Podcast
Questions and Answers
What is the typical range of sulfur content found in most crude oils?
What is the typical range of sulfur content found in most crude oils?
- Less than 0.05 wt%
- 5-10 wt%
- More than 10 wt%
- 1-4 wt% (correct)
Which type of hydrocarbons are characterized by carbon-carbon triple bonds?
Which type of hydrocarbons are characterized by carbon-carbon triple bonds?
- Alkenes
- Alkanes
- Alkynes (correct)
- Naphthenes
Which of the following is a key function of a desalter unit in crude oil refining?
Which of the following is a key function of a desalter unit in crude oil refining?
- Increasing the sulfur content of the crude oil
- Removing salt and other impurities from the crude oil (correct)
- Adding valuable minerals to the crude oil
- Converting heavy hydrocarbons into lighter ones
At what temperature range should crude oil be maintained during the heating stage of desalting to ensure effective water-oil separation?
At what temperature range should crude oil be maintained during the heating stage of desalting to ensure effective water-oil separation?
In a desalter unit, what is the role of the electric field applied between two electrodes?
In a desalter unit, what is the role of the electric field applied between two electrodes?
What is the primary operational difference between atmospheric distillation and vacuum distillation?
What is the primary operational difference between atmospheric distillation and vacuum distillation?
What is the main purpose of Solvent Deasphalting (SDA) in petroleum refining?
What is the main purpose of Solvent Deasphalting (SDA) in petroleum refining?
Which solvent is commonly used in the solvent deasphalting process to dissolve oil and precipitate asphaltene?
Which solvent is commonly used in the solvent deasphalting process to dissolve oil and precipitate asphaltene?
In the context of solvent extraction, what is the 'lube oil stock' treated with?
In the context of solvent extraction, what is the 'lube oil stock' treated with?
What is the primary role of N-methyl pyrrolidone (NMP) in solvent extraction processes?
What is the primary role of N-methyl pyrrolidone (NMP) in solvent extraction processes?
Which solvent is typically used in solvent dewaxing to dissolve raffinate?
Which solvent is typically used in solvent dewaxing to dissolve raffinate?
What is the primary purpose of chilling the solution in the solvent dewaxing process?
What is the primary purpose of chilling the solution in the solvent dewaxing process?
Which of the following parameters influences the effectiveness of water-oil separation during the desalting process?
Which of the following parameters influences the effectiveness of water-oil separation during the desalting process?
In crude oil refining, what is the term for the process where smaller water droplets combine to for larger drops for easier separation?
In crude oil refining, what is the term for the process where smaller water droplets combine to for larger drops for easier separation?
If a crude oil sample is measured to have a salt content of 3 PTB (pounds per thousand barrels) after desalting, what would be the approximate equivalent in kg/1000 m³?
If a crude oil sample is measured to have a salt content of 3 PTB (pounds per thousand barrels) after desalting, what would be the approximate equivalent in kg/1000 m³?
Which of the following outcomes is specifically associated with poor desalting in a crude oil refinery?
Which of the following outcomes is specifically associated with poor desalting in a crude oil refinery?
If a refinery wants to process heavier crude oil fractions, which distillation method would be more suitable?
If a refinery wants to process heavier crude oil fractions, which distillation method would be more suitable?
What is the key characteristic of 'deasphalted oil (DAO)' produced in the solvent deasphalting process?
What is the key characteristic of 'deasphalted oil (DAO)' produced in the solvent deasphalting process?
What is the name of the well-known solvent deasphalting process known for energy efficiency?
What is the name of the well-known solvent deasphalting process known for energy efficiency?
In the context of solvent extraction, if the solvent removes aromatic components from the lube oil stock, what is the remaining oil phase called?
In the context of solvent extraction, if the solvent removes aromatic components from the lube oil stock, what is the remaining oil phase called?
Which of the following is the correct general formula for paraffin hydrocarbons (alkanes)?
Which of the following is the correct general formula for paraffin hydrocarbons (alkanes)?
Which term accurately describes hydrocarbons characterized by branched structures that exhibit structural isomerization?
Which term accurately describes hydrocarbons characterized by branched structures that exhibit structural isomerization?
Which of the following crude oil characteristics would be LEAST desirable for efficient petroleum refining?
Which of the following crude oil characteristics would be LEAST desirable for efficient petroleum refining?
Which process is positioned at the 'front-end' of a crude oil refinery, functioning as the initial separation step?
Which process is positioned at the 'front-end' of a crude oil refinery, functioning as the initial separation step?
A refinery is experiencing high levels of corrosion in its overhead equipment. Which of the following is the MOST likely cause?
A refinery is experiencing high levels of corrosion in its overhead equipment. Which of the following is the MOST likely cause?
Which of the following products is typically produced using catalytic cracking units after solvent deasphalting is complete?
Which of the following products is typically produced using catalytic cracking units after solvent deasphalting is complete?
A refinery aims to maximize the output of high-quality lubricating oils. Which of the following processing sequences is MOST appropriate?
A refinery aims to maximize the output of high-quality lubricating oils. Which of the following processing sequences is MOST appropriate?
Which type of crude oil would generally command a higher price due to its desirable properties for refining?
Which type of crude oil would generally command a higher price due to its desirable properties for refining?
A refinery needs to reduce the viscosity of heavy residual oils. Which of the following processes would be MOST suitable?
A refinery needs to reduce the viscosity of heavy residual oils. Which of the following processes would be MOST suitable?
Which of the following compounds found in crude oil can act as a poison to catalysts used in catalytic cracking units?
Which of the following compounds found in crude oil can act as a poison to catalysts used in catalytic cracking units?
Which product is created during solvent dewaxing?
Which product is created during solvent dewaxing?
Which of the following parameters is LEAST relevant when choosing between atmospheric and vacuum distillation?
Which of the following parameters is LEAST relevant when choosing between atmospheric and vacuum distillation?
In the context of crude oil refining, what primarily determines whether a specific hydrocarbon will be found in the extract phase or the raffinate phase?
In the context of crude oil refining, what primarily determines whether a specific hydrocarbon will be found in the extract phase or the raffinate phase?
At what operational condition is more distillates extracted in a Vacuum Distillation Unit?
At what operational condition is more distillates extracted in a Vacuum Distillation Unit?
How does the continuous phase manifest in an oil rig?
How does the continuous phase manifest in an oil rig?
The desalter in a refinery is not operating correctly, as the PTB is to high. As an operator , what are the best series of actions?
The desalter in a refinery is not operating correctly, as the PTB is to high. As an operator , what are the best series of actions?
What is the trade name of the solvent used to dewax?
What is the trade name of the solvent used to dewax?
Flashcards
Block flow diagram
Block flow diagram
Diagram showing stages of a modern oil refinery.
Feedstock
Feedstock
Raw, unprocessed petroleum as the initial input.
Products from Crude Oil
Products from Crude Oil
Various fuels, lubricants, and materials created from crude oil.
Physical & Chemical Processes
Physical & Chemical Processes
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Desalter Unit
Desalter Unit
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Crude Oil Desalting
Crude Oil Desalting
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Atmospheric Distillation
Atmospheric Distillation
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Vacuum Distillation
Vacuum Distillation
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Solvent Deasphalting
Solvent Deasphalting
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Solvent Extraction
Solvent Extraction
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Solvent Dewaxing
Solvent Dewaxing
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Paraffins (Alkanes)
Paraffins (Alkanes)
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Isoparaffins (Isoalkanes)
Isoparaffins (Isoalkanes)
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Olefins (Alkenes)
Olefins (Alkenes)
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Naphthenes (Cycloalkanes)
Naphthenes (Cycloalkanes)
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Aromatics
Aromatics
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Sulfur content
Sulfur content
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Oxygen content
Oxygen content
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Nitrogen compounds
Nitrogen compounds
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Metallic compounds
Metallic compounds
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LPG
LPG
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Desalter Unit
Desalter Unit
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Water washing
Water washing
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Heating
Heating
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Coalescence
Coalescence
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Distillation
Distillation
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Crude Distillation Unit (CDU)
Crude Distillation Unit (CDU)
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Atmospheric residue
Atmospheric residue
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Vacuum Distillation
Vacuum Distillation
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Vacuum Unit Distillates
Vacuum Unit Distillates
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Solvent Deasphalting
Solvent Deasphalting
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ROSE process
ROSE process
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Lube oil stock
Lube oil stock
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Raffinate
Raffinate
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Study Notes
Learning Outcomes
- Lesson aims: Recognize refinery block flow, describe feedstock/products, identify separation/conversion, explain desalting, differentiate distillation, describe solvent processes.
Feedstock: Crude Oil
- Is the raw material for petroleum refining.
Hydrocarbons
- Paraffins (alkanes) are saturated compounds with the formula CnH2n+2.
- Isoparaffins (isoalkanes) are branched hydrocarbons exhibiting structural isomerization.
- Olefins (alkenes) are unsaturated hydrocarbons containing carbon-carbon double bonds, known as biolefins or alkynes when containing carbon-carbon triple bonds.
- Naphthenes (cycloalkanes) are saturated hydrocarbons with at least one carbon atom ring.
- Aromatics are unsaturated cyclic compounds with one or more benzene rings.
Other Compounds
- The sulfur content in crude oils typically ranges from 1–4 wt%, but varies from less than 0.05 to more than 10 wt%.
- The oxygen content in crude oil is usually less than 2 wt%.
- Crude oils have low nitrogen compound amounts.
- Metallic compounds, like Nickel (Ni) and Vanadium (V), are present in tiny amounts in all crude oil types.
Crude Oil
- Origins determine physical and chemical traits.
Products of Crude Oil Refining
- Liquified petroleum gas
- Gasoline
- Diesel
- Kerosene
- Jet fuel
- Lube oil
- Asphalt
- Petroleum Coke
Crude Oil Refining
- Physical separation and chemical conversion are the two main types of processes
Desalting
- Crude oil contains brine as emulsified water droplets.
- Salt content can reach 2000 pounds per thousand barrels (PTB), lowered to 5.7-14.3 kg/1000 m3 (2-5 PTB) post-treatment.
Desalting Issues
- Poor desalting effects: fouling from salt deposits, corrosion, and catalyst poisoning in cracking units.
Desalter Unit Operation
- Water Washing: mixes incoming crude oil with water to dissolve salt crystals and distribute salts into the water, creating tiny droplets.
- Heating: maintains crude oil temperature between 48.9–54.4°C because water-oil separation is affected by oil viscosity and density.
- Coalescence: encourages tiny water droplets (1-10 mm) to merge using an electrostatic field between two electrodes.
- Settling: Coalescence produces larger drops that can be settled by gravity.
Distillation
- Crude distillation unit (CDU) is at the refinery's front-end which is also called a topping unit, or atmospheric distillation unit.
Vacuum Distillation
- Vacuum distillation extracts more distillates from atmospheric residue and uses vacuum distillation units.
- Vacuum unit distillates: light vacuum gas oil (LVGO) and heavy vacuum gas oil (HVGO)
Solvent Deasphalting (SDA)
- SDA is the only physical process rejecting carbon from heavy petroleum fraction/vacuum residue.
- Propane in liquid form (at moderate pressure) dissolves the whole oil, precipitating asphaltene.
- Deasphalted oil (DAO) has low sulfur/metal content, is called "Bright Stock", used as lube oil plant feedstock being sent to cracking units to increase light oil production.
- The ROSE process is an energy efficient and cost-effective deasphalting technology.
Solvent Extraction
- Uses solvents like N-methyl pyrrolidone (NMP) to separate lube oil stock, dissolving aromatic components in the extract phase, and leaving the rest of the oil in the raffinate.
- It removes the solvent from both phases and dewaxes the raffinate.
Solvent Dewaxing
- Dissolves raffinate in methyl ethyl ketone (MEK), then gradually chills the solution to crystallize the high molecular weight paraffin (wax).
- The remaining solution is filtered where the extracted and dewaxed resulting oil is called "lube oil".
- Aromatics and waxes are removed via catalytic hydrogenation in many modern refineries .
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