Pharmaceutical Organic Chemistry II Exam 2020
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Questions and Answers

Which of the following correctly defines Huckel's rule?

  • An aromatic compound must have 4n + 2 π electrons. (correct)
  • An aromatic compound can have any number of π electrons.
  • A compound's aromaticity is determined by its molecular weight.
  • A non-aromatic compound must have 2n π electrons.
  • What is the primary purpose of saponification in organic chemistry?

  • To neutralize acids in an organic reaction.
  • To esterify fatty acids.
  • To convert glycerides into alcohols.
  • To hydrolyze fats and oils into glycerol and fatty acids. (correct)
  • Which statement about the rancidity of oils is accurate?

  • Rancidity has no impact on the flavor of oils.
  • Rancidity occurs only in solid fats.
  • Rancidity is an oxidation process that can be prevented through refrigeration. (correct)
  • Rancidity is caused solely by microbial activity.
  • What structural feature is common to an aromatic compound such as anthracene?

    <p>Conjugated pi bonds arranged in a ring.</p> Signup and view all the answers

    Which is a characteristic reaction of benzoic acid?

    <p>Reduction to form benzyl alcohol.</p> Signup and view all the answers

    In the preparation of 1-naphthol from naphthalene, which reagent is primarily used?

    <p>Bromine in an aqueous solution.</p> Signup and view all the answers

    Acid and iodine values are both measures of what property in organic compounds?

    <p>Unsaturation level.</p> Signup and view all the answers

    What is the major difference between fats and oils in terms of their chemical structure?

    <p>Oils are liquid at room temperature while fats are solid.</p> Signup and view all the answers

    Study Notes

    Pharmaceutical Organic Chemistry II Exam - January 2020

    • Instructions: Students must not write anything other than their roll number on the exam paper. Any other writing constitutes cheating.
    • Exam Structure: The exam contains three sections (A, B, and C) and is divided into multiple question types.
    • Section A: Contains 10 very short answer questions (5 marks each). All questions in this section must be answered.
    • Section B: Contains 3 descriptive questions (10 marks each), students must choose 2 to answer.
    • Section C: Contains 7 short answer questions (5 marks each). Students must answer four or three of these (depending on the question numbering in the exam paper).

    Section A - Very Short Answer Questions

    • Example topics/questions:
      • Resonance in Benzene
      • Saponification value
      • Rancidity of oils
      • Saccharin's structure and use
      • Ester value
      • DDT's structure and uses
      • Huckel's rule
      • Anthracene structure and uses
      • Triphenylmethane structure and uses
      • Reichert-Meissl value

    Section B - Long Answer Questions

    • Topics/questions:
      • Mechanisms of electrophilic substitution reactions in benzene (e.g., sulfonation, halogenation).
      • Properties of fats and oils and their differences from waxes. Chemical reaction examples.
      • Synthesis of compounds from naphthalene (e.g., 1-Fluoronaphthalene, 1-Naphthol, 1-Cyclonaphthalene, 1-Chloro-2-naphthylamine, 1-Iodonaphthalene).

    Section C - Short Answer Questions

    • Topics/questions:
      • Converting benzene to anthracene
      • Phenol, cresol, and resorcinol structures and uses
      • Basicity of amines
      • Diazotization and synthetic uses of diazonium salts
      • Chemical reactions of benzoic acid
      • Acid and iodine value
      • Baeyer's strain theory and limitations
      • Structures and uses of BHC, chloramine, and diphenylmethane
      • Sachse-Mohr theory

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    Description

    Prepare for your January 2020 exam in Pharmaceutical Organic Chemistry II with this comprehensive quiz. It includes various question types across three sections, covering essential topics such as resonance, saponification, and the structure of organic compounds. Test your knowledge and readiness for the exam with these focused questions.

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