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Questions and Answers
What is a characteristic feature of methyl methacrylate during its polymerization process?
What is a characteristic feature of methyl methacrylate during its polymerization process?
Which of the following properties of Plexi glass makes it suitable for use in lenses?
Which of the following properties of Plexi glass makes it suitable for use in lenses?
In what form can polyurethanes be produced?
In what form can polyurethanes be produced?
Why are synthetic polymers considered non-biodegradable?
Why are synthetic polymers considered non-biodegradable?
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Which application of Plexi glass is incorrect?
Which application of Plexi glass is incorrect?
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What is a significant property of polyurethanes that differentiates them from other polymers?
What is a significant property of polyurethanes that differentiates them from other polymers?
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What temperature is Plexi glass known to soften at?
What temperature is Plexi glass known to soften at?
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Which of the following is not a feature of natural polymers?
Which of the following is not a feature of natural polymers?
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What happens to polyaniline upon protonation and oxidation?
What happens to polyaniline upon protonation and oxidation?
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Which application is NOT associated with conducting polyaniline?
Which application is NOT associated with conducting polyaniline?
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What defines biodegradable polymers?
What defines biodegradable polymers?
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Which of the following is a renewable source for biodegradable polymers?
Which of the following is a renewable source for biodegradable polymers?
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What is a crucial factor for the effectiveness of biodegradable polymers?
What is a crucial factor for the effectiveness of biodegradable polymers?
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How are polyhydroxyalkanoates (PHAs) primarily produced?
How are polyhydroxyalkanoates (PHAs) primarily produced?
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What challenges do biodegradable polymers face for a sustainable future?
What challenges do biodegradable polymers face for a sustainable future?
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Which of the following statements about polyaniline is false?
Which of the following statements about polyaniline is false?
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What is the primary role of monomers in polymer chemistry?
What is the primary role of monomers in polymer chemistry?
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Which of the following statements regarding polymers is true?
Which of the following statements regarding polymers is true?
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Who proposed the existence of macromolecules and received the Nobel Prize in 1953 for his work?
Who proposed the existence of macromolecules and received the Nobel Prize in 1953 for his work?
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What is the typical molecular mass range for polymers?
What is the typical molecular mass range for polymers?
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Which of the following is an example of a monomer?
Which of the following is an example of a monomer?
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What is the significance of polymers in daily life?
What is the significance of polymers in daily life?
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Which component is the major constituent of natural fibres?
Which component is the major constituent of natural fibres?
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What type of bond links the repeating units in cellulose?
What type of bond links the repeating units in cellulose?
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How are polymers formed from monomers?
How are polymers formed from monomers?
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Which property is NOT associated with cellulose?
Which property is NOT associated with cellulose?
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Which term describes the small repeating units that make up a polymer?
Which term describes the small repeating units that make up a polymer?
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What distinguishes hemicelluloses from cellulose?
What distinguishes hemicelluloses from cellulose?
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Which of the following is true about the molecular weight of hemicelluloses compared to cellulose?
Which of the following is true about the molecular weight of hemicelluloses compared to cellulose?
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What is the degree of polymerization of hemicelluloses approximately?
What is the degree of polymerization of hemicelluloses approximately?
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What function do hemicelluloses serve in relation to cellulose?
What function do hemicelluloses serve in relation to cellulose?
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Which type of sugar units do hemicelluloses consist of?
Which type of sugar units do hemicelluloses consist of?
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What effect does alkali treatment have on the crystalline structure of cellulose?
What effect does alkali treatment have on the crystalline structure of cellulose?
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How does alkali treatment modify the moisture resistance property of natural fibres?
How does alkali treatment modify the moisture resistance property of natural fibres?
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What is a direct result of the elimination of surface impurities during alkali treatment?
What is a direct result of the elimination of surface impurities during alkali treatment?
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What happens to the fibre diameter as a result of alkali treatment?
What happens to the fibre diameter as a result of alkali treatment?
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During the potassium permanganate treatment of natural fibres, how do permanganate ions interact with lignin?
During the potassium permanganate treatment of natural fibres, how do permanganate ions interact with lignin?
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What is the consequence of the roughened surface of fibres after alkali and potassium permanganate treatment?
What is the consequence of the roughened surface of fibres after alkali and potassium permanganate treatment?
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What is primarily removed from natural fibres during alkali treatment?
What is primarily removed from natural fibres during alkali treatment?
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What occurs to the cellulose molecular chains during alkali treatment?
What occurs to the cellulose molecular chains during alkali treatment?
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What is the primary purpose of alkali pre-treatment of natural fibres before immersing them in acrylic acid?
What is the primary purpose of alkali pre-treatment of natural fibres before immersing them in acrylic acid?
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What happens to the moisture absorption property of chemically treated fibres after the introduction of hydrophobic ester groups?
What happens to the moisture absorption property of chemically treated fibres after the introduction of hydrophobic ester groups?
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What is the significance of the ester linkage formed between acrylic acid and natural fibres?
What is the significance of the ester linkage formed between acrylic acid and natural fibres?
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Which of the following is NOT a property that modern composite materials aim to modify?
Which of the following is NOT a property that modern composite materials aim to modify?
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When were polymer composites first developed for military and aerospace applications?
When were polymer composites first developed for military and aerospace applications?
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What is the definition of a polymer composite?
What is the definition of a polymer composite?
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How has the application of polymer composites evolved over the years?
How has the application of polymer composites evolved over the years?
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Which of the following materials is NOT mentioned as part of bispolymeric composites?
Which of the following materials is NOT mentioned as part of bispolymeric composites?
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Flashcards
Polymer
Polymer
A large molecule formed by many small repeating units (monomers).
Monomer
Monomer
A simple molecule that can bond to form a polymer chain.
Polymerization
Polymerization
The process of converting monomers into polymers.
Hermann Staudinger
Hermann Staudinger
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Macromolecule
Macromolecule
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Covalent bonds
Covalent bonds
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Examples of Polymers
Examples of Polymers
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Building blocks of Polymers
Building blocks of Polymers
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Alkali effect on cellulose
Alkali effect on cellulose
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Amorphous cellulose
Amorphous cellulose
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Hydrogen bonding in cellulose
Hydrogen bonding in cellulose
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Surface topography alteration
Surface topography alteration
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Hemicelluloses removal
Hemicelluloses removal
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Potassium Permanganate Treatment
Potassium Permanganate Treatment
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Chemical interlocking enhancement
Chemical interlocking enhancement
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Aspect ratio increase
Aspect ratio increase
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Biodegradable Polymers
Biodegradable Polymers
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Synthetic Polymers
Synthetic Polymers
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Plexi Glass
Plexi Glass
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Properties of Plexi Glass
Properties of Plexi Glass
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Applications of Plexi Glass
Applications of Plexi Glass
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Polyurethanes
Polyurethanes
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Properties of Polyurethanes
Properties of Polyurethanes
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Polyurethane Foams
Polyurethane Foams
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Natural Fibres
Natural Fibres
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Cellulose
Cellulose
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1,4-β-D-glycosidic linkages
1,4-β-D-glycosidic linkages
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Degree of Polymerization
Degree of Polymerization
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Hemicelluloses
Hemicelluloses
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Lignin
Lignin
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Pectin
Pectin
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Chemical Composition of Natural Fibres
Chemical Composition of Natural Fibres
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Doped Polyaniline
Doped Polyaniline
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Polyaniline Color Variations
Polyaniline Color Variations
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Applications of Conducting Polyaniline
Applications of Conducting Polyaniline
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Sources of Biodegradable Polymers
Sources of Biodegradable Polymers
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Efficiency in Composting
Efficiency in Composting
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Choosing Biodegradable Polymers
Choosing Biodegradable Polymers
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Electromagnetic Properties of Polyaniline
Electromagnetic Properties of Polyaniline
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Acrylic Acid Treatment
Acrylic Acid Treatment
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Alkali Pre-treatment
Alkali Pre-treatment
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Reactive Cellulose Macro Radicals
Reactive Cellulose Macro Radicals
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Ester Linkage
Ester Linkage
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Moisture Absorption Property
Moisture Absorption Property
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Polymer Composites
Polymer Composites
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Applications of Polymer Composites
Applications of Polymer Composites
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Bispolymeric Composites
Bispolymeric Composites
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Study Notes
Introduction
- Chemists initially doubted the existence of molecules with weights exceeding a few thousand.
- Hermann Staudinger challenged this view, proposing macromolecules (comprised of 10,000+ atoms).
- Staudinger's work, particularly on rubber and cellulose, led to the Nobel Prize in 1953.
- The terms "polymer" and "monomer" originate from Greek roots, signifying "many parts" and "one part," respectively.
- Polymers are crucial for daily life essentials such as food, clothing, and shelter.
- Polymer science and technology have led to diverse materials including plastics, fibers, and resins.
- These materials range in properties from soft silk to strong steel.
Basic Definitions
- Polymer: A large molecule from numerous small repeating molecules joined by covalent bonds.
- Examples: polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), Teflon.
- Molecular weight usually ranges from 10,000 to 100,000.
- Properties differ significantly from individual monomers.
Monomer
- A simple molecule with two or more bonding sites to link with other monomers to grow polymer chains.
- Examples include alkenes, vinyl chloride, adipic acid, and glycol.
Polymerization
- The chemical process transforming small molecules (monomers) into a large polymer molecule.
- Requires each monomer to have at least two bonding sites (e.g., a double bond within a molecule).
- May involve various techniques, like bulk polymerization, to achieve the reaction.
- An initiator (like hydrogen peroxide) may be required to start the process.
Functionality
- The number of bonding sites available in a monomer to participate in polymerization.
- Monomers can be bi-functional, tri-functional, or poly-functional depending on the number of bonding sites.
Commercial Polymers
- Polymethyl methacrylate (PMMA): A transparent thermoplastic.
- Also known as Plexiglass or Lucite, it is easily molded and resistant to organic solvents.
- Applications: windows, lenses, glazing, and many other applications.
- Synthesis involves heating methyl methacrylate monomers in the presence of a catalyst, and bulk polymerization.
Polyurethanes
- Polyurethanes are created via the addition polymerization of a diisocyanate with a glycol (or triol).
- Resultant polymer features the –NHCOO– urethane linkage.
- Usable as elastomers, fibers, coatings, or foams.
- Resistant to corrosive chemicals, oils, and greases.
- Exhibits high stretchability and abrasion resistance.
- Available in both rigid and flexible foam forms.
- Applications include tire treads, industrial wheels, and various fabrications.
Conducting Polymers
- Materials capable of conducting electricity.
- Before 1960, most polymers were considered insulators.
- Polyacetylene (among others) demonstrated electrical conductivity when doped.
- The Nobel Prize in Chemistry was awarded to those who developed these materials in the 1970s.
- Conducting polymers feature a conjugated backbone with alternating single and double carbon-carbon bonds.
- Doping of polymers (with oxidizing or reducing agents) is crucial for electron delocalization and conductivity improvement.
- Advantages: light weight, flexibility, low cost.
- Applications: telecommunication, printed circuit boards, aerospace wiring, and others.
Properties of Polymers
- Polymers exhibit diverse properties influenced by monomer type, structure, and other factors.
- Light weight and chemically stable.
- Easily molded into various shapes and sizes.
- High melting and boiling points due to stronger intermolecular forces.
- Some polymers have strong, elastic properties, especially those with increased chain length and cross-linking.
- Additional properties include tensile strength, transparency, insulation characteristics, corrosion résistance, thermal stability and non-rusting tendencies.
- Applications including their use in lasers, food packaging, and electronic devices.
Biodegradable Polymers
- Biodegradable polymers are an alternative to conventional plastics.
- They can break down into natural substances through the action of microorganisms under specific conditions.
- Can originate from renewable sources like corn starch, wood cellulose as well as be generated by microorganisms from specific chemical substances
- Suitable for applications including replacing existing plastics for packaging, medical implants, and various other applications.
Natural Fibres
- Natural fibres like cotton, hemp, and flax exhibit adaptability, fineness, and a good aspect ratio.
- Suitable as reinforcement in several composites due to properties including superior strength/weight ratio, biodegradability and resistance to low temperatures.
- Processing conditions and moisture absorption properties are important factors.
Surface Modification of Natural Fibres
- Chemical treatments (e.g., alkali, potassium permanganate, and acrylic acid) can alter natural fibres' properties:
- Strength / flexibility.
- Improving their adhesion to different polymers.
- Their interaction with various chemicals.
- These alterations are important for the success of polymer composites fabrication
- Examples: Alkali Treatment for enhanced interactions between polymers and natural materials, and potassium permangnate treatment for increased fibre strength and rigidity.
Polymer Composites
- Combination of two or more materials with different properties.
- Polymer composites often combine polymers with other materials like natural fibers, metals, or other polymers to achieve specific properties (like high strength, low weight).
- Enhanced properties compared to the constituent materials.
- Applications in various industries, from aerospace to automotive to consumer products.
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Description
Explore the fascinating world of polymers, their definitions, and significance in everyday life. This quiz delves into the pioneering work of Hermann Staudinger and the diverse applications of polymers such as plastics and fibers. Test your knowledge about macromolecules and their role in modern materials.