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Questions and Answers
The ______ reactions of alkylhalides are classified into two types, SN 1 and SN 2.
nucleophilic
The ______ condensation reaction is a type of organic reaction in which an aldehyde reacts with a ketone to form a β-hydroxy aldehyde.
crossed aldol
The ______ reaction is an organic reaction in which an aldehyde is converted into an alkoxide.
benzoin
The ______ reactions are a type of elimination reaction in which an alkylhalide is converted into an alkene.
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The ______ of amines is a measure of their ability to accept a proton.
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The ______ reaction is a type of organic reaction in which an alkene reacts with an electrophile to form a product.
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The ______ reaction is a type of organic reaction in which an alkene reacts with a halogen to form a product.
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The ______ rearrangement is a type of organic reaction in which an alkyl group migrates from one position to another.
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Study Notes
Pharmaceutical Organic Chemistry I
Reactions of Alkylhalides
- SN1 and SN2 reactions of alkylhalides involve kinetics, order of reactivity, and stereochemistry
- Factors affecting SN1 and SN2 reactions include solvents, temperatures, and nucleophiles
Named Reactions
- Crossed aldol condensation: a reaction involving the combination of two different aldehydes or ketones
- Benzoin condensation: a reaction involving the condensation of two aldehydes to form a benzoin
- Crossed cannizaro reaction: a reaction involving the oxidation and reduction of two different aldehydes
- Aldol condensation: a reaction involving the combination of two aldehydes or ketones
Elimination Reactions
- E1 and E2 reactions involve the elimination of leaving groups to form alkenes
- Factors affecting E1 and E2 reactions include solvents, temperatures, and nucleophiles
Amines
- Basicity of amines: the ability of amines to accept protons
- Qualitative tests for amines include the formation of ammonium salts and the use of indicators
Organic Compounds
- Ethylchloride: a colorless liquid used as a solvent and anesthetic
- Chloroform: a colorless liquid used as a solvent and anesthetic
- Methyl alcohol: a colorless liquid used as a fuel and solvent
- Glycerol: a colorless liquid used as a sweetener and humectant
- Propylene glycol: a colorless liquid used as a solvent and humectant
Electrophilic Addition Reactions
- Electrophilic addition reactions of alkenes involve the addition of electrophiles to form carbocations
- Ozonolysis: a reaction involving the cleavage of alkenes using ozone
Structure and IUPAC Nomenclature
- Structure and IUPAC names of organic compounds of each class
Halogenation of Alkanes
- Halogenation of alkanes involves the substitution of halogens for hydrogen atoms
- Paraffins: saturated hydrocarbons used as fuels and lubricants
Free Radical Addition Reactions
- Free radical addition reactions of alkenes involve the addition of free radicals to form new bonds
- Anti-Markovnikov's orientation: a rule stating that the free radical adds to the less substituted carbon atom
Allylic Rearrangement
- Allylic rearrangement: a reaction involving the rearrangement of allylic systems
- Stability of conjugated dienes: conjugated dienes are stable due to resonance stabilization
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Description
Test your knowledge of pharmaceutical organic chemistry with this quiz, covering topics from the second semester of the B.Pharm degree examination.
