Reaction Rates and Interfacial Chemical Reactions

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Questions and Answers

Which type of reaction model is considered in the discussions on reaction models in the text?

  • Reaction of particles in suspension
  • Reaction of multiple particles only
  • Reaction of both single and multiple particles
  • Reaction of single particles only (correct)

In the Shrinking Particle Model, how does the particle size change as the reaction proceeds?

  • The particle size fluctuates
  • The particle size decreases (correct)
  • The particle size remains constant
  • The particle size increases

What is the reaction equation for the Shrinking Particle Model?

  • A(fluid) + bB(solid) = cD(removable solid)
  • A(fluid) + bB(solid) = cR (fluid)
  • A(fluid) + bB(solid) = cR (solid) + dD(removable solid)
  • A(fluid) + bB(solid) = cR (fluid) + dD(removable solid) (correct)

Which of the following is the correct way to write the equation for a line in slope-intercept form?

<p>y = mx + b (D)</p> Signup and view all the answers

Which of the following is the correct formula for the area of a rectangle?

<p>A = l * w (D)</p> Signup and view all the answers

Which of the following formulas represents the Pythagorean Theorem?

<p>a^2 + b^2 = c^2 (A)</p> Signup and view all the answers

Which of the following is the correct formula for the circumference of a circle?

<p>C = 2Ï€r (D)</p> Signup and view all the answers

Which of the following is the correct formula for the volume of a sphere?

<p>V = (4/3)Ï€r^3 (A)</p> Signup and view all the answers

Which equation represents the macro mass balance equation for reaction engineering?

<p>$V \frac{dVC_A},{dt} = F_iC_{Ai} - F_oC_{Ao} + \int r_A dV$ (D)</p> Signup and view all the answers

Which reactor type has a spatially uniform reaction rate?

<p>Plug Flow Reactor (PFR) (A)</p> Signup and view all the answers

Which reactor type has the lowest effluent reactant concentration for n>0?

<p>Plug Flow Reactor (PFR) (D)</p> Signup and view all the answers

Which reactor type requires the largest volume for a given duty for n>0?

<p>Continuously Stirred Tank Reactor (CSTR) (A)</p> Signup and view all the answers

Which type of reactor is characterized by a well-mixed stirred tank operated continuously and is normally run at steady-state?

<p>Continuously Stirred Tank Reactor (B)</p> Signup and view all the answers

What is the equation for the mass balance for solid reactant B within each solid grain?

<p>$-\rho_B \frac{dC_B}{dt} = bks C_B^{25}$ (A)</p> Signup and view all the answers

What is the equation for the relationship between time and conversion in a reactor, given the dimensionless variable $t^*$ and the shrinking core reaction modulus $\sigma$?

<p>$t^* \approx gFg(x) + \sigma^2 Fp(x)$ (A)</p> Signup and view all the answers

What is the residence time in a plug flow reactor (PFR)?

<p>The time required to process one reactor volume of feed based on entrance conditions (B)</p> Signup and view all the answers

Which of the following is true about the reaction rate expression for a first-order reaction assuming interfacial chemical reaction and fast external mass transfer?

<p>The reaction rate is given by $-\frac{d[B]}{dt} = -bks[C_b]$ (B)</p> Signup and view all the answers

In the case of a single porous particle, when does the overall reaction become strongly influenced by pore diffusion?

<p>When no solid product is formed and diffusion offers no resistance (C)</p> Signup and view all the answers

What is the mass balance equation for a single porous particle when no solid product is formed and diffusion offers no resistance?

<p>$\frac{d^2[C_b]}{dx^2} - k_sSV[C_b]^n = 0$ (A)</p> Signup and view all the answers

What is the solution to the mass balance equation for a single porous particle when no solid product is formed and diffusion offers no resistance?

<p>$\frac{1}{2}\left(\frac{d[C_b]}{dx}\right)^2 = \frac{k_sSV}{n+1}[C_s]^{n+1}$ (A)</p> Signup and view all the answers

Which of the following steps is NOT part of the overall process in the Shrinking Core Model?

<p>Reaction at the surface of the particle (A)</p> Signup and view all the answers

What is the rate of external mass transport across the boundary layer in the Shrinking Core Model?

<p>$-r_B = 4\pi r_o^2 k_m(C_b - C_s)$ (C)</p> Signup and view all the answers

What is the rate of disappearance of B in the Shrinking Core Model?

<p>$-\frac{dn_B},{dt} = -b\frac{dn_A},{dt} = -\rho_B \frac{dV},{dt} = -4\pi \rho_B r_c^2 \frac{dr_c},{dt}$ (B)</p> Signup and view all the answers

What is the expression for the change in the unreacted core with time in the Shrinking Core Model?

<p>$r^2 \frac{dt},{dX} = 6bDB_oC[1 - 3(1 - X)^2 + 2(1 - X)^3]$ (B)</p> Signup and view all the answers

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