Precision and Accuracy in Analytical Procedures
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Questions and Answers

What is the main reason for analyzing replicates in an analytical procedure?

  • To obtain the exact same individual results
  • To decrease the central value
  • To increase the variability of results
  • To improve reliability and estimate uncertainty (correct)

Which term refers to the most widely used measure of central value in a set of replicate measurements?

  • Mean (correct)
  • Mode
  • Range
  • Median

How is the median calculated when there is an odd number of results?

  • By summing all results and dividing by the number of results
  • By arranging in order and choosing the middle result (correct)
  • By taking the average of the middle pair
  • By finding the result with maximum value

What does the mean represent in a set of replicate measurements?

<p>The central value obtained by division (A)</p> Signup and view all the answers

Why is it important to justify the extra effort required to analyze replicates in an analytical procedure?

<p>To estimate uncertainty and improve reliability (B)</p> Signup and view all the answers

How do we determine the median when there is an even number of results?

<p>Choosing the average value of the middle pair (D)</p> Signup and view all the answers

What does precision in measurements refer to?

<p>The reproducibility of measurements taken in the same way (C)</p> Signup and view all the answers

How is accuracy different from precision?

<p>Accuracy indicates closeness to the true or accepted value. (A)</p> Signup and view all the answers

What type of error causes data to be scattered around a mean value?

<p>Random error (B)</p> Signup and view all the answers

Which type of error causes the mean of a data set to differ from the accepted value?

<p>Systematic error (B)</p> Signup and view all the answers

What is a common source of systematic errors related to measuring devices?

<p>Instrumental errors (C)</p> Signup and view all the answers

Which type of error is characterized by being constant or proportional?

<p>'Systematic errors' (A)</p> Signup and view all the answers

'Indeterminate error' is also known as what type of error?

<p>'Random error' (D)</p> Signup and view all the answers

'Absolute or relative error' is used to express which measure related to experimental data?

<p>'Accuracy' (D)</p> Signup and view all the answers

'Personal errors' often arise in measurements that require what kind of judgments?

<p>'Personal judgments' (D)</p> Signup and view all the answers

What do systematic method errors often result from in chemical analyses?

<p>Slowness and incompleteness of reactions (C)</p> Signup and view all the answers

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