Reaction Mechanisms and Processes

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Questions and Answers

Which of the following best describes a reaction mechanism?

  • The overall balanced equation representing the chemical change.
  • The energy required for a reaction to occur.
  • The step-by-step sequence of reactions by which the overall chemical change occurs. (correct)
  • The rate at which reactants are converted into products.

In a proposed reaction mechanism, what term describes a species that appears in one step but is consumed in a later step, and therefore does not appear in the overall balanced equation?

  • Intermediate (correct)
  • Reactant
  • Catalyst
  • Product

In the context of chemical reactions, what does the collision theory primarily explain?

  • The equilibrium constants of reversible reactions.
  • The spontaneity of thermodynamically favored reactions.
  • The conservation of mass in chemical reactions.
  • How particle collisions lead to chemical reactions (correct)

According to collision theory, what are the two primary factors that determine whether a collision between reactant molecules will lead to a successful reaction?

<p>Molecular orientation and kinetic energy (D)</p> Signup and view all the answers

What is the role of activation energy in a chemical reaction?

<p>The minimum energy required for reactants to transform into an activated complex. (C)</p> Signup and view all the answers

Which statement is true regarding the relationship between bond breaking and bond forming in a chemical reaction?

<p>Bond breaking is an endothermic process, while bond forming is exothermic. (B)</p> Signup and view all the answers

What is the significance of an 'activated complex' in a chemical reaction?

<p>It is a very short-lived transitional molecular structure formed during an effective collision. (B)</p> Signup and view all the answers

How does increasing the temperature generally affect the rate of a chemical reaction, according to the principles discussed?

<p>It increases the reaction rate by providing more molecules with the necessary activation energy. (A)</p> Signup and view all the answers

Which of the following is a key factor in determining the speed of a chemical reaction?

<p>The energy pathway the reaction follows. (B)</p> Signup and view all the answers

Consider the elementary steps of a reaction mechanism. What is the classification of a reaction where all reactants and products exist in the same phase?

<p>Homogeneous reaction (B)</p> Signup and view all the answers

A chemist proposes a multi-step reaction mechanism. What type of experimental evidence would be most useful in determining the probable sequence of these steps?

<p>Identifying the presence of specific intermediates (C)</p> Signup and view all the answers

For the elementary reaction $A + B \rightarrow C$, which of the following molecular orientations would likely be most effective in leading to product formation, assuming A and B react through specific sites?

<p>A and B approach each other with the reactive sites directly aligned. (D)</p> Signup and view all the answers

The reaction $2H_2(g) + O_2(g) \rightarrow 2H_2O(l)$ is exothermic, yet it does not occur spontaneously at room temperature. Why?

<p>The reaction has a high activation energy. (A)</p> Signup and view all the answers

In an energy diagram for a chemical reaction, what does the 'activation energy' correspond to?

<p>The energy gap between the reactants and the activated complex. (C)</p> Signup and view all the answers

Consider a reaction coordinate diagram. What does a higher activation energy for a reaction indicate about the reaction rate?

<p>The reaction rate will be slower. (A)</p> Signup and view all the answers

What happens to the kinetic energies of molecules as temperature increases, according to kinetic-molecular theory?

<p>Kinetic energies increase (B)</p> Signup and view all the answers

Consider a reaction with an activation energy ($E_a$) of 50 kJ/mol. If the energy of the reactants is 20 kJ/mol, and the energy of the products is -10 kJ/mol, what is the energy of the activated complex?

<p>70 kJ/mol (A)</p> Signup and view all the answers

For a reversible reaction, what is the relationship between the activation energy for the forward reaction ($E_{a,forward}$) and the activation energy for the reverse reaction ($E_{a,reverse}$) in an exothermic reaction?

<p>$E_{a,forward} &lt; E_{a,reverse}$ (B)</p> Signup and view all the answers

Given the reaction $I_2(g) \rightleftharpoons 2I(g)$, which represents the first step of a possible reaction mechanism for the formation of HI. If the forward reaction is endothermic, how would you describe the change in enthalpy?

<p>Positive (C)</p> Signup and view all the answers

In a reaction coordinate diagram, the difference in energy between the reactants and the products is known as what?

<p>Enthalpy change (A)</p> Signup and view all the answers

How does the addition of a catalyst affect the activation energy of a reaction?

<p>It decreases the activation energy. (B)</p> Signup and view all the answers

What is the primary reason why only a fraction of collisions between reactant molecules lead to a chemical reaction, even when they have sufficient energy?

<p>The orientation of the molecules during collision is not favorable. (D)</p> Signup and view all the answers

Which of the following statements accurately reflects bond energies in relation to the stability of molecules?

<p>Higher bond energies indicate more stable molecules. (D)</p> Signup and view all the answers

If a reaction mechanism involves multiple steps, what is the rate-determining step?

<p>The slowest step in the mechanism. (D)</p> Signup and view all the answers

How can the enthalpy of a reaction ($\Delta H$) be determined from the activation energies of the forward ($E_{a,forward}$) and reverse ($E_{a,reverse}$) reactions?

<p>$\Delta H = E_{a,forward} - E_{a,reverse}$ (C)</p> Signup and view all the answers

Flashcards

What is a reaction mechanism?

The step-by-step sequence of reactions by which the overall chemical change occurs.

What are reaction intermediates?

Species that appear transiently in some steps of a reaction mechanism but are not in the net equation.

What is a homogeneous reaction?

A reaction where all reactants and products exist in a single phase.

What is the collision theory?

A set of assumptions stating that reactions occur through collisions, and explains why reactions occur or don't occur.

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How do molecules react?

Reactant molecules must collide with a favorable orientation and with enough energy to merge the valence electrons and disrupt the bonds of the molecules to form to the products.

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When do collisions fail? (Collision theory)

The collision is not energetic enough to supply the required energy or the colliding molecules are not oriented in a way that enables them to react with each other.

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What is activation energy (Ea)?

The minimum energy required to transform the reactants into an activated complex.

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What is an activated complex?

A transitional structure that results from an effective collision. Old bonds are breaking and new bonds are forming.

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How does temperature affect reaction rate?

Raising the temperature of a reaction provides more molecules that have the necessary activation energy and causes an increase in the reaction rate.

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What is ΔEforward?

The energy of products minus the energy of reactants.

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What is ΔEreverse?

The energy of reactants minus the energy of products.

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What is Ea?

Energy of activated complex minus the energy of reactants

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What is E'a?

Energy of activated complex minus the energy of products.

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Study Notes

Reaction Process Overview

  • Chemical reactions occur at varying speeds
  • Reaction speed hinges on the energy pathway and molecular-level changes during substance interaction
  • Objectives include explaining reaction mechanisms, using collision theory, defining the activated complex and relating activation energy to enthalpy

Reaction Mechanisms

  • High kinetic energy enables ions/molecules to overcome repulsive forces and react
  • Chemical equations depict reactions but not their mechanisms
  • Reaction mechanism refers to the step-by-step sequence of reactions causing a chemical change
  • A reaction appearing simple may involve multiple steps
  • Experiments determine the probable sequence in a reaction mechanism
  • Intermediates are species appearing in some steps but not in the net equation
  • Homogeneous reactions involve reactants/products existing in a single phase

Reaction mechanisms for HI formation

  • Possible reaction mechanisms for the formation of HI are:
    • I2 -> 2I
    • 2I + H2 -> 2HI or
    • I2 -> 2I
    • I + H2 -> H2I
    • H2I + I -> 2HI
  • Reaction intermediates like I and H2I do not appear in the net equation

Collision Theory

  • Reactions occur when particles collide
  • Collision theory encompasses assumptions about collisions and reactions
  • Effective collisions require favorable orientation and sufficient energy to merge valence electrons and disrupt bonds

Collision Theory Factors

  • Chemical reactions form new bonds between specific atoms in colliding molecules
  • Molecules do not react unless correct atoms are close and properly oriented
  • Collision theory identifies two reasons collisions between reactant molecules might not yield a new chemical species
    • Insufficient energy during collision
    • Improper orientation of colliding molecules

Activation Energy

  • Forming water from oxygen and hydrogen is exothermic: 2H2(g) + O2(g) -> 2H2O(l)
  • Reactions do not always occur spontaneously even at room temperature
  • Bond breaking is endothermic, while bond formation is exothermic
  • Initial energy overcomes repulsion between reactant molecules
  • Activation energy (Ea) is the minimum energy needed to transform reactants into an activated complex

Activated Complex

  • In the brief period of bond breakage and formation, the collision complex is in a transition state with partial bonding
  • An activated complex is a transitional structure from effective collision, where old bonds break and new ones form
  • The activated complex has a very short life

Activated Complex and Reaction Rate

  • The kinetic-molecular theory postulates that higher temperatures increase molecular speeds and kinetic energies
  • Collisions must have enough energy to form an activated complex for a reaction to occur
  • Raising reaction temperature increases molecules with necessary activation energy, accelerating the reaction rate

Sample Problem A Solution

  • ΔEforward = energy of products – energy of reactants
    • ΔEforward = 50 kJ/mol – 0 kJ/mol = +50 kJ/mol
  • ΔEreverse = energy of reactants – energy of products
    • ΔEreverse = 0 kJ/mol - 50 kJ/mol = - 50 kJ/mol
  • Ea = energy of activated complex – energy of reactants
    • Ea = 80 kJ/mol – 0 kJ/mol = 80 kJ/mol
  • E'a = energy of activated complex – energy of products
    • E'a = 80 kJ/mol - 50 kJ/mol = 30 kJ/mol

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