Position of d-Block Elements in Periodic Table
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Questions and Answers

What is the reason behind the high melting and boiling points of transition metals?

  • Weak interatomic interactions
  • High ionization energy of transition metals
  • Involvement of both ns and (n-1)d electrons in metallic bonding (correct)
  • Presence of fully filled d-orbitals

Why do zinc, cadmium, and mercury have relatively low melting points and boiling points?

  • Strong metallic bonds
  • High ionization energy
  • Less delocalization of electrons
  • Presence of fully filled d-orbitals (correct)

Why do manganese (Mn), Technetium (Tc), and Rhenium (Re) have lower melting points compared to their neighborhood elements?

  • Strong metallic bonding
  • Presence of d5 configuration (correct)
  • High ionization energy
  • Full d-orbitals

What is the trend in melting points of transition metals in a series?

<p>Maximum at the middle of the series and then decrease (C)</p> Signup and view all the answers

Why is mercury liquid at room temperature?

<p>[Xe] configuration with full 5d10 6s2 (A)</p> Signup and view all the answers

Why are d-block elements called transition elements?

<p>Because they come between s and p block elements and have incomplete d-orbitals. (A)</p> Signup and view all the answers

Why are Zn, Cd, and Hg not classified as transition elements?

<p>Because they have fully filled d-orbitals in both their ground state and common oxidation states. (D)</p> Signup and view all the answers

Which series of d-block elements includes elements from Scandium (Sc) to Zinc (Zn)?

<p>3d series (A)</p> Signup and view all the answers

Why is Copper (Cu) considered a transition element despite having a fully filled d-orbital?

<p>Because it has an incomplete d-orbital in its ground state. (D)</p> Signup and view all the answers

Why do Zn, Cd, and Hg have the same electron configuration in their ground state?

<p>They all have fully filled d-orbitals. (A)</p> Signup and view all the answers

Study Notes

  • D-block elements are in the middle of s and p blocks, comprising groups 3 to 12 in the periodic table, with four transition series: 3d, 4d, 5d, and 6d series.
  • The general electronic configuration of d-block elements is (n-1)d(1-10) ns(1-2) for different series.
  • Transition elements are called so because they bridge the most electropositive ‘s’ and less electropositive ‘p’ block elements, with incomplete d-orbitals in their ground state or oxidation state.
  • Zinc, Cadmium, and Mercury are d-block elements but not called transition elements as their d-orbitals are fully filled in both ground state and common oxidation state.
  • Transition metals have high melting points due to the presence of more unpaired electrons in d-orbitals, involving both ns and (n-1)d electrons in metallic bonding.

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Learn about the position of d-block elements in the periodic table, which are situated between the s and p blocks. Explore the transition series including the 3d, 4d, 5d, and 6d series.

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