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CH 17: pH and the pH scale

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52 Questions

What does the pH scale range from?

0 to 14

What does a pH value less than 7 indicate?

Acidity

What is the formula used to calculate the pH of a solution?

$pH = -log[H_3O^+]$

What is the value of the ion product constant for water (Kw) at 25°C?

1 x 10^-14

What do the acid dissociation constant (Ka) and base dissociation constant (Kb) quantify?

The strength of acids and bases

What is the relationship between the strength of an acid and its Ka value?

Stronger acids have higher Ka values

What is the relationship between the strength of a base and its Kb value?

Stronger bases have higher Kb values

What is the pH of a 0.1 M solution of HCl (a strong acid)?

pH = 1

What is the purpose of the pH scale?

To specify the acidity or alkalinity of a solution

How is pH defined in terms of hydronium ion activity?

pH = -log[H_3O^+]

What is the equilibrium constant expression (Kc) for the auto-ionisation of water?

[H3O+][OH-]

How does a high Ka value for an acid correlate with its strength?

It signifies a strong acid.

What is the relationship between the equilibrium constants Ka and Kb for a conjugate acid-base pair?

Ka x Kb = Kw

In which pH range would a solution be classified as basic?

pH > 7

Why are indicators used in titrations?

To determine the equivalence point by changing color based on pH

What does Kw represent in relation to water's auto-ionisation?

Equilibrium constant

How are pH calculations different for weak acids compared to strong acids?

Weak acids require setting up an equilibrium expression using Ka values

'Deviation from the normal blood pH of 7.4 can indicate health issues.' Which of the following pH ranges would be indicative of potential health problems?

pH 5.5 - 6.0

If a solution has a pOH value of 2, what is its hydroxide ion concentration?

0.01 M

What does a high Ka value indicate for acids?

Strong acid that ionizes significantly

In the Law of Mass Action, what does the equilibrium constant (Kc) express?

Concentration of products at equilibrium

For a conjugate acid-base pair, what is the relationship between Ka and Kb?

Ka × Kb = Kw

How are pH calculations for weak acids and bases different from strong ones?

Equilibrium expressions with Ka or Kb are used for weak acids and bases

What pH range would be classified as acidic based on the pH scale?

pH < 7

Why is understanding the pH scale crucial in various fields like medicine and environmental science?

To assess human health and ecological impacts

How do indicators contribute to titrations in determining the equivalence point?

By changing color based on the pH of the solution

What does a pH value of 3 indicate?

The solution is acidic

Which ion product constant represents the product of H₃O⁺ and OH⁻ ions in pure water?

Kw

What does a pOH value of 11 indicate about a solution?

The solution is basic

How are the molar concentration and pH related for strong acids?

They have a logarithmic relationship

Which constant quantifies the strength of a base?

Ka

If the pH of a solution changes from 6 to 3, how does this impact its acidity?

It becomes more acidic

What is the primary factor that determines whether a solution is acidic or basic?

[H3O+] concentration

What is the primary factor that determines the acidity or basicity of a solution according to the pH scale?

The concentration of hydronium ions (H₃O⁺)

Which of the following is the correct formula to calculate the pH of a solution?

pH = -log[H₃O⁺]

What does the ion product constant for water (Kw) represent at 25°C?

The product of the molar concentrations of H₃O⁺ and OH⁻ ions in pure water

How are the acid dissociation constant (Ka) and base dissociation constant (Kb) related for a conjugate acid-base pair?

Ka and Kb are inversely proportional

What does a higher Ka value indicate about the strength of an acid?

The acid is stronger

What is the pH of a 0.1 M solution of the strong acid HCl?

pH = 1

What is the relationship between the strength of a base and its Kb value?

Stronger bases have higher Kb values

If the pH of a solution changes from 6 to 3, how does this impact the acidity of the solution?

The solution becomes more acidic

What is the relationship between the equilibrium constants Ka and Kb for a conjugate acid-base pair?

Ka and Kb are inversely proportional

What does a pH value of 3 indicate about the acidity of a solution?

The solution is highly acidic

What is the primary purpose of the equilibrium constant (Kc) in the Law of Mass Action as it applies to chemical reactions?

To express the relationship between the concentrations of reactants and products at equilibrium

How do the Ka and Kb values of a conjugate acid-base pair relate to each other?

The product of Ka and Kb is equal to the equilibrium constant (Kc)

Which of the following best describes the relationship between the pH of a solution and the concentration of hydronium ions (HO)?

pH is inversely proportional to the concentration of HO ions

How do the Ka and Kb values of an acid and its conjugate base relate to their relative strengths?

A high Ka value indicates a strong acid, while a high Kb value indicates a strong base

What is the significance of the ion product constant (Kw) for water's auto-ionisation?

Kw represents the equilibrium constant for the dissociation of water into hydronium and hydroxide ions

Why are indicators used in titrations to determine the equivalence point?

Indicators change color based on the pH of the solution, allowing the equivalence point to be identified

How do the pH calculations differ between strong acids/bases and weak acids/bases?

For strong acids/bases, the pH calculation is straightforward, but for weak acids/bases it involves setting up an equilibrium expression using Ka or Kb

What is the relationship between the pH of a solution and its acidity?

As the pH of a solution decreases, its acidity increases

How does the pH of natural water bodies and biological fluids impact their health and functioning?

The pH of natural water bodies and biological fluids is crucial for the health of ecosystems and organisms, as deviations from the optimal range can lead to adverse effects

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