Physics Lab: Calorimetry and Specific Heat

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Questions and Answers

What is the primary purpose of a calorimeter?

  • To measure the temperature of a substance.
  • To measure the specific heat of a substance.
  • To determine the mass of a substance.
  • To provide an insulated environment for measuring heat transfer during a reaction. (correct)

In calorimetry, what is the relationship between the heat lost by a hotter object and the heat gained by a cooler object in an isolated system?

  • Heat lost is greater than heat gained.
  • Heat lost is equal to heat gained. (correct)
  • Heat lost is less than heat gained.
  • There is no consistent relationship between heat lost and heat gained.

Which of the following is the correct formula to calculate the heat (Q) absorbed or released by a substance?

  • $Q = m \times c / \Delta T$
  • $Q = c / (m \times \Delta T)$
  • $Q = m \times c \times \Delta T$ (correct)
  • $Q = m / (c \times \Delta T)$

What does the 's' stand for in the equation $Q = s \cdot m \cdot \Delta T$?

<p>Specific Heat (D)</p> Signup and view all the answers

If a calorimeter isn't perfectly insulated and some heat is lost to the surroundings, how would it affect the calculation of the specific heat of a substance?

<p>The calculated specific heat would be higher than the actual specific heat. (D)</p> Signup and view all the answers

In the calorimetry experiment, what is the significance of using a weighed amount of a substance?

<p>To accurately calculate the specific heat of the substance. (A)</p> Signup and view all the answers

Why is it important to gently swirl the calorimeter during the experiment?

<p>To ensure a uniform temperature distribution within the water. (B)</p> Signup and view all the answers

What does the change in temperature ($\Delta$T) represent in calorimetry calculations?

<p>The difference between the initial and final temperatures of the substance. (D)</p> Signup and view all the answers

What is the approximate specific heat of pure water?

<p>4.184 J/g°C (C)</p> Signup and view all the answers

Why is it important to avoid dropping the hot substance directly into the calorimeter's beaker or thermometer?

<p>To avoid breaking the beaker or thermometer. (C)</p> Signup and view all the answers

In calorimetry, what is meant by 'thermal equilibrium'?

<p>The state where all objects within the system reach the same temperature. (B)</p> Signup and view all the answers

What is the definition of 'specific heat'?

<p>The amount of energy needed to raise the temperature of one gram of a substance by one degree Celsius. (C)</p> Signup and view all the answers

During the calorimetry experiment involving metal and water, which of the following assumptions is made?

<p>Heat loss to the surroundings is negligible. (A)</p> Signup and view all the answers

In the context of food calorimetry, what does a higher calorie content indicate?

<p>More heat is released when the food is burned. (B)</p> Signup and view all the answers

In food calorimetry, what is being directly measured?

<p>The temperature change of the water. (C)</p> Signup and view all the answers

What unit is used to quantify the amount of heat measured in food calorimetry?

<p>Calories (C)</p> Signup and view all the answers

Why is distilled water preferred over tap water in calorimetry experiments?

<p>Distilled water is free from impurities that could affect the results. (B)</p> Signup and view all the answers

Why is it important to measure the initial temperature of the water in the calorimeter and the hot metal before mixing them?

<p>To calculate the temperature change ($\Delta$T) for both substances. (D)</p> Signup and view all the answers

If the final temperature of the water in a calorimeter is higher than expected, what could be a potential reason?

<p>The calorimeter was not properly insulated. (C)</p> Signup and view all the answers

Consider a scenario where you're using a calorimeter to determine the specific heat of an unknown metal. You notice that the temperature of the water increases rapidly at first, then the rate of increase slows down significantly. What does this observation suggest?

<p>The system is approaching thermal equilibrium. (C)</p> Signup and view all the answers

When using the formula $Q = m imes c imes \Delta T$, what condition must be met for Q to be considered negative?

<p>The temperature change ($\Delta T$) must be negative, indicating a decrease in temperature. (D)</p> Signup and view all the answers

Why are two styrofoam cups used in the calorimeter?

<p>To improve the calorimeter's insulation. (D)</p> Signup and view all the answers

In the food calorimetry experiment, if the cashew nut doesn't completely burn, how would this affect the results?

<p>The calculated calorie content would be lower than the actual value. (B)</p> Signup and view all the answers

If 50.0g of a metal at 85°C is placed in 100.0g of water at 22°C, and the final temperature of the water and metal is 25°C, calculate the heat lost by the metal, given that the specific heat of water is 4.184 J/g°C. (Assume no heat loss to the surroundings.)

<p>1255 J (A)</p> Signup and view all the answers

If 1500 J of energy is added to 100 g of Aluminum, what is the temperature increase if the specific heat of Aluminum is 0.900 J/g°C?

<p>16.7°C (C)</p> Signup and view all the answers

Consider a calorimetry experiment where a 75.0 g metal sample at 90.0°C is placed into 125.0 g of water at 21.0°C. The final temperature of the water and metal is 24.6°C. What is the specific heat of the metal?

<p>0.452 J/g°C (D)</p> Signup and view all the answers

What is the purpose of determining the percent yield in the context of a calorimetry experiment?

<p>To compare experimental specific heat to literature values. (B)</p> Signup and view all the answers

Why is the calorimeter insulated?

<p>To prevent any heat transfer between the contents of the calorimeter and the surroundings. (B)</p> Signup and view all the answers

Why is it important to gently swirl the calorimeter during the procedure?

<p>To ensure a uniform temperature distribution within the water. (B)</p> Signup and view all the answers

What would be the effect of significantly increasing the volume of water used in the calorimeter?

<p>It would decrease the change in temperature. (B)</p> Signup and view all the answers

When determining the calories in food, what is the role of the water that is suspended above the burning food item?

<p>To absorb the heat released by the burning food. (A)</p> Signup and view all the answers

Why must the bulb of the thermometer be submerged in the water during the entire calorimetry process?

<p>To ensure an accurate measurement of the water's temperature. (D)</p> Signup and view all the answers

What is the crucial reason that each team must keep track of their metal sample? (Imagine, another team has the exact same metal, and your team accidentally swaps! What happens?)

<p>To accurately record the correct mass for specific heat calculations. (C)</p> Signup and view all the answers

In the equation Qmetal = (ΔTm)(mm)(sm) = Qwater = (∆Tw)(mw)(sw), what do the subscripts 'm' and 'w' refer to?

<p>Metal and Water (C)</p> Signup and view all the answers

If you are not using absolute values of (\Delta T), what change needs to be made to the equation Qmetal = Q water?

<p>Qmetal = - Q water. (D)</p> Signup and view all the answers

If 1 calorie is equivalent to 4.184 joules, how many calories are there in 1 joule?

<p>0.239 calories (D)</p> Signup and view all the answers

What is 'specific heat capacity' a measure of?

<p>The quantity of heat needed to raise the temperature of one gram of a substance by one degree Celsius. (B)</p> Signup and view all the answers

How does specific heat generally compare between water and other substances?

<p>Water generally has a higher specific heat than most other substances. (D)</p> Signup and view all the answers

In calorimetry, what does the 'Q' represent in the equation $Q = s \cdot m \cdot \Delta T$?

<p>The amount of heat involved. (B)</p> Signup and view all the answers

When a substance cools, how does the value of Q in the equation $Q = s \cdot m \cdot \Delta T$ change?

<p>Q represents the heat that is given off by the sample. (D)</p> Signup and view all the answers

In calorimetry, which of the following is assumed to be true during the heat transfer process?

<p>The calorimeter is perfectly sealed, and no heat is exchanged with the surroundings. (C)</p> Signup and view all the answers

What happens to the thermal energy of two objects that are at different temperatures when they come into contact?

<p>Heat flows from the hotter object to the cooler object until they reach thermal equilibrium. (A)</p> Signup and view all the answers

What does the equation $Q_{metal} = (\Delta T_m)(m_m)(s_m) = Q_{water} = (\Delta T_w)(m_w)(s_w)$ express?

<p>The concept that heat lost by the metal is equal to heat gained by the water in a calorimeter. (B)</p> Signup and view all the answers

If the absolute value of (\Delta T) is not used in the equation Qmetal = Q water, what adjustment must be made?

<p>A negative sign must be introduced to account for the direction of heat flow. (A)</p> Signup and view all the answers

Based on the materials list, what piece of equipment is used to transfer the heated metal into the calorimeter?

<p>Crucible tongs (C)</p> Signup and view all the answers

During the calorimetry procedure, why should the hot plate only have '2 - 2.5' of water in it?

<p>To ensure the water boils quickly. (C)</p> Signup and view all the answers

Why is it important to know which metal sample belongs to your team during the calorimetry experiment?

<p>Because your team might accidentally switch pieces and the different metal may have a different mass/specific heat. (C)</p> Signup and view all the answers

During the calorimetry procedure, how long should the substance be soaking in the boiling water?

<p>At least 3 minutes (B)</p> Signup and view all the answers

In the context of the experiment, what should you do with the water and the substance after using it in the calorimeter?

<p>Discard the water in the calorimeter and repeat the process with a new sample. (D)</p> Signup and view all the answers

When calculating the heat gained by the water in the calorimeter, which equation should you use?

<p>(Q = s \cdot m \cdot \Delta T) (C)</p> Signup and view all the answers

In Part B of the experiment, what is being measured when burning food items?

<p>The chemical energy stored in the food, released as heat and light. (A)</p> Signup and view all the answers

What unit is typically used to quantify the energy released when burning food items in calorimetry?

<p>Calories (A)</p> Signup and view all the answers

What releases more energy when burned: one gram of protein or one gram of fat?

<p>One gram of fat. (A)</p> Signup and view all the answers

In food calorimetry, the amount of energy contained in a food item is approximated by measuring the heat absorbed by what?

<p>Water suspended above the burning food item. (C)</p> Signup and view all the answers

In the food calorimetry experiment, what piece of equipment measures the distilled water?

<p>Graduated cylinder (A)</p> Signup and view all the answers

In the food calorimetry experiment, what is the next step once the cashew catches fire?

<p>Immediately place it inside the calorimeter (A)</p> Signup and view all the answers

Why is it important to measure the initial temperature of the water in the food calorimetry experiment?

<p>In order to calculate (\Delta T) which is necessary for calculating the amount of heat gained. (B)</p> Signup and view all the answers

Which of the following laboratory equipment are utilized during the food calorimetry experiment?

<p>All of the above (D)</p> Signup and view all the answers

In a calorimetry experiment, 55.0g of a metal at 93°C is placed into 100.0g of water at 25°C. The final temperature of the water and metal is 29°C. What is the change in temperature of the metal?

<p>64°C (D)</p> Signup and view all the answers

In a calorimetry experiment, 55.0g of a metal at 93°C is placed into 100.0g of water at 25°C. The final temperature of the water and metal is 29°C. The specific heat capacity of water is 4.18 J/g°C. How much heat was gained by the water?

<p>1672 J (A)</p> Signup and view all the answers

In a calorimetry experiment, 55.0g of a metal at 93°C is placed into 100.0g of water at 25°C. The final temperature of the water and metal is 29°C. The specific heat capacity of water is 4.18 J/g°C. The values have been plugged in for H = m x (sh) x (\Delta T) to find the specific heat of the metal, but the value is now negative! What must be done to the absolute value of the answer, to adhere to the rules taught in the passage?

<p>Take the absolute value of the answer (D)</p> Signup and view all the answers

84.0g of a metal are heated to 99°C in a hot water bath, and then placed in a coffee cup calorimeter containing 60.0g of water at 32°C. The final temperature in the calorimeter is 42°C. What is the change in temperature of the water?

<p>10°C (D)</p> Signup and view all the answers

84.0g of a metal are heated to 99°C in a hot water bath, and then placed in a coffee cup calorimeter containing 60.0g of water at 32°C. The final temperature in the calorimeter is 42°C. How much heat was gained by the water?

<p>2508 J (A)</p> Signup and view all the answers

84.0g of a metal are heated to 99°C in a hot water bath, and then placed in a coffee cup calorimeter containing 60.0g of water at 32°C. The final temperature in the calorimeter is 42°C. How much heat was lost by the metal?

<p>2508 J (B)</p> Signup and view all the answers

84.0g of a metal are heated to 99°C in a hot water bath, and then placed in a coffee cup calorimeter containing 60.0g of water at 32°C. The final temperature in the calorimeter is 42°C. What is the specific heat of the metal?

<p>0.525 J/g°C (C)</p> Signup and view all the answers

A 50.0g metal sample is heated to 95.0°C and placed into 100.0g of water at 22.0°C. If the final temperature of the water and metal is 25.5°C, and the specific heat of water is 4.184 J/g°C, how much heat did the water gain?

<p>1464.4 J (B)</p> Signup and view all the answers

A 50.0g metal sample is heated to 95.0°C and placed into 100.0g of water at 22.0°C. If the final temperature of the water and metal is 25.5°C, and the specific heat of water is 4.184 J/g°C, the heat gained by the water is 1464.4 J. What is the specific heat of the metal?

<p>0.42 J/g°C (B)</p> Signup and view all the answers

A 75.0 g metal sample at 89.0°C is placed into 125.0 g of water at 21.0°C. The final temperature of the water and metal is 24.6°C. Assuming no heat loss to the surroundings and given the specific heat of water is 4.184 J/g°C, determine the amount of heat gained by the water.

<p>1880.4 J (C)</p> Signup and view all the answers

A 75.0 g metal sample at 89.0°C is placed into 125.0 g of water at 21.0°C. The final temperature of the water and metal is 24.6°C. Assuming no heat loss to the surroundings and given the specific heat of water is 4.184 J/g°C, the amount of heat gained by the water is 1880.4 J. What is the specific heat of the metal?

<p>0.35 J/g°C (C)</p> Signup and view all the answers

A student performs a calorimetry experiment to determine the specific heat of an unknown metal. They find that the experimental specific heat is somewhat lower than the literature value for the metal they believe they used. Assuming they performed the experiment carefully, what could explain this discrepancy?

<p>Some of the heat from the metal was lost to the surroundings, the calorimeter, or was otherwise unaccounted for. (D)</p> Signup and view all the answers

A student is performing a calorimetry experiment to determine the specific heat of a metal. They use a setup with a metal container instead of styrofoam cups. How would this affect their results, and why?

<p>The results would likely be inaccurate because the metal container will absorb a significant amount of heat. (B)</p> Signup and view all the answers

A student wants to improve the insulation of their calorimeter setup. Which of the following changes would be MOST effective at reducing heat loss to the surroundings?

<p>Adding a lid to the calorimeter. (A)</p> Signup and view all the answers

During a calorimetry experiment, a student observes that the temperature of the water in the calorimeter rises very slowly after adding the heated metal. What could this indicate?

<p>The calorimeter is not well-insulated, and heat is escaping to the surroundings. (C)</p> Signup and view all the answers

A student performs a calorimetry experiment to determine the specific heat of a metal and forgets to account for the heat absorbed by the calorimeter itself. How will this error affect the calculated specific heat of the metal?

<p>The calculated specific heat of the metal will be higher than the true value. (B)</p> Signup and view all the answers

A student is using a bomb calorimeter to measure the energy content of a new snack food. After combusting the food sample inside the calorimeter, they find that the temperature of the water surrounding the bomb increases by only a very small amount, close to the resolution limit of their thermometer. However, upon inspecting the bomb itself, they note that the food sample has completely combusted (burned to ash). What is the most likely source of experimental error?

<p>The thermometer used was not accurate enough to measure the small temperature change accurately. The error lies in temperature resolution, not precision. (D)</p> Signup and view all the answers

What is the definition of specific heat capacity, according to the provided text?

<p>The amount of heat needed to raise the temperature of one gram of a substance by one Celsius degree. (C)</p> Signup and view all the answers

In calorimetry, what does the symbol 'Q' represent in the equation $Q = s \cdot m \cdot \Delta T$?

<p>The amount of heat absorbed or released. (D)</p> Signup and view all the answers

Why should the bulb of the thermometer be submerged in the water when taking measurements during calorimetry experiment?

<p>To measure the temperature of the water accurately. (A)</p> Signup and view all the answers

What is the purpose of using a hot plate and beaker with boiling water in the calorimetry experiment?

<p>To heat the metal sample to a known temperature. (D)</p> Signup and view all the answers

What is the key assumption made when calculating heat transfer in a calorimeter?

<p>No heat is lost to the surroundings. (D)</p> Signup and view all the answers

What happens to the 'Q' value in the equation $Q = s \cdot m \cdot \Delta T$ when a substance is cooled?

<p>Q becomes negative. (D)</p> Signup and view all the answers

In the calorimetry procedure, after heating the metal sample, what is the next step?

<p>Immediately place it inside the calorimeter. (A)</p> Signup and view all the answers

In calorimetry experiments, distilled water is preferred over tap water. What is the primary reason for this preference?

<p>Tap water contains minerals that can affect the experimental results. (A)</p> Signup and view all the answers

What is the likely consequence of using significantly more water than recommended in the hot water can?

<p>The water may never reach boiling temperature. (B)</p> Signup and view all the answers

What is the purpose of using two nested styrofoam cups in the calorimeter setup?

<p>To provide better insulation and reduce heat loss. (C)</p> Signup and view all the answers

In calorimetry, why is it important to frequently but gently swirl the calorimeter during the experiment?

<p>To ensure uniform temperature distribution within the water. (C)</p> Signup and view all the answers

Why is it important to avoid dropping the heated metal directly into the calorimeter or thermometer?

<p>To prevent damage to the calorimeter or thermometer. (D)</p> Signup and view all the answers

If a team accidentally uses another team's metal sample during the calorimetry experiment, what is the most significant consequence?

<p>The calculated specific heat will be incorrect due to the wrong mass and/or substance. (C)</p> Signup and view all the answers

In the food calorimetry experiment, what does the water suspended above the burning food item measure?

<p>The approximate heat from the burning food. (C)</p> Signup and view all the answers

According to the provided text, which type of food releases far more Calories when burned: fat or protein?

<p>Fat (B)</p> Signup and view all the answers

During the calorimetry experiment, before combining the metal and the water, you measure the mass of the styrofoam cups and the water. Why do you do this?

<p>To calculate the mass of the water that will be used in the $Q = s \cdot m \cdot \Delta T$ equation. (C)</p> Signup and view all the answers

In a calorimetry experiment, what is the final step before repeating with a second sample?

<p>Discard the water and the metal sample. (C)</p> Signup and view all the answers

What key piece of lab equipment must be used to pick up the metal so that the student does not burn themselves?

<p>Tongs (C)</p> Signup and view all the answers

What does thermal equilibrium refer to?

<p>When two objects in contact reach the same temperature. (B)</p> Signup and view all the answers

If a cashew nut in a food calorimetry experiment does not completely burn, how will this affect the determination of its calorie content?

<p>The calculated calorie content will be artificially lower than its actual value. (D)</p> Signup and view all the answers

What is the relationship betwen Joules and Calories?

<p>Joules is the unit for heat that is used in industry; Calories is not (C)</p> Signup and view all the answers

According to the provided text, what should you do with the water and the metal after using it in the calorimetry experiment?

<p>Discard it (A)</p> Signup and view all the answers

A student finds the experimental specific heat of a metal to be higher than its literature value. What error could account for this discrepancy?

<p>The calorimeter absorbed more heat than accounted for. (A)</p> Signup and view all the answers

During a calorimetry experiment, a student observes that it takes a very long time for the water in the calorimeter to reach thermal equilibrium after adding the heated metal. What could this indicate about the experimental setup?

<p>The calorimeter is not well-insulated. (C)</p> Signup and view all the answers

A student measures the energy content of a food item using a bomb calorimeter. However, the temperature of the water and the calorimeter increases only slightly, close to the limit of the resolution of their thermometer. However, the food has completely combusted. What is the most likely reason for this?

<p>The food sample released heat, but the calorimeter was not able to absorb the heat effectively. (A)</p> Signup and view all the answers

In a closed calorimetry experiment, a 50.0 g metal sample at 80.0C is placed into 100.0 g of water at 22.0C. The final temperature of the water and metal is 25.6C. The specific heat capacity of water is 4.184 J/gC. How much energy did the water gain?

<p>1506 J (A)</p> Signup and view all the answers

In a closed calorimetry experiment, a 50.0 g metal sample at 80.0C is placed into 100.0 g of water at 22.0C. The final temperature of the water and metal is 25.6C. The specific heat capacity of water is 4.184 J/gC. The water gained 1506 Joules. Find the specific heat of the metal.

<p>0.54 J/gC (A)</p> Signup and view all the answers

In a calorimetry experiment, 75.0g of a metal at 100C is placed into 100.0g of water at 22C. The final temperature of the water and metal is 30C. The specific heat capacity of water is 4.18 J/gC. What is the mass of the water?

<p>100.0 g (C)</p> Signup and view all the answers

81.0g of a metal are heated to 97C in a hot water bath, and then placed in a coffee cup calorimeter containing 66.0g of water at 32C. The final temperature in the calorimeter is 44C. The specific heat capacity of water is 4.18 J/gC. How much heat did the water gain?

<p>3306.24 J (C)</p> Signup and view all the answers

81.0g of a metal are heated to 97C in a hot water bath, and then placed in a coffee cup calorimeter containing 66.0g of water at 32C. The final temperature in the calorimeter is 44C. The change in temperature of the water is 12C, and the heat gained by the metal is 3306.24 J. What is the specific heat of the metal?

<p>0.75 J/gC (A)</p> Signup and view all the answers

What is the purpose of repeating the calorimetry procedure with a second sample?

<p>To get more accurate results by averaging. (A)</p> Signup and view all the answers

What piece of equipment is used measure 100ml of distilled water?

<p>A graduated cylinder (C)</p> Signup and view all the answers

What should you measure using the analytical balance?

<p>Weight of the cashew nut (D)</p> Signup and view all the answers

What is the next step once the cashew immediately catches fire?

<p>Immediately place it inside the calorimeter (C)</p> Signup and view all the answers

A student heats a metal sample in boiling water before dropping it into a calorimeter, but forgets to record the temperature of the boiling water. How will this affect their calculations?

<p>They need to re-do the whole thing, since the initial temperature of the metal is needed. (B)</p> Signup and view all the answers

A student is using a coffee cup calorimeter to measure the heat of reaction of a chemical process. To improve the accuracy of the experiment, what is the most important modification they should make to the setup?

<p>Add a lid to the coffee cup to minimize heat loss. (A)</p> Signup and view all the answers

What is likely to happen as the water reaches thermal equilibrium with the metal?

<p>The water will stop heating (C)</p> Signup and view all the answers

Why is the mass of samples important?

<p>The mass of samples must be known when calculating results. (D)</p> Signup and view all the answers

When measuring the calories in food, what must immediately happen once the cashew catches fire?

<p>Place the food inside the calorimeter (B)</p> Signup and view all the answers

Why must the thermometer bulb be fully submerged?

<p>So that it correctly measures the temperature of the water. (D)</p> Signup and view all the answers

Which equation presented in the provided document should used when calculating heat gained by water?

<p>All of the above (D)</p> Signup and view all the answers

Flashcards

Specific Heat

The amount of heat needed to raise the temperature of one gram of a substance by one Celsius degree.

Calorimeter

An insulated container used to measure the heat involved in a chemical reaction or physical change.

Heat

The energy transferred between objects or systems due to a temperature difference.

Thermal Equilibrium

The state where two objects in contact have reached the same temperature and there is no net heat flow.

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Heat Transfer Equation

Q = s * m * ΔT, where Q is heat, s is specific heat, m is mass, and ΔT is the change in temperature.

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Calorie

The amount of heat required to raise the temperature of 1 gram of water by 1°C.

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Heat Exchange Principle

The heat lost by a substance equals the heat gained by another substance in a closed system.

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Chemical Energy

Energy stored in the bonds of molecules.

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Heating a Substance

Raise the temperature of a known substance to a target level.

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Calorimeter Purpose

An insulated container used to measure heat transfer, where the heat exchange occurs.

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Heat Calculation

Heat gained or lost can be quantified by the formula: Q = sm∆T

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Achieving Thermal Equilibrium

Heat transfer occurs until thermal equilibrium is reached, balancing temperature.

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Calorimetry Equipment

Goggles, apron, hot plate, thermometer, balance, calorimeter, substances, metal bars, crucible tongs

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Food Calorimetry

A process to approximate the energy in food by burning it and measuring the heat released.

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Crucible Tongs

Used to hold items in place during heating.

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Calorie Definition

The amount of heat needed to raise a mass of water one degree Celsius.

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∆T (Delta T)

The change in temperature of a substance.

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What is a calorimeter?

Device used to measure the heat absorbed or released during a chemical or physical process.

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What is food calorimetry?

To find the calories in food by burning pieces of food to release energy as heat and light.

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What is a calorie?

The amount of heat (energy) required to increase the temperature of 1 gram of water by 1 °C.

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What is heat?

Heat that must be put into a sample is equal to the temperature change, times the grams of sample, times specific heat.

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What is heat exchange?

Amount of heat lost by a metal equals the amount of heat gained by the water: Qmetal = Qwater

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What do calorimeters measure?

Mass and temperature of water, change in water temp, and the specific heat using mass and temp data

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When does heat stop flowing?

When two objects at different temperatures are placed in contact, heat flows from the hotter to the cooler object until they reach the same temperature.

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Study Notes

  • The experiment is Physics Laboratory Activity #16.
  • The experiment is on the Calorimeter

Objectives

  • Measure the mass and temperature of water in a calorimeter
  • Heat a substance of known mass to a specific temperature
  • Determine the change in water temperature caused by a hot substance
  • Calculate the specific heat of a substance using mass and temperature data
  • Find the calories in food

Theory

  • The amount of heat needed to raise the temperature of one gram of a substance by one Celsius degree is called the “specific heat” or "specific heat capacity”
  • This amount for pure water is one calorie, which is equivalent to 4.184 joules
  • Almost all other substances have lower specific heats than water
  • Specific heat applies to different sized samples and temperature changes
  • Heat that must be put into a sample = (temperature change) × (grams sample) × (specific heat)
  • Q = s•m•∆T, where Q is heat, s is specific heat, m is mass, and ∆T is temperature change
  • The equation can calculate the heat involved if the other three values are known
  • When a substance cools, the term Q represents heat given off by the sample
  • The same equation is used to calculate specific heat if the other three terms are known

Calorimeter

  • An insulated container called a calorimeter can measure the heat taken from a hot sample into cooler surrounding material, like water
  • A weighed substance is heated, and then poured quickly into the calorimeter that contains a measured amount of water at a known temperature
  • Heat flows from the hot substance into cooler water, until both temperatures are equal
  • The final temperature will be between the initial temperatures of the two substances
  • When objects at different temperatures touch, heat flows from the hotter to cooler object until they reach thermal equilibrium
  • The calories (or joules) lost by the hot object will be the same amount of calories gained by the cold object (Qlost = Qgained)
  • In the experiment, the heat lost by a metal sample is equal to the heat gained by the calorimeter water
  • This assumes no heat is lost to the surroundings
  • The equation: Heat lost by the metal = heat gained by the water, or Qmetal = (ΔTm)(mm)(sm) = Qwater = (∆Tw)(mw)(sw) where m and w are metal and water subscripts
  • In this equation, both ∆T values are known because initial and final temperatures are measured
  • All water values will be known, and all but one metal value, so you can solve for the "unknown" specific heat of the metal
  • Note: the above equation assumes you will use the absolute value of ∆T, if you do not, then Qmetal = - Q water

Materials

  • Goggles and apron
  • Hot plate or burner with tripod stand
  • 1000 mL beaker substances
  • Metal bars
  • Thermometer
  • Balance
  • Calorimeter (2 cups with lid)
  • Crucible tongs

Procedure

  • Turn hot plate on to #8, should only have about 2”-2.5” of water, notify instructor if water level drops below 1”
  • Obtain a sample of metal or substance, record the type and mass in the data table
  • Carefully place the substance into the boiling water with tongs
  • The thermometer in the beaker measures the boiling water temperature, and after 3 minutes this will be the initial temperature of the substance,
  • Use caution to not tip can over nor burn self
  • Find the exact mass of the styrofoam cups with lid and record in data table, use two cups for better insulation
  • Fill the cup one-fourth full of tap water and determine the mass of cups and water to find mass of the water
  • Place the thermometer in the calorimeter and measure the water's initial temperature when the level stops moving, keep the thermometer in the water
  • Add the sample substance to the water in the calorimeter and quickly place the lid on, making sure the thermometer sticks out of the hole in the lid
  • Occasionally swirl the calorimeter to keep the water at an even temperature but don't break the thermometer
  • Heat from the hot substance is moving into the water until both are the same temperature
  • When the thermometer stops rising, record the final temperature of the system, remembering the bulb must be in the water
  • Remove thermometer and substance, and discard the water, and repeat with a second sample

Calculations

  • Calculate the heat gained by the water (lost by the substance) using the equation in the introduction
  • Qwater = mwater x (Tf-Ti)water X Cp water
  • Calculate the specific heat of the substance using the equation in the introduction and the previous Q results
  • Qsubst = msubst X (Ti - Tf)subst x Cp subst
  • Find the percent error
  • Compare the experimental and literature values

Experiment Part B

  • Burning food releases the chemical energy stored in molecular bonds as heat and light
  • Heat is measured in Calories (or Joules sometimes)
  • Foods high in calories give off more heat
  • One gram of protein releases fewer Calories than one gram of fat
  • A calorie is the amount of heat (energy) required to increase the temperature of 1 gram of water by 1 °C
  • This is the basis of calorimetry, in which you use the method to approximate the amount of energy in foods
  • The heat from the reaction will be absorbed by water which is suspended above the food item, and this method measures heat given off by the food

Materials for Food Experiment

  • Graduated cylinder
  • Calorimeter
  • Thermometer
  • Alcohol lamp
  • Lighter
  • Crucible tong
  • Cashew nuts
  • Popcorn

Food Experiment Procedure

  • Hypothesize which food item has more calories
  • Determine the weight of the cashew nut using an analytical balance
  • Measure 100ml of distilled water and pour it in a small metal can using a graduated cylinder
  • Measure the initial temperature of the water and record
  • Place the cashew on the rod and light it
  • Place the cashew in the calorimeter as soon as it catches fire
  • Allow the nuts to burn
  • Carefully remove the cashew from the can to cool once it is done burning
  • Measure the water's temperature using the thermometer after stirring
  • Determine the calories of the food by weighing the cashew nuts
  • Repeat the experiment with popcorn

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