Alcohol and carboxylic acid under acidic conditions (correct)
  • Alcohol and amine under basic conditions

What is the name for the reverse reaction of esterification of alcohols?

<p>Hydrolysis (D)</p> Signup and view all the answers

How can one manipulate the reverse reaction of esterification to undertake soap preparation (saponification)?

<p>Use excess water with high pH (A)</p> Signup and view all the answers

What is the term used for the reaction where an alcohol reacts with a carboxylic acid in the presence of concentrated sulphuric acid to form esters?

<p>Esterification (D)</p> Signup and view all the answers

When esterification occurs, what is the backward reaction called?

<p>Acid-hydrolysis of ester (A)</p> Signup and view all the answers

What can be used in place of a carboxylic acid to speed up the esterification reaction?

<p>Acyl chloride or acid anhydride (C)</p> Signup and view all the answers

Which common oxidizing agents are used to oxidize alcohols into carbonyl compounds or carboxylic acids?

<p>Acidified potassium permanganate (A)</p> Signup and view all the answers

What color change is observed when primary alcohols are oxidized with acidified potassium dichromate?

<p>From orange to green (B)</p> Signup and view all the answers

In the drunken driver test, what color change occurs when ethanol vapour from the breath reacts with K2Cr2O7 coated paper?

<p>Orange to green (B)</p> Signup and view all the answers

What are the conditions for the dehydration of an alcohol to an alkene?

<p>Strong acid and heat (A)</p> Signup and view all the answers

How do you obtain an aldehyde as the only product from an alcohol?

<p>Oxidation with mild oxidizing agents (C)</p> Signup and view all the answers

What is the composition of Lucas reagent used to distinguish different classes of monohydric alcohols?

<p>Concentrated hydrochloric acid and zinc chloride (B)</p> Signup and view all the answers

How can you distinguish ethanol from 2-propanol and 1-propanol from 2-methyl-2-propanol using Lucas Reagent?

<p>Color change (B)</p> Signup and view all the answers

What observation confirms a primary alcohol when using Lucas Reagent?

<p>Stable color change after heating (D)</p> Signup and view all the answers

How do you recognize an alcohol that can undergo the iodoform test?

<p>Tertiary alcohol (B)</p> Signup and view all the answers

What is the product formed when an aliphatic primary amine reacts with HNO2?

<p>Alcohol, nitrogen gas, and water (A)</p> Signup and view all the answers

In the Lucas test for distinguishing monohydric alcohols, which type of alcohol forms a cloudy mixture immediately upon refluxing?

<p>3° alcohols (A)</p> Signup and view all the answers

What is the order of reactivity based on carbocation stability in alcohol halogenation reactions?

<p>3° alcohol &gt; 2° alcohol &gt; 1° alcohol (C)</p> Signup and view all the answers

Which reaction leads to the formation of carbon (IV) oxide and water when alcohols burn in air?

<p>Combustion (A)</p> Signup and view all the answers

What is the product formed when Grignard’s Reagent reacts with an ester?

<p>Alcohol (C)</p> Signup and view all the answers

Which reaction follows the order: 3°alcohol > 2°alcohol > 1°alcohol in terms of rate of reaction?

<p>Halogenation to alkyl halides (A)</p> Signup and view all the answers

What reagents can be used to convert alcohols to alkyl halides?

<p>Phosphorus halides and sulphur dichloride oxide (D)</p> Signup and view all the answers

How is the dehydration of alcohols to alkenes usually carried out?

<p>By passing alcohol vapor over an aluminum oxide catalyst heated to 350°C (B)</p> Signup and view all the answers

What is the major product formed when an excess alcohol is heated with concentrated sulphuric acid at about 140°C?

<p>Ether (D)</p> Signup and view all the answers

Which rule guides the regioselectivity of dehydration of alcohols to alkenes?

<p>Zaitsev rule (A)</p> Signup and view all the answers

What forms when alcohols react with reactive metals like sodium and potassium?

<p>Metal alkoxides and hydrogen gas (B)</p> Signup and view all the answers

In the context of alcohol dehydration, what are Phosphorus halides used for?

<p>Converting alcohols to alkyl halides (A)</p> Signup and view all the answers

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