Periodic Trends and Ion Formation
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Questions and Answers

How does the electronegativity of an element typically relate to its metallic character?

  • Metals generally exhibit higher electronegativity values than nonmetals.
  • Electronegativity has no direct relationship with metallic character.
  • Electronegativity is solely determined by the atomic mass, irrespective of metallic character.
  • Metals generally exhibit lower electronegativity values than nonmetals. (correct)

Across a period from left to right, how do ionization energy and atomic radius generally change?

  • Ionization energy increases, and atomic radius increases.
  • Ionization energy decreases, and atomic radius increases.
  • Ionization energy increases, and atomic radius decreases. (correct)
  • Ionization energy decreases, and atomic radius decreases.

Considering the trends of ionization energy and electronegativity, which of the following elements would likely require the most energy to remove an electron and have a strong tendency to attract bonding electrons?

  • An element located at the bottom right of the periodic table.
  • An element located at the bottom left of the periodic table.
  • An element located at the top right of the periodic table (excluding noble gases). (correct)
  • An element located in the middle of the periodic table.

How does the reactivity of metals typically correlate with their ionization energy?

<p>Metals with higher ionization energies are generally less reactive. (D)</p> Signup and view all the answers

If element X has a significantly lower ionization energy and electronegativity compared to element Y, what can be inferred about their positions on the periodic table and their chemical behavior?

<p>X is likely located towards the bottom left and behaves as a metal, while Y is towards the top right and behaves as a nonmetal. (D)</p> Signup and view all the answers

What is the primary reason sodium (Na) forms a positive ion?

<p>To achieve a stable electron configuration resembling a noble gas. (C)</p> Signup and view all the answers

Which statement correctly describes how magnesium (Mg) achieves an octet?

<p>By losing two valence electrons. (B)</p> Signup and view all the answers

What is the ionic charge of a magnesium ion ($Mg$)?

<p>2+ (D)</p> Signup and view all the answers

What is the electronic configuration of a magnesium ion ($Mg^{2+}$)?

<p>$1s^22s^22p^6$ (C)</p> Signup and view all the answers

How many valence electrons does Aluminum (Al) have?

<p>3 (C)</p> Signup and view all the answers

What electron transfer process does aluminum (Al) undergo to form an octet?

<p>It loses 3 electrons. (B)</p> Signup and view all the answers

What is the ionic charge of an aluminum ion?

<p>Al3+ (B)</p> Signup and view all the answers

What is the electronic configuration of an aluminum ion ($Al^{3+}$)?

<p>$1s^22s^22p^6$ (B)</p> Signup and view all the answers

An element from Group 5A on the periodic table is likely to form an ion with what charge?

<p>3- (A)</p> Signup and view all the answers

If an element gains two electrons, which of the following describes the resulting change?

<p>The element becomes a negative ion with a 2- charge. (B)</p> Signup and view all the answers

How many valence electrons does Chlorine (Cl) have, and what charge does it typically form as an ion?

<p>7 valence electrons, 1- charge (C)</p> Signup and view all the answers

Which electronic configuration represents a chloride ion (Cl-)?

<p><code>1s2 2s2 2p6 3s2 3p6</code> (C)</p> Signup and view all the answers

Sulfur (S) is in Group 6A. How many electrons must it gain to achieve a stable octet?

<p>Gain 2 electrons (D)</p> Signup and view all the answers

What is the typical ionic charge of an ion formed from an element in Group 6A?

<p>2- (B)</p> Signup and view all the answers

How many protons and electrons does a $S^{2-}$ ion contain?

<p>16 protons and 18 electrons (B)</p> Signup and view all the answers

Which of the following elements is least likely to form an ion?

<p>Argon (A)</p> Signup and view all the answers

An element is located in the 5th period of the periodic table. How many energy levels are occupied by its electrons?

<p>5 (B)</p> Signup and view all the answers

Which of the following statements accurately describes the relationship between energy levels and sublevels?

<p>Each of the seven energy levels can have up to four sublevels. (A)</p> Signup and view all the answers

What is the maximum number of electrons that can occupy a 'd' sublevel?

<p>10 (A)</p> Signup and view all the answers

Which principle dictates that electrons first fill the lowest energy orbitals available?

<p>Aufbau's Principle (C)</p> Signup and view all the answers

According to Pauli's Exclusion Principle, what is the maximum number of electrons that can occupy a single atomic orbital, and what must be true of their spins?

<p>Two electrons, with opposite spins. (D)</p> Signup and view all the answers

Which of the following statements best describes Hund's Rule of Maximum Multiplicity?

<p>Electrons will individually occupy each orbital within a subshell before doubling up in any one orbital. (C)</p> Signup and view all the answers

Element X has an electronic configuration ending in $p^4$. In which group of the periodic table is element X most likely located?

<p>Group 16 (C)</p> Signup and view all the answers

An atom has 13 electrons. What is its electronic configuration according to Aufbau's principle?

<p>$1s^22s^22p^63s^23p^3$ (B)</p> Signup and view all the answers

Which of the following ionic compounds is most likely to conduct electricity in its molten state?

<p><code>MgO</code> (A)</p> Signup and view all the answers

Gallium (Ga) typically forms a 3+ ion. Which noble gas does Ga3+ resemble in its electronic configuration?

<p>Argon (Ar) (B)</p> Signup and view all the answers

Based on electronegativity differences, which of the following compounds is LEAST likely to exhibit ionic bonding?

<p><code>HCl</code> (Electronegativity difference: 0.96) (B)</p> Signup and view all the answers

Which of the following describes what happens when Selenium (Se) forms a Se2- ion?

<p>Selenium gains two electrons and becomes isoelectronic with Krypton. (D)</p> Signup and view all the answers

Consider the formation of an ionic compound between element X, which readily loses two electrons, and element Y, which readily gains one electron. What is the most likely formula of the resulting compound?

<p><code>XY2</code> (A)</p> Signup and view all the answers

Which property is generally associated with ionic compounds?

<p>Poor conductivity in solid state, good conductivity when dissolved in water. (B)</p> Signup and view all the answers

Beryllium (Be) forms Be2+ ions. Which noble gas has the same electronic configuration as the Beryllium ion?

<p>Helium (He) (A)</p> Signup and view all the answers

Which of the following pairs of elements is most likely to form an ionic bond?

<p>Sodium (Na) and Chlorine (Cl) (D)</p> Signup and view all the answers

What characteristic primarily determines whether a covalent bond will be polar or non-polar?

<p>The electronegativity difference between the bonding atoms. (D)</p> Signup and view all the answers

Which statement accurately describes the properties of compounds formed through covalent bonds?

<p>They typically have low melting and boiling points and do not conduct electricity well. (A)</p> Signup and view all the answers

For a bond to be classified as a polar covalent bond according to the Pauling scale, what must be true of the electronegativity difference ($\triangle E$) between the two atoms?

<p>$0.5 \leq \triangle E \leq 1.7$ (D)</p> Signup and view all the answers

If element X has an electronegativity of 3.0 and element Y has an electronegativity of 2.5, what type of bond is most likely to form between them?

<p>Polar covalent bond (B)</p> Signup and view all the answers

In a water molecule (H₂O), oxygen has a higher electronegativity than hydrogen. What is the consequence of this difference?

<p>The oxygen atom has a partial negative charge $(\delta-)$ and the hydrogen atoms have a partial positive charge $(\delta+)$ (C)</p> Signup and view all the answers

Which of the following diatomic molecules is held together by a non-polar covalent bond?

<p>O₂ (D)</p> Signup and view all the answers

Why do covalent bonds typically form between two non-metal atoms?

<p>Non-metals have similar, relatively high electronegativities, leading to sharing of electrons. (A)</p> Signup and view all the answers

How does the number of covalent bonds a nonmetal typically forms relate to its electron configuration?

<p>It forms covalent bonds equal to the number of electrons it needs to achieve a noble gas configuration. (C)</p> Signup and view all the answers

Flashcards

Electronegativity

The ability of an atom to attract bonding electrons from another atom.

Electronegativity trend

Increases from bottom to top within a group and left to right across a period.

Ionization energy

The energy required to remove an electron from an atom's outermost shell.

Ionization energy trend

Increases from bottom to top in a group and left to right across a period.

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Reactivity

A measure of how easily an atom reacts with other atoms.

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Energy levels

Regions around the nucleus where electrons orbit, labeled 1 to 7.

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Quantum number (n)

A number (1-7) indicating the energy level of an electron.

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Sublevels/subshells

Regions within energy levels with specific shapes labeled S, P, D, F.

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Aufbau’s principle

Electrons fill the lowest energy orbitals first.

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Pauli’s exclusion principle

No more than two electrons can occupy the same orbital with opposite spins.

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Hund’s rule

Electrons will fill degenerate orbitals singly before pairing.

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Electron configuration

A notation showing how electrons are arranged in an atom.

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Orbital capacity

Maximum number of electrons that different subshells can hold: S(2), P(6), D(10), F(14).

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Electron Configuration of Sodium

Sodium's electron configuration is 1s² 2s² 2p⁶ 3s¹. It has 11 electrons as a neutral atom.

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Sodium Ion Charge

The sodium ion (Na⁺) has a positive charge due to loss of one electron.

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Electrons in Magnesium Atom

Magnesium has 12 electrons arranged as 1s² 2s² 2p⁶ 3s².

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Magnesium Ion Configuration

The magnesium ion (Mg²⁺) gains a stable configuration of 1s² 2s² 2p⁶ after losing two electrons.

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Valence Electrons of Aluminum

Aluminum has 3 valence electrons, as it is in group 3A of the periodic table.

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Ionic Charge of Aluminum Ion

The aluminum ion (Al³⁺) has a charge of +3 after losing three electrons.

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Formation of Anions

Nonmetals gain electrons to form negative ions (anions) achieving octets.

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Negative Ion Electron Configuration

Anions have electron configurations of the nearest noble gas, with more electrons than protons.

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Group 7A nonmetals

Nonmetals in Group 7A have 7 valence electrons and tend to gain 1 electron to form ions.

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Chlorine ion (Cl-)

Chlorine gains 1 electron to form a negative ion with a charge of 1-.

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Valence electrons (S)

Sulfur has 6 valence electrons since it's in Group 6A.

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Sulfur ionic charge

Sulfur gains 2 electrons to form a negative ion with a charge of 2- (S2-).

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Ionic charge determination

Ionic charges can be determined from the group number in the periodic table.

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Negative ion formation

Nonmetals form negative ions by gaining electrons to achieve an octet.

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Electronic configuration (S2-)

The electronic configuration for the sulfur ion is 1s22s22p63s23p6, like argon (noble gas).

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Group 4A and 8A elements

Elements in groups 4A and 8A do not typically form ions.

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Chemical Bond

An attraction between atoms that forms compounds through electron sharing or transfer.

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Ionic Bond

A bond formed by the transfer of valence electrons from metals to nonmetals, creating charged ions.

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Covalent Bond

A bond formed by the sharing of valence electrons between two atoms, usually nonmetals.

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Metal Atom

An atom that loses electrons easily to form positively charged ions in ionic bonds.

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Nonmetal Atom

An atom that gains electrons to form negatively charged ions in ionic bonds.

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Pauling Scale

A scale used to measure electronegativity differences between atoms.

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Ionic Bond Characteristics

Ionic bonds are strong, high melting/boiling points, and can conduct electricity.

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Covalent Bonding

A type of bond formed by sharing pairs of electrons between non-metals.

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Octet Rule

Atoms tend to share or transfer electrons to achieve a stable arrangement of eight electrons in their outer shell.

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Polar Covalent Bond

A bond formed between two non-metals with unequal electronegativities, causing a dipole.

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Non-Polar Covalent Bond

A bond where two non-metals share electrons equally resulting in no dipole.

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Electronegativity Difference

The measure of how strongly an atom attracts bonding electrons; indicates bond type.

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Dipole

A molecule with two distinct poles (positive and negative) due to uneven electron sharing.

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Characteristics of Covalent Compounds

Usually have low melting and boiling points and are poor electrical conductors.

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Diatomic Molecule

A molecule composed of two identical atoms, often forming non-polar covalent bonds.

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Study Notes

Atomic Structure and Properties

  • Atoms are the smallest parts of an element that retain its properties
  • Atoms consist of protons, neutrons, and electrons
  • Protons are positively charged and found in the nucleus
  • Neutrons have no charge and are found in the nucleus
  • Electrons are negatively charged and found outside the nucleus

History of Atomic Models

  • Solid Sphere Model (Dalton, 1803): Atoms are indivisible and identical for a given element
  • Plum Pudding Model (Thomson, 1904): Electrons are embedded in a sphere of positive charge
  • Nuclear Model (Rutherford, 1911): The atom is mostly empty space, with a dense, positively charged nucleus
  • Planetary Model (Bohr, 1913): Electrons orbit the nucleus in specific energy levels. Electrons can only exist at specific energy levels
  • Quantum Mechanical Model (Schrödinger, 1926): Electrons exist in orbitals where their exact location is uncertain, described by probability functions

Subatomic Particles

  • Protons: Positive charge, mass of 1 amu
  • Neutrons: No charge, mass of 1 amu
  • Electrons: Negative charge, extremely small mass (1/1836 amu)

Atomic Number and Mass Number

  • Atomic Number (Z): Number of protons in an atom
  • Mass Number (A): Sum of protons and neutrons in an atom

Isotopes

  • Isotopes are atoms of the same element with different numbers of neutrons
  • The atomic number is the same, but the mass number is different
  • Most elements exist as a mixture of isotopes -The periodic table's atomic weight is an average of the masses of its isotopes

Ions

  • Ions are atoms that have gained or lost electrons
  • Cations: Positively charged ions (formed by loss of electrons)
  • Anions: Negatively charged ions (formed by gain of electrons)

Electronic Configurations

  • Aufbau's principle: Electrons fill the lowest energy levels first
  • Pauli exclusion principle: Each orbital can hold a maximum of two electrons with opposite spins
  • Hund's rule: Electrons fill orbitals singly before pairing up

Electronic Configuration of Carbon

  • Carbon is in the 2nd period and Group 4
  • Ground state electronic configuration: 1s2 2s2 2p2

Noble Gas Configurations

  • Noble gases have a full valence shell (8 electrons, except for Helium which has 2)
  • They are used to abbreviate the electronic configuration of other elements

Orbital Diagrams

  • Visual representation of electron distribution in orbitals and subshells
  • Obey Pauli's exclusion principle (no two electrons can have the same quantum numbers) and Hund's rule (fill degenerate orbitals singly before pairing electrons)

Types of Chemical Bonds

  • Ionic Bonds: Form between a metal and a nonmetal, involving the transfer of electrons to form ions with opposite charges
  • Covalent Bonds: Form between nonmetals, involving the sharing of electrons to achieve a stable electron configuration (octet)

Polar Covalent Bonds

  • Occur when two nonmetals share electrons unequally, due to a difference in electronegativity
  • The more electronegative atom attracts the shared electrons more strongly leading to a slightly positive and slightly negative end

Non-polar Covalent Bonds

  • Occur when two nonmetals share electrons almost equally due to little or no electronegativity difference

Periodic Properties

  • Atomic Radius: Decreases across periods, increases down groups
  • Metallic character: Increases down groups and left to right across the periods
  • Electronegativity: Increases across periods and decreases down groups
  • Ionization energy: Increases across periods and decreases down groups
  • Reactivity: Metals lose electrons, nonmetals gain electrons

Octet Rule

  • Atoms tend to gain, lose, or share electrons to achieve a full valence shell with 8 electrons (octet), except for hydrogen and helium
  • Noble gases have a full octet

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Explore trends in electronegativity, ionization energy, and atomic radius within the periodic table. Understand how these properties influence metallic character, reactivity, and ion formation. Investigate elements like sodium and magnesium to explain why they form specific ions.

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