Periodic Trends in Halogen Atoms
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Questions and Answers

What is the relationship between the size of the halogen atom and the carbon–halogen bond length?

  • The carbon–halogen bond length decreases as the halogen atom size increases.
  • The carbon–halogen bond length increases as the halogen atom size increases. (correct)
  • The carbon–halogen bond length is directly proportional to the square of the halogen atom size.
  • The carbon–halogen bond length is independent of the halogen atom size.
  • Which of the following is a characteristic of fluoromethane?

  • It is non-polar and has a medium C–X bond length.
  • It has a strong C–X bond and a short C–X bond length. (correct)
  • It has a weak C–X bond and a long C–X bond length.
  • It is highly polar and has a medium C–X bond length.
  • What is the trend in the polarity of the methyl halides as one progresses from fluorine to iodine substitution?

  • The polarity fluctuates randomly as one progresses from fluorine to iodine substitution.
  • The polarity decreases as one progresses from fluorine to iodine substitution. (correct)
  • The polarity remains constant as one progresses from fluorine to iodine substitution.
  • The polarity increases as one progresses from fluorine to iodine substitution.
  • What is the relationship between the size of the halogen atom and the carbon–halogen bond strength?

    <p>The carbon–halogen bond strength decreases as the halogen atom size increases.</p> Signup and view all the answers

    Which of the following is a characteristic of iodomethane?

    <p>It has a weak C–X bond and a long C–X bond length.</p> Signup and view all the answers

    Study Notes

    Halogen Atom Size and Carbon-Halogen Bond Properties

    • Halogen atom size increases as you go down the periodic table, with fluorine being the smallest and iodine being the largest.
    • As you go down the periodic table, the carbon-halogen bond length increases, and the carbon-halogen bond strength decreases.
    • The electrostatic potential maps at the van der Waals surface illustrate the trend in polarity, C–X bond length, and halogen atom size for the four methyl halides.
    • Fluoromethane has the highest polarity, shortest C–X bond length, and strongest C–X bond.
    • Iodomethane has the lowest polarity, longest C–X bond length, and weakest C–X bond.
    • The trend in carbon-halogen bond properties can be observed in the methyl halides, with fluorine substitution resulting in the strongest and shortest bond, and iodine substitution resulting in the weakest and longest bond.

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    Description

    This quiz explores the relationship between halogen atom size, carbon-halogen bond length, and bond strength as you move down the periodic table. It also examines the polarity of methyl halides.

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