Powder Bed Fusion Processes
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Questions and Answers

Which of the following is the first commercialized Powder Bed Fusion process?

  • Binder Jetting
  • Direct Energy Deposition
  • Selective Laser Sintering (correct)
  • Fused Deposition Modeling

Powder Bed Fusion processes include only metallic materials.

False (B)

What is one of the main powder fusion mechanisms mentioned in Powder Bed Fusion processes?

Liquid-phase sintering

The first PBF process, Selective Laser Sintering, was developed at the __________.

<p>University of Texas at Austin</p> Signup and view all the answers

Match the following powder fusion mechanisms with their descriptions:

<p>Solid-state sintering = Fusion without melting of particles Chemically induced sintering = Fusion induced by chemical reactions Liquid-phase sintering = Fusion through partial melting Full melting = Complete melting of powder particles</p> Signup and view all the answers

What happens to the rate constant as activation energy decreases?

<p>It increases (A)</p> Signup and view all the answers

The activation energy of a catalyzed reaction is larger than that of an un-catalyzed reaction.

<p>False (B)</p> Signup and view all the answers

What is the rate constant found when the temperature is 289K, Activation Energy is 200kJ/mol, and pre-exponential factor is 9 M-1s-1?

<p>6.37 x 10^-36 M-1s-1</p> Signup and view all the answers

Chemically-induced sintering forms a by-product that binds the powder together with the help of ___________ reactions.

<p>thermally-activated</p> Signup and view all the answers

Match the following reactions to their resulting compounds:

<p>Laser processing of SiC = SiO2 Laser processing of ZrB2 = ZrO2 Laser processing of Al = AlN</p> Signup and view all the answers

Which of the following is a disadvantage of chemically-induced sintering?

<p>High cost and time in post-processing (C)</p> Signup and view all the answers

Liquid-Phase Sintering (LPS) is the most versatile mechanism for Powder Bed Fusion (PBF).

<p>True (A)</p> Signup and view all the answers

At what temperature is the rate constant 7 M-1s-1?

<p>389K</p> Signup and view all the answers

Which of the following processes is primarily used for producing plastic prototypes?

<p>Laser Sintering (B)</p> Signup and view all the answers

Thermoset polymers can be processed using Powder Bed Fusion into parts.

<p>False (B)</p> Signup and view all the answers

What is the typical thickness of the powder layers used in the polymer laser sintering process?

<p>0.075 - 0.1 mm</p> Signup and view all the answers

The build chamber for polymer laser sintering is filled with __________ gas to minimize oxidation.

<p>nitrogen</p> Signup and view all the answers

Match the following materials with their classification:

<p>Nylon = Thermoplastic polymer Titanium = Metal Alumina = Ceramic Cobalt-chromium = Metal alloy</p> Signup and view all the answers

Which of these materials is commonly known to be processed using Powder Bed Fusion?

<p>Thermoplastic polymers (C)</p> Signup and view all the answers

Infrared heaters are used in the polymer laser sintering process.

<p>True (A)</p> Signup and view all the answers

What are the two types of molecular structures found in thermoplastic polymers?

<p>Amorphous and Crystalline</p> Signup and view all the answers

PBF technology is increasingly used for direct digital manufacturing of __________ products.

<p>end-use</p> Signup and view all the answers

Which of the following materials is NOT typically processed with Powder Bed Fusion?

<p>Thermoset polymers (C)</p> Signup and view all the answers

What is the primary purpose of LPS in powder processing?

<p>To act as a glue binding solid particles together (C)</p> Signup and view all the answers

LPS can be used in additive manufacturing as a fusion mechanism.

<p>True (A)</p> Signup and view all the answers

What is the common material used in PBF processing?

<p>Nylon polyamide</p> Signup and view all the answers

In LPS, the molten constituent acts as the ______ which binds the solid particles together.

<p>glue</p> Signup and view all the answers

Which of the following materials is NOT typically used in PBF processing?

<p>Cemented Carbide (B)</p> Signup and view all the answers

Match the following terms with their descriptions:

<p>LPS = Fusion of powder particles where some constituents melt PBF = Process that melts the entire region of material Nylon Polyamide = Common material used in PBF Co = Low melting point constituent in cemented carbide tools</p> Signup and view all the answers

Full melting means that only a portion of the material is melted during PBF processing.

<p>False (B)</p> Signup and view all the answers

What are two engineering alloys mentioned as utilized in PBF processing?

<p>Titanium and Stainless Steel</p> Signup and view all the answers

What is a characteristic of an electron beam when it interacts with gas at atmospheric pressure?

<p>It is deflected. (D)</p> Signup and view all the answers

A laser beam requires a vacuum environment to function effectively.

<p>False (B)</p> Signup and view all the answers

What is one of the primary benefits of using Powder Bed Fusion over other additive manufacturing processes?

<p>It can process a wide variety of materials.</p> Signup and view all the answers

PBF processes typically have accuracy and surface finish that are __________ compared to liquid-based processes.

<p>inferior</p> Signup and view all the answers

Match the following terms with their descriptions related to Powder Bed Fusion processes:

<p>Finer particle size = Produces smoother, more accurate parts Larger particle size = Facilitates easier powder processing Loose powder during part building = Sufficient support material for polymer PBF Total part construction time = Can take longer due to preheat and cool-down cycles</p> Signup and view all the answers

Which of the following describes one possible process parameter that can influence the final microstructure of materials in Powder Bed Fusion?

<p>Powder particle size (B)</p> Signup and view all the answers

Materials with high thermal conductivity typically produce better accuracy in Powder Bed Fusion processes.

<p>False (B)</p> Signup and view all the answers

What is a common drawback of using larger powder particle sizes in Powder Bed Fusion?

<p>It hurts surface finish and minimum feature size.</p> Signup and view all the answers

What is primarily used in Polymer Laser Sintering (pLS) machines to create parts?

<p>CO2 lasers (A)</p> Signup and view all the answers

Electron Beam Melting (EBM) uses laser beams for metal fusion.

<p>False (B)</p> Signup and view all the answers

What materials are commonly processed in Polymer Laser Sintering machines?

<p>Nylon polyamide materials</p> Signup and view all the answers

In EBM, a stream of __________ moving near the speed of light is used for particle fusion.

<p>electrons</p> Signup and view all the answers

Match the following PBF process variants with their main characteristics:

<p>Selective Laser Sintering (SLS) = Uses lasers to process polymers and indirectly process metals. Electron Beam Melting (EBM) = Uses high-energy electron beams for metal fusion. Polymer Laser Sintering (pLS) = Designed for processing a variety of powdered polymer materials. Laser Sintering (LS) = Commonly refers to laser-based sintering processes.</p> Signup and view all the answers

Which of the following statements about the atmosphere in Polymer Laser Sintering machines is true?

<p>They use nitrogen with approximately 0.1-3.0% oxygen. (D)</p> Signup and view all the answers

PLS machines are capable of directly processing pure metals.

<p>False (B)</p> Signup and view all the answers

What is the primary advantage of using Electron Beam Melting compared to laser-based systems?

<p>It uses a high-energy electron beam for fusion, allowing different processing capabilities.</p> Signup and view all the answers

Which of the following is a primary approach used in extrusion processes?

<p>Using chemical changes for solidification (D)</p> Signup and view all the answers

Fused deposition modeling (FDM) requires a fixed horizontal position for the extruder.

<p>False (B)</p> Signup and view all the answers

What is the purpose of bonding in extrusion-based systems?

<p>To ensure that materials adhere properly during the extrusion process.</p> Signup and view all the answers

In extrusion-based systems, the term __________ refers to the control of the extruder's position during the printing process.

<p>Positional control</p> Signup and view all the answers

Match the following FDM related terms with their descriptions:

<p>Gel formation = A state where material transitions into a gel before solidification Scaffold architectures = Structures designed to support the growth of cells in biomedical applications Melt extrusion = The process of melting materials for deposition Bioextrusion = Extrusion processes tailored for biocompatible materials</p> Signup and view all the answers

What limitation is often associated with FDM?

<p>Limited choice of extrudable materials (C)</p> Signup and view all the answers

Contour crafting is considered one of the other systems in extrusion-based methods.

<p>True (A)</p> Signup and view all the answers

What is the significance of solidification in the extrusion-based process?

<p>Solidification ensures that the extruded material maintains its shape and structural integrity.</p> Signup and view all the answers

Flashcards

What is Powder Bed Fusion (PBF)?

PBF is a type of additive manufacturing where a powder material is selectively fused together layer by layer using a focused energy source, like a laser or electron beam.

What is Selective Laser Sintering (SLS)?

SLS is a specific PBF process where a laser beam selectively melts and fuses powdered material, creating a solid object layer by layer.

What materials can be used in PBF processes?

PBF processes are versatile and can use a wide range of materials, including polymers, metals, ceramics, and composites.

How does powder fusion happen in PBF processes?

Powder fusion in PBF processes can occur through various mechanisms, including solid-state sintering, chemically induced sintering, liquid-phase sintering, and full melting depending on the material and process parameters.

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What are the main process parameters in PBF?

Process parameters in PBF processes are crucial for the final product quality and include factors like laser power, scan speed, layer thickness, and powder bed temperature.

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What is PBF?

Powder Bed Fusion (PBF) is an additive manufacturing process where a powder material is selectively fused together layer by layer using a focused energy source, like a laser or electron beam.

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What are PBF process modifications?

Modifications to the basic PBF process can improve machine productivity, enable the use of different materials, and avoid patented features.

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What is Laser Sintering (LS)?

LS is a specific PBF process that utilizes a laser to melt and fuse powder, creating a solid object layer by layer.

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What is the basic principle of LS?

LS uses a laser to scan and fuse thin layers of powder, with the build platform moving down after each layer to create a 3D object.

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What is a Powder Leveling Roller?

A powder leveling roller is used to evenly distribute the powder onto the build platform before each layer in LS.

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Why is nitrogen gas used in LS?

Nitrogen gas is used in the LS chamber to prevent oxidation and degradation of the powdered material during the process.

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What materials can be used in LS?

LS can be used to process a wide range of materials, including polymers, metals, ceramics, and composites.

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What are some examples of materials used in LS?

Examples of materials used in LS include nylon and composites for polymers, stainless steel, titanium, and aluminum alloys for metals, and various ceramic materials for ceramics.

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What is a key benefit of LS?

LS is increasingly being used for direct digital manufacturing of end-use products, as the produced objects have properties comparable to traditionally manufactured parts.

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What is a difference between thermoplastic and thermoset polymers?

Thermoplastics can be melted and reshaped repeatedly while thermosets solidify permanently and cannot be remelted.

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Arrhenius Equation

A mathematical equation that relates the rate constant of a chemical reaction to the activation energy, temperature, and pre-exponential factor. It helps predict the rate of a reaction at different temperatures.

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Activation Energy (Ea)

The minimum amount of energy that reactant molecules must possess to overcome the energy barrier and initiate a chemical reaction.

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What effect does temperature have on the rate constant?

As temperature increases, the rate constant increases because molecules have more energy to overcome the activation energy barrier and react more readily.

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How does a catalyst impact activation energy?

A catalyst lowers the activation energy of a reaction by providing an alternative reaction pathway with a lower energy barrier, speeding up the reaction rate.

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Chemically-induced Sintering

A process where chemical reactions between powders and atmospheric gases form a byproduct that binds the powder together, forming a solid material.

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Liquid-Phase Sintering (LPS)

A sintering process where a liquid phase forms during the sintering process, allowing for faster densification and faster material transport.

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What is a common characteristic of chemically-induced sintering?

Chemically-induced sintering often results in some porosity in the final material, requiring additional processing to achieve full density.

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Why is post-processing often required in chemically-induced sintering?

Post-processing, such as infiltration with reactive elements or furnace sintering, is often necessary to achieve the desired density and mechanical properties for most applications.

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LPS

A process where powder particles fuse together due to the melting of a lower-melting-point constituent, acting as a glue for solid particles.

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LPS in Powder Metallurgy

Used in traditional powder metallurgy to create materials like cemented carbide cutting tools, where Co is used to bind WC particles.

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LPS in Additive Manufacturing

LPS can be utilized as a fusion mechanism in AM, particularly in Powder Bed Fusion (PBF) processes.

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Full Melting

A type of LPS in PBF where the entire material region is melted, exceeding the layer thickness, creating strong bonds.

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Full Melting in PBF

The heat from subsequent scans re-melts a portion of the previously solidified structure, ensuring strong bonding and high density.

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Materials for Full Melting

Engineering metals and polymers are ideal for full melting PBF processes, with examples including nylon, titanium, stainless steel, and CoCr alloys.

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PBF Material Examples

The most common material used in PBF with full melting is nylon polyamide, due to a distinct melting point.

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Full Melting in PBF

Full melting is crucial in PBF for materials like nylon to achieve maximum strength and density.

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Why can't pLS process pure metals or ceramics?

pLS machines use CO2 lasers and a nitrogen atmosphere with a small amount of oxygen. This environment is not suitable for directly melting and fusing pure metals or ceramics, which require higher temperatures.

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What are the most common materials used in pLS?

Nylon polyamide materials are the most popular materials for pLS. However, other polymers and indirect processing of metals and ceramics with polymer binders are also possible.

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How does EBM differ from laser-based systems?

EBM uses an electron beam, which is a stream of electrons moving at near the speed of light, while laser-based systems use photons traveling at the speed of light.

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What are the benefits of EBM?

EBM has proven to be successful in PBF because it allows for the manufacturing of complex metal parts with high accuracy and density.

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How does EBM achieve fusion?

EBM uses the high energy of electrons to melt and fuse metal powder particles, creating a solid object layer by layer.

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What are the key differences between EBM and SLM?

EBM and SLM are both PBF processes, but they differ in their energy source (electrons vs. laser) and temperature control. EBM operates in a vacuum with a high-energy electron beam, while SLM utilizes a laser in a controlled atmosphere.

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What is EBM used for?

Electron beam melting (EBM) is used in 3D printing to fuse powdered metal by selectively melting it with an electron beam. It's often used for creating complex and dense metal parts in a vacuum environment.

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What is a key advantage of powder bed fusion (PBF)?

Powder bed fusion processes can utilize a broad range of materials, including polymers, metals, ceramics, and composites. This versatility makes it a popular choice for various applications and industries.

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What is a key disadvantage of PBF?

The surface finish and accuracy of powder-based additive manufacturing are typically inferior to liquid-based methods due to the nature of the powder. Finer particles lead to smoother surfaces, but handling them is challenging. Larger particles are easier to work with but impact surface finish, feature size, and layer thickness.

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What is mask-based sintering?

It's a method in powder bed fusion where a mask defines the areas to be sintered. The mask blocks the energy source (like a laser) from reaching unwanted regions, allowing selective fusion.

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How does printing an absorptivity-enhancing agent work in PBF?

Adding an agent that absorbs more energy from the laser beam to specific areas increases the localized temperature, promoting sintering in those regions only, while other areas remain untouched.

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How does printing a sintering inhibitor work in PBF?

Printing a substance that prevents sintering in undesired regions ensures controlled fusion in specific areas while keeping others untouched.

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What is the benefit of using loose powder as a support material in PBF?

Using loose powder instead of a dedicated support material simplifies the process, saving time and resources during part construction and post-processing.

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Extrusion-Based Systems: What are the two primary approaches?

These systems use either temperature to control the material state (like melting and solidifying) or a chemical change (like curing or drying) to achieve bonding.

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Material Loading

The process of introducing the feedstock material into the extrusion system, often in a powder or filament form.

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Liquification

The process of melting or dissolving the feedstock material to create a liquid or viscous state suitable for extrusion.

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Extrusion

The process of pushing the liquefied material through a nozzle to form a continuous, controlled stream, building a layer of the final product.

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Solidification

The process of the extruded material transitioning back to a solid state, hardening and bonding to previously deposited layers.

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Positional Control

The ability to precisely move the extrusion nozzle in 3D space, ensuring accurate layering and building of the desired shape.

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Fused Deposition Modeling (FDM)

A common extrusion-based additive manufacturing process where thermoplastic materials are melted and extruded layer by layer to create a 3D part.

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Bioextrusion: What is involved?

Specialized extrusion techniques used to create biocompatible scaffolds for tissue engineering and regenerative medicine.

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Study Notes

Chapter 5: Powder Bed Fusion Processes

  • Powder bed fusion (PBF) is a paradigm approach
  • PBF processes use lasers, electron beams, and other thermal sources for sintering
  • The first commercial PBF process was Selective Laser Sintering (SLS)
  • SLS is at the core of other PBF process variations
  • Several types of materials are used including polymers, metals, and ceramics

Objectives

  • Powder bed fusion processes
  • SLS process description
  • Materials (polymers, metals, and ceramics)
  • Powder fusion mechanisms (solid-state, chemically induced, liquid-phase, and full melting)
  • Part fabrication (metal and ceramic)
  • Process parameters and modeling
  • Powder handling
  • PBF process variants and commercial machines
  • Process benefits and drawbacks
  • Conclusions

Materials

  • Polymers (thermoplastic, thermoset)
  • Metals (stainless steels, tool steels, titanium, nickel-based alloys, aluminum alloys, and cobalt-chromium alloys)
  • Ceramics (aluminum oxide, titanium oxide, calcium hydroxyapatite)

Powder Fusion Mechanisms

  • Solid-state sintering: Diffusion between particles to minimize surface area, necking and consolidation
  • Chemically induced sintering: Chemical reactions between powders and atmospheric gases to form a by-product. Examples include SiO2 formation when sintering SiC in oxygen, ZrO2 formation when sintering ZrB2 in oxygen, and AIN formation when sintering Al in nitrogen.
  • Liquid-phase sintering: Molten constituents act like glue to bind particles. Often uses lower-melting point additives like cobalt (Co) in tungsten carbide (WC) composites
  • Full melting: Entire region of material gets melted to higher depths. This is most commonly associated with engineering metals and semi-crystalline polymers.

Part Fabrication

  • Metal parts
  • Ceramic parts
  • Pattern methods to create metal parts (investment casting patterns or sand casting molds)

Process Parameters and Modeling

  • Laser-related parameters (laser power, spot size, pulse duration, pulse frequency)
  • Scan-related parameters (scan speed, scan spacing, and scan patterns)
  • Powder-related parameters (particle shape, size, distribution, powder bed density, and layer thickness, absorptivity)
  • Temperature-related parameters (powder bed temperature, powder feed temperature, material properties, etc. e.g. absorptivity)
  • Applied Energy calculations: Melting pool formation, and characteristics are fundamentally determined by the total amount of energy the laser beam absorbs from the powder bed. The formula for energy density (Ea=P/(U*SP)), where P = laser power, U = scan velocity, and SP = scan spacing. Scan spacing, scan speed, and laser power affect energy density.

Powder Handling

  • Challenges of powder delivery systems (e.g., shear forces, electrostatic forces, spreading issues, airborne powder).
  • Methods to transport correct powder volumes to build platforms
  • Methods for spreading and leveling powder layers, like doctor blades, rollers, or hoppers

PBF Process Variants and Commercial Machines

  • SLS, Laser Sintering (LS), other 3D systems' low-temperature machines using CO2 lasers and nitrogen atmosphere. Specific types of commercial machines (e.g. from 3D Systems and EOS)
  • Nylon polyamide (polymer) materials are most used.
  • Melting and solidification characteristics
  • Idealized polymer DSC curve for polymer laser sintering can be observed.
  • 3D printing systems with powder feed systems, build platforms
  • Machines with multiple heads for different materials.

Applied Energy Calculations and Scan Patterns

  • Melt pool formation depends on how much energy the laser beam absorbed from the powder bed
  • Formula for energy density (EA=P/(U * SP))
  • Scan spacing (SP), scan speed (U), laser power (P) affect energy density -Different scan paths (e.g., contour, squares) can create different effects on the part, with implications for precision, accuracy, and material strength. -Process maps showing regions of power and scan speed combinations that result in each of the track types (as described by Childs et al.) have been characterized.

Optical Absorption vs Wavelength

  • Different materials absorb different wavelengths differently (especially useful for selecting the right laser and material). Fiber lasers, N:YAG lasers, and CO2 lasers are common. Material absorptivity, and wavelengths associated with each laser type, are useful for determining the optimal conditions for a particular material.

Electron Beam Melting (EBM)

  • High-energy electron beam for inducing fusion
  • Uses a vacuum environment for operation
  • The Electron beam is different from lasers.
  • Table and figure showing key differences between EBM and SLS: such as thermal source, atmosphere, scanning, energy absorption, and other important features.

Line-wise and Layer-wise PBF Processes

  • Mask-based sintering
  • Printing of an absorptivity-enhancing agent (or a sintering inhibitor)

Process Benefits and Drawbacks

  • PBF offers better accuracy and surface finish for particular materials
  • PBF has advantages in part building time for some materials
  • Challenges include accuracy and surface finish of parts using powder-based AM, minimum feature size, limited build rates, minimum layer thickness, shrinkage, and the handling of different powders.

Exercises

  • Includes questions requiring application of Arrhenius equation, energy driving forces of different powder beds, advantages/disadvantages of binders in liquid-phase sintering, powder characteristics exploration (using standard kitchen ingredients), parameter limitations in nylon polyamide PBF, minimum laser dwell time calculations, and other process parameter explorations.

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Powder Bed Fusion Processes PDF

Description

Explore the concepts of Powder Bed Fusion (PBF) processes in this quiz. Test your knowledge on mechanisms like Selective Laser Sintering, activation energy, and chemically-induced sintering. Deepen your understanding of how different powder fusion methods work and their applications.

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