Physical Properties of Aldehydes, Ketones, and Carboxylic Acids

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What is the main reason for the higher boiling points of aldehydes compared to corresponding alkanes?

Dipole-dipole forces between molecules

Which of the following is a general trend for the density of ketones?

Ketones are generally more dense than water

What is a characteristic of the odor of many aldehydes?

Often unpleasant

Why do carboxylic acids have high boiling points?

<p>Due to strong hydrogen bonding between molecules</p> Signup and view all the answers

What is a general trend for the solubility of ketones in water?

<p>Ketones are less soluble in water than corresponding alcohols</p> Signup and view all the answers

Which of the following is a characteristic of many carboxylic acids?

<p>Unpleasant, pungent odor</p> Signup and view all the answers

What is a general trend for the density of aldehydes?

<p>Aldehydes are generally more dense than water</p> Signup and view all the answers

Why do ketones have lower boiling points than aldehydes?

<p>Due to weaker dipole-dipole forces</p> Signup and view all the answers

Study Notes

Physical Properties of Aldehydes, Ketones, and Carboxylic Acids

Aldehydes

  • Boiling Point: Aldehydes have higher boiling points than corresponding alkanes due to dipole-dipole forces between molecules.
  • Solubility: Soluble in organic solvents and water, but less soluble in water than corresponding alcohols.
  • Density: Generally, aldehydes are denser than water.
  • Odor: Many aldehydes have characteristic, often unpleasant, odors.

Ketones

  • Boiling Point: Ketones have higher boiling points than corresponding alkanes, but lower than aldehydes, due to weaker dipole-dipole forces.
  • Solubility: Soluble in organic solvents and water, but less soluble in water than corresponding alcohols.
  • Density: Generally, ketones are denser than water.
  • Odor: Many ketones have characteristic, sweet or fruity, odors.

Carboxylic Acids

  • Boiling Point: Carboxylic acids have high boiling points due to strong hydrogen bonding between molecules.
  • Solubility: Soluble in water and organic solvents, but less soluble in water than corresponding alcohols.
  • Density: Generally, carboxylic acids are denser than water.
  • Odor: Many carboxylic acids have unpleasant, pungent, odors.

Note: These physical properties are general trends and may vary depending on the specific compound.

Aldehydes

  • Higher boiling points than corresponding alkanes due to dipole-dipole forces between molecules.
  • Soluble in organic solvents and water, but less soluble in water than corresponding alcohols.
  • Generally denser than water.
  • Many have characteristic, often unpleasant, odors.

Ketones

  • Higher boiling points than corresponding alkanes, but lower than aldehydes, due to weaker dipole-dipole forces.
  • Soluble in organic solvents and water, but less soluble in water than corresponding alcohols.
  • Generally denser than water.
  • Many have characteristic, sweet or fruity, odors.

Carboxylic Acids

  • High boiling points due to strong hydrogen bonding between molecules.
  • Soluble in water and organic solvents, but less soluble in water than corresponding alcohols.
  • Generally denser than water.
  • Many have unpleasant, pungent, odors.

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