Petroleum Refining: Feedstock and Hydrocarbons

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Questions and Answers

What is the typical range of sulfur content found in most crude oils?

  • Less than 0.05 wt%
  • 5-10 wt%
  • More than 10 wt%
  • 1-4 wt% (correct)

Which type of hydrocarbons are characterized by carbon-carbon triple bonds?

  • Alkenes
  • Alkanes
  • Alkynes (correct)
  • Naphthenes

Which of the following is a key function of a desalter unit in crude oil refining?

  • Increasing the sulfur content of the crude oil
  • Removing salt and other impurities from the crude oil (correct)
  • Adding valuable minerals to the crude oil
  • Converting heavy hydrocarbons into lighter ones

At what temperature range should crude oil be maintained during the heating stage of desalting to ensure effective water-oil separation?

<p>48.9-54.4°C (B)</p> Signup and view all the answers

In a desalter unit, what is the role of the electric field applied between two electrodes?

<p>To ionize water droplets and orient them for attraction and coalescence (A)</p> Signup and view all the answers

What is the primary operational difference between atmospheric distillation and vacuum distillation?

<p>Vacuum distillation operates at reduced pressures. (B)</p> Signup and view all the answers

What is the main purpose of Solvent Deasphalting (SDA) in petroleum refining?

<p>To remove carbon from heavy petroleum fraction (A)</p> Signup and view all the answers

Which solvent is commonly used in the solvent deasphalting process to dissolve oil and precipitate asphaltene?

<p>Propane (C)</p> Signup and view all the answers

In the context of solvent extraction, what is the 'lube oil stock' treated with?

<p>N-methyl pyrrolidone (NMP) (B)</p> Signup and view all the answers

What is the primary role of N-methyl pyrrolidone (NMP) in solvent extraction processes?

<p>To dissolve aromatic components from the lube oil stock (C)</p> Signup and view all the answers

Which solvent is typically used in solvent dewaxing to dissolve raffinate?

<p>Methyl ethyl ketone (MEK) (C)</p> Signup and view all the answers

What is the primary purpose of chilling the solution in the solvent dewaxing process?

<p>To crystallize high molecular weight paraffin (wax) (B)</p> Signup and view all the answers

Which of the following parameters influences the effectiveness of water-oil separation during the desalting process?

<p>Viscosity and density of the oil (C)</p> Signup and view all the answers

In crude oil refining, what is the term for the process where smaller water droplets combine to for larger drops for easier separation?

<p>Coalescence (B)</p> Signup and view all the answers

If a crude oil sample is measured to have a salt content of 3 PTB (pounds per thousand barrels) after desalting, what would be the approximate equivalent in kg/1000 m³?

<p>8.6 kg/1000 m³ (B)</p> Signup and view all the answers

Which of the following outcomes is specifically associated with poor desalting in a crude oil refinery?

<p>Catalyst poisoning in catalytic cracking units (A)</p> Signup and view all the answers

If a refinery wants to process heavier crude oil fractions, which distillation method would be more suitable?

<p>Vacuum distillation (A)</p> Signup and view all the answers

What is the key characteristic of 'deasphalted oil (DAO)' produced in the solvent deasphalting process?

<p>Low sulfur and metal contents (A)</p> Signup and view all the answers

What is the name of the well-known solvent deasphalting process known for energy efficiency?

<p>ROSE (B)</p> Signup and view all the answers

In the context of solvent extraction, if the solvent removes aromatic components from the lube oil stock, what is the remaining oil phase called?

<p>Raffinate (B)</p> Signup and view all the answers

Which of the following is the correct general formula for paraffin hydrocarbons (alkanes)?

<p>$C_nH_{2n+2}$ (D)</p> Signup and view all the answers

Which term accurately describes hydrocarbons characterized by branched structures that exhibit structural isomerization?

<p>Isoparaffins (D)</p> Signup and view all the answers

Which of the following crude oil characteristics would be LEAST desirable for efficient petroleum refining?

<p>High Carbon Content (B)</p> Signup and view all the answers

Which process is positioned at the 'front-end' of a crude oil refinery, functioning as the initial separation step?

<p>Crude Distillation (C)</p> Signup and view all the answers

A refinery is experiencing high levels of corrosion in its overhead equipment. Which of the following is the MOST likely cause?

<p>Inefficient desalting (B)</p> Signup and view all the answers

Which of the following products is typically produced using catalytic cracking units after solvent deasphalting is complete?

<p>Light Oil (C)</p> Signup and view all the answers

A refinery aims to maximize the output of high-quality lubricating oils. Which of the following processing sequences is MOST appropriate?

<p>Vacuum Distillation → Solvent Extraction → Solvent Dewaxing (D)</p> Signup and view all the answers

Which type of crude oil would generally command a higher price due to its desirable properties for refining?

<p>Light crude with low sulfur content (A)</p> Signup and view all the answers

A refinery needs to reduce the viscosity of heavy residual oils. Which of the following processes would be MOST suitable?

<p>Visbreaking (B)</p> Signup and view all the answers

Which of the following compounds found in crude oil can act as a poison to catalysts used in catalytic cracking units?

<p>Salts (A)</p> Signup and view all the answers

Which product is created during solvent dewaxing?

<p>Lube Oil (B)</p> Signup and view all the answers

Which of the following parameters is LEAST relevant when choosing between atmospheric and vacuum distillation?

<p>Ambient Air Temperature (A)</p> Signup and view all the answers

In the context of crude oil refining, what primarily determines whether a specific hydrocarbon will be found in the extract phase or the raffinate phase?

<p>Its solubility in the selected solvent (B)</p> Signup and view all the answers

At what operational condition is more distillates extracted in a Vacuum Distillation Unit?

<p>Elevated Temperatures, Reduced Pressure (A)</p> Signup and view all the answers

How does the continuous phase manifest in an oil rig?

<p>Oil with dispersed water droplets. (A)</p> Signup and view all the answers

The desalter in a refinery is not operating correctly, as the PTB is to high. As an operator , what are the best series of actions?

<p>Increase diluent rate, check operation of electrostatic grid, reduce the temperature (C)</p> Signup and view all the answers

What is the trade name of the solvent used to dewax?

<p>MEK (A)</p> Signup and view all the answers

Flashcards

Block flow diagram

Diagram showing stages of a modern oil refinery.

Feedstock

Raw, unprocessed petroleum as the initial input.

Products from Crude Oil

Various fuels, lubricants, and materials created from crude oil.

Physical & Chemical Processes

Methods of separating and modifying oil components.

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Desalter Unit

Removes salt from crude oil

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Crude Oil Desalting

To eliminate salts that cause corrosion

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Atmospheric Distillation

Separates by boiling point at normal air pressure.

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Vacuum Distillation

Separates by boiling point under reduced pressure.

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Solvent Deasphalting

Removing asphaltenes from crude oil.

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Solvent Extraction

Extracting specific compounds from oil.

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Solvent Dewaxing

Removing waxes.

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Paraffins (Alkanes)

Saturated hydrocarbons of general formula CnH2n+2.

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Isoparaffins (Isoalkanes)

Branched alkanes with structural isomerization.

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Olefins (Alkenes)

Unsaturated hydrocarbons with carbon-carbon double bonds.

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Naphthenes (Cycloalkanes)

Ringed, saturated hydrocarbons.

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Aromatics

Ring structured but unsaturated hydrocarbons

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Sulfur content

A common element found in crude oil, can vary from 0.05 to 10%

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Oxygen content

Content of crude oil usually less than 2 wt%.

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Nitrogen compounds

Very low amount of these are found in crude oil.

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Metallic compounds

Very small amount of metallic ones found in crude oil types.

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LPG

Liquified Petroleum Gas

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Desalter Unit

Device to desalinate oils

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Water washing

Dissolves salt crystals and distributes salts into the water, forming tiny droplets.

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Heating

Process where temperature is in the range of of 48.9–54.4°C

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Coalescence

Process where larger drops occur.

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Distillation

Separation by boiling point.

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Crude Distillation Unit (CDU)

Front-end of the refinery and also known as a topping unit,

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Atmospheric residue

Distillate material produced by a CDU

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Vacuum Distillation

Extracting more distillates from atmospheric residue

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Vacuum Unit Distillates

light vacuum gas oil and heavy vacuum gas oil

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Solvent Deasphalting

Only physical process where carbon is rejected. Is efficient when cost effective and provides energy

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ROSE process

A well known process of solvent deasphalting.

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Lube oil stock

Treated by a solvent.

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Raffinate

Dissolved in a solvent in a solution

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Study Notes

Learning Outcomes

  • Lesson aims: Recognize refinery block flow, describe feedstock/products, identify separation/conversion, explain desalting, differentiate distillation, describe solvent processes.

Feedstock: Crude Oil

  • Is the raw material for petroleum refining.

Hydrocarbons

  • Paraffins (alkanes) are saturated compounds with the formula CnH2n+2.
  • Isoparaffins (isoalkanes) are branched hydrocarbons exhibiting structural isomerization.
  • Olefins (alkenes) are unsaturated hydrocarbons containing carbon-carbon double bonds, known as biolefins or alkynes when containing carbon-carbon triple bonds.
  • Naphthenes (cycloalkanes) are saturated hydrocarbons with at least one carbon atom ring.
  • Aromatics are unsaturated cyclic compounds with one or more benzene rings.

Other Compounds

  • The sulfur content in crude oils typically ranges from 1–4 wt%, but varies from less than 0.05 to more than 10 wt%.
  • The oxygen content in crude oil is usually less than 2 wt%.
  • Crude oils have low nitrogen compound amounts.
  • Metallic compounds, like Nickel (Ni) and Vanadium (V), are present in tiny amounts in all crude oil types.

Crude Oil

  • Origins determine physical and chemical traits.

Products of Crude Oil Refining

  • Liquified petroleum gas
  • Gasoline
  • Diesel
  • Kerosene
  • Jet fuel
  • Lube oil
  • Asphalt
  • Petroleum Coke

Crude Oil Refining

  • Physical separation and chemical conversion are the two main types of processes

Desalting

  • Crude oil contains brine as emulsified water droplets.
  • Salt content can reach 2000 pounds per thousand barrels (PTB), lowered to 5.7-14.3 kg/1000 m3 (2-5 PTB) post-treatment.

Desalting Issues

  • Poor desalting effects: fouling from salt deposits, corrosion, and catalyst poisoning in cracking units.

Desalter Unit Operation

  • Water Washing: mixes incoming crude oil with water to dissolve salt crystals and distribute salts into the water, creating tiny droplets.
  • Heating: maintains crude oil temperature between 48.9–54.4°C because water-oil separation is affected by oil viscosity and density.
  • Coalescence: encourages tiny water droplets (1-10 mm) to merge using an electrostatic field between two electrodes.
  • Settling: Coalescence produces larger drops that can be settled by gravity.

Distillation

  • Crude distillation unit (CDU) is at the refinery's front-end which is also called a topping unit, or atmospheric distillation unit.

Vacuum Distillation

  • Vacuum distillation extracts more distillates from atmospheric residue and uses vacuum distillation units.
  • Vacuum unit distillates: light vacuum gas oil (LVGO) and heavy vacuum gas oil (HVGO)

Solvent Deasphalting (SDA)

  • SDA is the only physical process rejecting carbon from heavy petroleum fraction/vacuum residue.
  • Propane in liquid form (at moderate pressure) dissolves the whole oil, precipitating asphaltene.
  • Deasphalted oil (DAO) has low sulfur/metal content, is called "Bright Stock", used as lube oil plant feedstock being sent to cracking units to increase light oil production.
  • The ROSE process is an energy efficient and cost-effective deasphalting technology.

Solvent Extraction

  • Uses solvents like N-methyl pyrrolidone (NMP) to separate lube oil stock, dissolving aromatic components in the extract phase, and leaving the rest of the oil in the raffinate.
  • It removes the solvent from both phases and dewaxes the raffinate.

Solvent Dewaxing

  • Dissolves raffinate in methyl ethyl ketone (MEK), then gradually chills the solution to crystallize the high molecular weight paraffin (wax).
  • The remaining solution is filtered where the extracted and dewaxed resulting oil is called "lube oil".
  • Aromatics and waxes are removed via catalytic hydrogenation in many modern refineries .

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