Periodic Trends and Bonding Concepts

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Questions and Answers

What type of bond typically forms between a metal and a nonmetal?

  • Ionic bond (correct)
  • Nonpolar covalent bond
  • Covalent bond
  • Polar covalent bond

Which describes a nonpolar covalent bond?

  • ΔEN is greater than 1.7
  • ΔEN is less than or equal to 0.5 (correct)
  • Formed between metals and nonmetals
  • Electrons are shared unequally

How is the name of an ionic compound typically structured?

  • Anion first, then cation
  • Cation with a suffix, anion without
  • Cation and anion both with -ide suffix
  • Cation first followed by an anion with an -ide suffix (correct)

What determines the geometry of a molecule according to VSEPR theory?

<p>The number of electron pairs around the central atom (A)</p> Signup and view all the answers

In which scenario would a polar covalent bond likely form?

<p>Moderate difference in electronegativity between 0.5 and 1.7 (B)</p> Signup and view all the answers

What is the typical bond angle in a linear molecular geometry?

<p>180° (A)</p> Signup and view all the answers

How do you determine the oxidation state in naming transition metals in ionic compounds?

<p>Specify the oxidation state using Roman numerals (C)</p> Signup and view all the answers

What kind of elements compose covalent compounds?

<p>Only nonmetals (A)</p> Signup and view all the answers

Which statement accurately describes electronegativity trends in the periodic table?

<p>Electronegativity increases across a period. (A)</p> Signup and view all the answers

What charge balance is required for an ionic compound to be neutral?

<p>Total positive charge must be equal to the total negative charge. (B)</p> Signup and view all the answers

Which type of bond is likely to form if the difference in electronegativity between two atoms is 0.3?

<p>Nonpolar covalent bond (B)</p> Signup and view all the answers

When naming a covalent compound, which prefix would be used for two atoms of the same element?

<p>Di- (A)</p> Signup and view all the answers

In VSEPR theory, what is the bond angle in a bent molecular geometry with two bonding pairs and one lone pair?

<p>Less than 120° (C)</p> Signup and view all the answers

What is the expected bond character when the difference in electronegativity between two atoms is greater than 1.7?

<p>Ionic bond (D)</p> Signup and view all the answers

Which step is NOT part of determining molecular geometry using VSEPR theory?

<p>Identify the atomic number of the central atom. (D)</p> Signup and view all the answers

Which of the following correctly describes how to name the compound FeCl₂?

<p>Iron(II) chloride (C)</p> Signup and view all the answers

What happens to electronegativity as you move from left to right across a period in the periodic table?

<p>It increases due to increased nuclear charge. (A)</p> Signup and view all the answers

Which type of bond typically forms when the difference in electronegativity is between 0.5 and 1.7?

<p>Polar covalent bond (C)</p> Signup and view all the answers

In the naming of ionic compounds, which suffix is used for the anion?

<p>-ide (A)</p> Signup and view all the answers

How are covalent compounds named when there are two atoms of the same element present?

<p>Omit the prefix for the first element only. (A)</p> Signup and view all the answers

What is the bond angle in a linear molecular geometry according to VSEPR theory?

<p>180° (C)</p> Signup and view all the answers

Which of the following terms refers to the ability of an atom to attract electrons in a bond?

<p>Electronegativity (B)</p> Signup and view all the answers

When determining molecular geometry, what is the first step in the VSEPR theory process?

<p>Draw the Lewis structure. (A)</p> Signup and view all the answers

What is the relationship between the number of lone pairs and the geometry of a molecule?

<p>Lone pairs can alter the bond angles and molecular shape. (C)</p> Signup and view all the answers

Flashcards

Electronegativity

An atom's ability to attract electrons in a bond.

Ionic Bond

Bond formed between atoms with a large electronegativity difference.

Covalent Bond

Bond formed between atoms with a smaller electronegativity difference.

VSEPR Theory

Electron pairs repel to maximize distance, influencing molecular shape.

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Ionic Compound Naming

Name cation (metal) first, then anion (nonmetal) with -ide; transition metals use Roman numerals.

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Covalent Compound Naming

Use prefixes (mono-, di-, tri-) to show number of atoms; omit mono- for first element.

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Polar Covalent Bond

Unequal sharing of electrons in a covalent bond.

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Nonpolar Covalent Bond

Equal sharing of electrons in a covalent bond.

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Electronegativity Trend Across a Period

Electronegativity increases as you move from left to right across a period in the periodic table.

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Electronegativity Trend Down a Group

Electronegativity decreases as you move down a group in the periodic table.

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Ionic Bond Formation

Forms between atoms with a large electronegativity difference (ΔEN > 1.7), typically between metals and nonmetals.

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Covalent Bond Formation

Forms between atoms with a smaller electronegativity difference (ΔEN ≤ 1.7), typically between nonmetals.

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What determines bond type?

The difference in electronegativity (ΔEN) between two atoms predicts the type of bond they form. A large ΔEN (>1.7) indicates an ionic bond, while a smaller ΔEN (≤1.7) suggests a covalent bond.

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VSEPR Theory: What affects molecular shape?

The VSEPR Theory states that electron pairs around a central atom will arrange themselves as far apart as possible to minimize repulsion. This arrangement determines the molecule's geometry.

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Linear Geometry

A molecular shape with two electron regions, resulting in a 180° bond angle.

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Bent Geometry

A molecular shape with two bonding pairs and 1-2 lone pairs, resulting in a bond angle less than 180°.

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Study Notes

  • Electronegativity increases across periods and decreases down groups.
  • Electronegativity is an atom's ability to attract electrons in a bond.
  • Higher nuclear charge leads to higher electronegativity across periods.
  • Added electron shells cause lower electronegativity down groups.
  • Ionic bonds form when the difference in electronegativity (ΔEN) is greater than 1.7, typically between metals and nonmetals.
  • Covalent bonds form when ΔEN is less than or equal to 1.7, typically between nonmetals.
  • Polar covalent bonds occur with moderate ΔEN (0.5 < ΔEN ≤ 1.7) where electrons are shared unequally.
  • Nonpolar covalent bonds occur with small ΔEN (ΔEN ≤ 0.5) where electrons are shared equally.

Naming and Writing Formulas for Ionic and Covalent Compounds

  • Ionic compounds consist of a metal cation and a nonmetal anion.
  • Name the cation followed by the anion (e.g., NaCl = sodium chloride).
  • Transition metal ions require specification of their oxidation state using Roman numerals (e.g., FeCl₂ = iron(II) chloride).
  • Balance ionic charges to create a neutral compound (e.g., Al³⁺ and Cl⁻ → AlCl₃).
  • Covalent compounds consist of two or more nonmetals.
  • Use prefixes to denote the number of each atom: mono-, di-, tri-, etc. Omit "mono-" for the first element. (e.g., CO₂ = carbon dioxide, N₂O₄ = dinitrogen tetroxide).
  • Formulas for covalent compounds are determined according to the prefixes.

VSEPR Theory and Molecular Geometry

  • VSEPR (Valence Shell Electron Pair Repulsion) theory explains molecular shapes.
  • Electron pairs (bonding & lone pairs) repel each other to maximize distance.
  • VSEPR shapes are used to classify molecular geometry.
  • Linear geometry has 2 regions of electron density and a 180° bond angle (e.g., CO₂).
  • Bent geometry has two bonding pairs and 1-2 lone pairs with bond angles determined accordingly by the number of lone pairs.

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