Polar Solvents and Temperature Effects Quiz
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Questions and Answers

According to Beer-Lambert's law, absorbance (A) is directly proportional to the concentration (C) of the absorbing medium, when the path length (b) is constant.

True

Molar absorptivity (ɛ) is a constant known as absorptivity when the concentration is 1M and the path length is 1cm.

False

Absorptivity (a) can be calculated from the intercept of the curve produced by plotting absorbance (A) against concentration (C) when path length (b) is fixed.

False

A 1% solution of a substance has a molar absorptivity represented as A(1%, 1cm).

<p>True</p> Signup and view all the answers

Isosbestic point is a characteristic absorption profile exhibited by all substances regardless of their nature.

<p>False</p> Signup and view all the answers

Temperature has no effect on the absorbance of a substance according to Beer-Lambert's law.

<p>False</p> Signup and view all the answers

At the isosbestic point, the absorbance is pH dependent.

<p>False</p> Signup and view all the answers

An increase in temperature may cause hypsochromic shift in a solution.

<p>False</p> Signup and view all the answers

The absorption of monochromatic light in an absorbing medium is only due to absorption (Ia) and refraction (If).

<p>False</p> Signup and view all the answers

The spectrum of a substance in polar solvents will be different from that in non-polar solvents.

<p>True</p> Signup and view all the answers

Isosbestic point is the point at which two reactants are present in stoichiometric quantities.

<p>False</p> Signup and view all the answers

Dilution of a dichromate solution with water leads to the formation of HCrO4.

<p>False</p> Signup and view all the answers

Oxidation of diphenylamine converts its quinonoid spectrum to the benzenoid spectrum.

<p>False</p> Signup and view all the answers

An increase in temperature may shift ionic equilibrium.

<p>True</p> Signup and view all the answers

A zero absorbance unit corresponds to 0% transmittance.

<p>False</p> Signup and view all the answers

Temperature has a significant effect on the UV spectrum of phenol.

<p>False</p> Signup and view all the answers

Dilution of a solution may lead to less scattering of monochromatic light.

<p>False</p> Signup and view all the answers

Isosbestic point is where all spectra intersect at a specific wavelength (λ) and absorbance is both pH and concentration dependent.

<p>False</p> Signup and view all the answers

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