Precipitation Reactions and Solubility Rules

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Questions and Answers

Which of the following metal hydroxides is soluble in excess ammonium hydroxide?

  • Al(OH)₃
  • Fe(OH)₂
  • Mg(OH)₂
  • AgOH (correct)

When $Fe^{3+}$ reacts with SCN⁻, what type of compound is formed?

  • A complex ion (correct)
  • A precipitate
  • A gaseous product
  • A strong acid

Which of these hydroxides is insoluble in $OH^-$?

  • Pb(OH)₄²⁻
  • Fe(OH)₂ (correct)
  • Zn(OH)₄²⁻
  • Al(OH)₄⁻

Identify which of the following metal ions will NOT form an insoluble hydroxide precipitate upon addition of $OH^−$?

<p>$NH_4^{+}$ (C)</p> Signup and view all the answers

Which of the following ions will form a tetraammine complex in the presence of excess ammonia?

<p>$Cu^{2+}$ (C)</p> Signup and view all the answers

Based on the provided reactions, which of the following statements is correct regarding the behavior of $Al^{3+}$ in the presence of hydroxide ions?

<p>It forms a precipitate, $Al(OH)₃$, with limited hydroxide ions, but the precipitate dissolves to form $[Al(OH)₄]^−$ in excess hydroxide ions. (D)</p> Signup and view all the answers

What is the general trend regarding the solubility of hydroxide compounds based on the reactions provided?

<p>All metal hydroxides are insoluble except those of Group 1 metals and ammonium. (C)</p> Signup and view all the answers

Consider the reaction of $Ba^{2+}$ with $SO₄^{2−}$. Which of the following is true about this reaction?

<p>It forms a precipitate that is insoluble. (B)</p> Signup and view all the answers

For the reactions shown, what is the oxidation state of iron in the precipitate $Fe(OH)₂$?

<p>+2 (C)</p> Signup and view all the answers

Based on the reactions, which of the following cations will form an insoluble hydroxide, but will re-dissolve upon the addition of excess hydroxide?

<p>$Zn^{2+}$ (B)</p> Signup and view all the answers

Flashcards

Mg(OH)₂

Magnesium hydroxide, a solid precipitate formed from magnesium ions and hydroxide ions.

AgOH (s)

Silver hydroxide, a solid precipitate.

[Ag(NH₃)₂]⁺(aq)

Complex ion formed when silver ions react with ammonia.

Fe(OH)₂ (s)

Iron(II) hydroxide, a solid precipitate formed from iron(II) ions and hydroxide ions.

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[FeSCN]²⁺ (aq)

Complex ion formed when iron(III) ions react with thiocyanate ions, often used for detection.

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Cu(OH)₂ (s)

Copper(II) hydroxide, a solid precipitate formed from copper(II) ions and hydroxide ions.

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[Cu(NH₃)₄]²⁺ (aq)

Complex ion formed when copper(II) ions react with ammonia.

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Al(OH)₃ (s)

Aluminum hydroxide, a solid precipitate.

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[Al(OH)₄]⁻(aq)

Complex ion formed when aluminum ions react with excess hydroxide ions.

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Insoluble Hydroxides

Insoluble compounds, except for those of Group 1 elements and ammonium.

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Study Notes

  • Mg²⁺(aq) + 2OH⁻(aq) → Mg(OH)₂(s)
  • Ag⁺(aq) + OH⁻(aq) → AgOH(s)
  • Ag⁺(aq) + 2NH₃(aq) → [Ag(NH₃)₂]⁺(aq)
  • Fe²⁺(aq) + 2OH⁻(aq) → Fe(OH)₂(s)
  • Fe³⁺(aq) + 3OH⁻(aq) → Fe(OH)₃(s)
  • Fe³⁺(aq) + SCN⁻(aq) → [FeSCN]²⁺(aq)
  • Cu²⁺(aq) + 2OH⁻(aq) → Cu(OH)₂(s)
  • Cu²⁺(aq) + 4NH₃(aq) → [Cu(NH₃)₄]²⁺(aq)
  • Al³⁺(aq) + 3OH⁻(aq) → Al(OH)₃(s)
  • Al³⁺(aq) + 4OH⁻(aq) → [Al(OH)₄]⁻(aq)
  • Pb²⁺(aq) + 2OH⁻(aq) → Pb(OH)₂(s)
  • Pb²⁺(aq) + 4OH⁻(aq) → [Pb(OH)₄]²⁻(aq)
  • Zn²⁺(aq) + 2OH⁻(aq) → Zn(OH)₂(s)
  • Zn²⁺(aq) + 4NH₄(aq) → [Zn(NH₃)₄]²⁺(aq)
  • Zn²⁺(aq) + 4OH⁻(aq) → [Zn(OH)₄]²⁻(aq)
  • Ba²⁺(aq) + 2OH⁻(aq) → Ba(OH)₂(s)
  • Ba²⁺(aq) + SO₄²⁻(aq) → BaSO₄(s)

Precipitation of Iron(II) Hydroxide

  • Fe(OH)₂ is produced from the identification of Fe²⁺
  • Fe(OH)₂ is insoluble
  • Oxides and hydroxides are generally insoluble, with exceptions of group 1 elements and ammonium ion
  • Iron(II) is not a group 1 element nor ammonium ion.

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