Phenoxide Formation and Acidity

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Questions and Answers

What is the special name given to methyl phenols?

  • Cresols (correct)
  • Hydroxy compounds
  • Eugenol
  • Tyrosine

How can ortho and para isomers of phenols be separated?

  • By sublimation
  • By steam distillation (correct)
  • By fractional distillation
  • By filtration

Which type of bonding in ortho-substituted phenols reduces water solubility and increases volatility?

  • Intramolecular hydrogen bonding (correct)
  • Ionic bonding
  • Van der Waals bonding
  • Covalent bonding

In phenol synthesis, what are diazonium salts used for?

<p>To form phenols (C)</p> Signup and view all the answers

Which reaction of phenols involves the introduction of a nitro group?

<p>Nitration (B)</p> Signup and view all the answers

What is the main effect of substituent groups on the acid strength of phenols?

<p>Increase acid strength (D)</p> Signup and view all the answers

How do electron withdrawing groups affect the negative charge in phenolate?

<p>Decrease the negative charge (D)</p> Signup and view all the answers

Which type of groups shift the equilibrium of phenolate farther to the left, making it a weaker acid?

<p>Electron donating groups (A)</p> Signup and view all the answers

In the context of phenols, why is it possible to generate phenoxide in situ using NaOH?

<p>Phenols are more acidic than water (D)</p> Signup and view all the answers

Which type of group serves as a powerful activating group in Electrophilic Aromatic Substitution (EAS) and is an ortho/para director?

<p>Acylation group (C)</p> Signup and view all the answers

What reaction occurs when allyl phenyl ether is heated to 200°C?

<p>Claisen rearrangement (C)</p> Signup and view all the answers

What is the product formed from the Claisen rearrangement of allyl phenyl ether at 200°C?

<p>o-Allyl phenol (D)</p> Signup and view all the answers

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