Phenol Reactions and Synthesis

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Questions and Answers

What is the main reason phenols are slightly acidic in water?

  • As a result of the resonance stabilization of the phenoxide ion (correct)
  • Because of the hydroxyl group's ability to donate a proton
  • Due to the electron-withdrawing effect of the aromatic ring
  • Due to the presence of a benzenediol functional group

Which of the following is NOT a characteristic of phenols?

  • They are white solids that are easily oxidized by atmospheric air
  • They are highly electrophilic and readily undergo nitration
  • They are hygroscopic and soluble in water
  • They are non-polar and insoluble in water (correct)

What is the product of the reaction between a phenol and aqueous sodium hydroxide?

  • ArONa(s) + H2O
  • ArONa(aq) + H2O (correct)
  • ArOH(aq) + NaOH(aq)
  • ArOH(aq) + NaOH(aq) → ArONa(s) + H2O

Which of the following is an example of a monohydric phenol?

<p>C6H5OH (C)</p> Signup and view all the answers

Which of the following is a medical application of phenols?

<p>Antiseptic and disinfectant properties (B)</p> Signup and view all the answers

Which of the following is NOT a type of polyhydric phenol?

<p>Monohydric phenol (C)</p> Signup and view all the answers

What is the primary mechanism of the Williamson synthesis?

<p>Nucleophilic substitution (C)</p> Signup and view all the answers

What is the product of the reaction of phenol with dilute HNO3 and HCl at 50°C?

<p>p-Nitrophenol (D)</p> Signup and view all the answers

What is the primary use of phenolic compounds in medicine?

<p>As keratolytics and antioxidants (A)</p> Signup and view all the answers

What is the product of the oxidation of phenol?

<p>p-Benzoquinone (C)</p> Signup and view all the answers

What is the purpose of the nitration reaction in the synthesis of picric acid?

<p>To introduce a nitro group onto a phenol (A)</p> Signup and view all the answers

What is the significance of the color change in the detection of phenols?

<p>It indicates the presence of a phenol (A)</p> Signup and view all the answers

What is the primary reaction that occurs when phenol reacts with sodium hydroxide?

<p>Formation of salts (B)</p> Signup and view all the answers

What is the product of the reaction between sodium benzene sulfonate and solid NaOH at 300°C?

<p>Sodium phenoxide (D)</p> Signup and view all the answers

What is the reaction type that occurs when phenol reacts with FeCl3?

<p>Complex formation (D)</p> Signup and view all the answers

Which of the following is a type of reaction that occurs with phenol?

<p>Reaction of O-H bond (B)</p> Signup and view all the answers

What is the primary use of coal tar?

<p>Production of phenol (C)</p> Signup and view all the answers

What is the mechanism of the reaction of cumene to produce phenol?

<p>Air oxidation (D)</p> Signup and view all the answers

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