Chemistry Chapter 12 - Chemical Bonding
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Questions and Answers

What type of bond is formed when electrons are shared between nonmetal atoms?

  • Hydrogen bond
  • Ionic bond
  • Covalent bond (correct)
  • Metallic bond
  • What is the definition of an isoelectronic series?

  • A series of ions/atoms containing the same number of electrons (correct)
  • A series of ions/atoms containing the same number of protons
  • A series of ions/atoms containing the same number of neutrons
  • A series of elements in the same group on the periodic table
  • Which of the following particles is isoelectronic with the noble gas Neon (Ne)?

  • Na+ (correct)
  • Mg2+
  • O2-
  • F-
  • Which of the following is a characteristic of ionic compounds?

    <p>They form crystalline structures at room temperature (B)</p> Signup and view all the answers

    Which of the following is a characteristic of molecular compounds?

    <p>They can exist in any state of matter (solid, liquid, or gas) at room temperature (B)</p> Signup and view all the answers

    Which of the following compounds is an example of an ionic compound?

    <p>NaCl (D)</p> Signup and view all the answers

    Based on the provided information, which of the following compounds would you expect to have the highest melting point?

    <p>NaCl (C)</p> Signup and view all the answers

    Which of the following statements is NOT true about covalent bonds?

    <p>Covalent bonds are generally stronger than ionic bonds (C)</p> Signup and view all the answers

    What is the primary distinction between ionic and covalent bonds, based on how electrons are involved?

    <p>Ionic bonds involve transferring electrons to achieve the same amount of electrons as the nearest noble gas, while covalent bonds share to achieve the same amount of electrons as the nearest noble gas. (A)</p> Signup and view all the answers

    Which of the following is NOT a characteristic of a stable chemical bond?

    <p>The bond is formed by the unequal sharing of electrons. (C)</p> Signup and view all the answers

    How do metals typically achieve a noble gas electron configuration when forming compounds?

    <p>By losing electrons to become a cation. (D)</p> Signup and view all the answers

    What is the name given to a chemical substance formed by the chemical combination of two or more elements?

    <p>A compound. (C)</p> Signup and view all the answers

    What type of compound is typically formed when non-metal elements combine?

    <p>Molecular (covalent) compound. (A)</p> Signup and view all the answers

    Which of the following best describes the nature of chemical bonds?

    <p>They are the forces holding atoms together to form a compound or function as a unit. (B)</p> Signup and view all the answers

    In the formation of an ionic compound, what role do metals play?

    <p>They lose electrons to form cations. (A)</p> Signup and view all the answers

    Which noble gas electron configuration are metals trying to achieve when forming cations?

    <p>The configuration of the previous noble gas. (B)</p> Signup and view all the answers

    Which of these molecules would have a dipole moment?

    <p>H-Cl (C)</p> Signup and view all the answers

    Based on the information provided, what is the primary reason for the difference in how sodium fluoride (Na+ F-) and hydrogen monofluoride (Hδ+ Fδ−) are written?

    <p>The difference in electronegativity between the elements in sodium fluoride is larger. (D)</p> Signup and view all the answers

    Which of the following statements correctly describes the relationship between dipole moment and molecular polarity?

    <p>Molecular polarity is a consequence of dipole moment. (A)</p> Signup and view all the answers

    If the electronegativity difference (∆EN) between two atoms in a bond is zero, what kind of bond is formed?

    <p>Nonpolar covalent bond (C)</p> Signup and view all the answers

    Which of the following statements correctly describes the relationship between bond polarity and the difference in electronegativity (∆EN) between the bonded atoms?

    <p>As ∆EN increases, the bond becomes more polar. (B)</p> Signup and view all the answers

    What is the primary reason why water (H2O) can dissolve ionic compounds?

    <p>Water is a polar solvent, and ionic compounds have a polar structure. (C)</p> Signup and view all the answers

    Which of the following has the most significant impact on a molecule's dipole moment?

    <p>The difference in electronegativity between the atoms (B)</p> Signup and view all the answers

    According to the information provided, which of the following is NOT directly affected by dipole moment?

    <p>Atomic radius (B)</p> Signup and view all the answers

    Which of the following statements is true about ionic compounds?

    <p>Metals usually lose electrons to form cations. (D)</p> Signup and view all the answers

    What is the electronegativity value for fluorine?

    <p>4.0 (A)</p> Signup and view all the answers

    Which of the following elements would have the lowest electronegativity?

    <p>Francium (D)</p> Signup and view all the answers

    What characterizes a polar covalent bond?

    <p>Unequal sharing of electrons resulting in charge separation. (D)</p> Signup and view all the answers

    In terms of electronegativity, what happens as you move down a group in the periodic table?

    <p>Electronegativity decreases. (A)</p> Signup and view all the answers

    Which statement about non-metals and electronegativity is accurate?

    <p>Non-metals generally attract electrons better due to higher electronegativity. (A)</p> Signup and view all the answers

    How does the effective nuclear charge relate to electronegativity trends across a period?

    <p>It increases, leading to higher electronegativity. (D)</p> Signup and view all the answers

    What is the boiling point of dry ice gas mentioned in the context?

    <p>-78 °C (B)</p> Signup and view all the answers

    Which type of bond involves complete transfer of electrons?

    <p>Pure ionic bond (A)</p> Signup and view all the answers

    Which of the following pairs has the greatest difference in electronegativity (∆EN)?

    <p>Na-Cl (C)</p> Signup and view all the answers

    What is the bond character of a bond with ∆EN equal to zero?

    <p>Nonpolar covalent bond (C)</p> Signup and view all the answers

    In a covalent bond characterized by a ∆EN of 1.9, what type of bond is formed?

    <p>Strong polar covalent bond (A)</p> Signup and view all the answers

    Which element has the highest electronegativity in the bond comparisons given?

    <p>F (A)</p> Signup and view all the answers

    What determines the bond character between atoms?

    <p>The difference in electronegativity (∆EN) (D)</p> Signup and view all the answers

    For the bond in H-F, what is the ∆EN value if H has an electronegativity of 2.1 and F has 4.0?

    <p>1.9 (D)</p> Signup and view all the answers

    Which bond is expected to have the least ionic character?

    <p>O-O (D)</p> Signup and view all the answers

    What does the difference in electronegativity (∆EN) determine in a bond?

    <p>The bond's polarity and ionic character (D)</p> Signup and view all the answers

    What occurs when the difference in electronegativity (∆EN) is zero?

    <p>Electrons are shared equally, resulting in a pure covalent bond (D)</p> Signup and view all the answers

    Which of the following bonds is expected to have a higher ionic character?

    <p>Na - Cl (D)</p> Signup and view all the answers

    In terms of bond character, what is expected when ∆EN increases in covalent bonds?

    <p>The bond becomes more polar (D)</p> Signup and view all the answers

    What is a dipole moment a measure of?

    <p>Charge separation within a molecule (C)</p> Signup and view all the answers

    Which statement accurately describes electronegativity trends on the periodic table?

    <p>Electronegativity increases across a period and decreases down a group (C)</p> Signup and view all the answers

    In which scenario would a bond have both ionic and covalent character?

    <p>In bonds between nonmetals and metals with a moderate electronegativity difference (A)</p> Signup and view all the answers

    What is indicated by the direction of an arrow used to represent a dipole moment?

    <p>The negative charge center (D)</p> Signup and view all the answers

    Flashcards

    Compound

    A chemical combination of two or more elements. Metal and non-metal elements form ionic compounds. Non-metal and non-metal elements form molecular compounds (also called covalent compounds).

    Chemical Bonds

    The forces that hold groups of atoms together to form a compound or function as a unit. Atoms are bonded in two ways: by transferring electrons from one atom to another (ionic bond) or by sharing electrons among the participating atoms (covalent bond).

    Stable Bond

    A stable bond is formed when participating atoms achieve a noble gas electron configuration, having the same number of electrons as a noble gas atom (e.g., He (2 electrons), Ne (10 electrons), Ar (18 electrons).

    Ionic Bond - Metals

    Metals lose one or more outermost electrons to achieve the previous noble gas configuration, forming positively charged ions called cations.

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    Ionic Bond - Non-metals

    Non-metals gain electrons to achieve the next noble gas configuration, forming negatively charged ions called anions.

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    Covalent Bond

    Atoms share electrons to achieve a stable noble gas electron configuration.

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    Electronegativity

    The tendency of an atom in a molecule to attract shared electrons toward itself. Higher electronegative (EN) atoms attract electrons more strongly.

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    Polar Covalent Bond

    A covalent bond where electrons are shared unequally between atoms due to differences in electronegativity, creating partial positive and negative charges within the molecule.

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    Anion Formation

    Nonmetal atoms achieve a stable electron configuration by gaining one or more electrons to become negatively charged ions called anions.

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    Covalent Bonding

    Nonmetal atoms share electrons to achieve a stable electron configuration, forming a covalent bond.

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    Isoelectronic Series

    A series of ions or atoms possessing the same number of electrons.

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    Ionic Compound

    A compound formed from the electrostatic attraction between oppositely charged ions, typically a metal and a nonmetal.

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    Molecular Compound

    A compound formed when nonmetal atoms share electrons, resulting in molecules.

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    Melting Point of Ionic Compounds

    Ionic compounds typically exhibit high melting points due to the strong electrostatic attraction between ions.

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    Conductivity of Ionic Compounds

    Ionic compounds are good conductors of electricity when dissolved in water or melted because the ions are free to move and carry charge.

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    Melting Point of Molecular Compounds

    Molecular compounds typically have lower melting points compared to ionic compounds because the weaker intermolecular forces are easier to overcome.

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    ΔEN (Delta EN)

    The difference in electronegativity between two atoms in a bond.

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    Electronegativity Trend: Across a Period

    Electronegativity increases across a period from left to right (excluding noble gases).

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    Electronegativity Trend: Down a Group

    Electronegativity decreases down a group.

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    EN of Non-metals

    Non-metals generally have higher electronegativity than metals.

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    Octet Rule

    The rule that states that atoms tend to gain, lose, or share electrons to achieve eight valence electrons (like a noble gas).

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    Non-polar covalent bond

    A bond between atoms where electrons are shared equally.

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    Ionic bond

    A bond where electrons are completely transferred from one atom to another, forming ions.

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    ∆EN (Difference in electronegativity)

    The difference in electronegativity between two atoms in a bond.

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    More covalent character

    A chemical bond with a greater degree of electron sharing.

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    More ionic character

    A chemical bond with a greater degree of electron transfer.

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    Solubility

    Substances with similar ionic character tend to dissolve in each other.

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    Dipole Moment

    A measure of electron distribution in a molecule, represented by a vector pointing from the partial positive charge to the partial negative charge.

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    Electronegativity Difference (ΔEN)

    The difference in electronegativity between two bonded atoms determines the polarity of a bond.

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    Polar Molecule

    A molecule with a dipole moment due to unequal charge distribution, creating a positive and negative end.

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    Nonpolar Molecule

    A molecule with no dipole moment due to evenly distributed charge.

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    Intermolecular Forces

    The overall attraction between molecules, which depends on dipole moments.

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    Electronegativity Difference (∆EN)

    The difference in electronegativity between two atoms bonded together.

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    Polar Covalent Bond With Ionic Character

    A bond with a smaller electronegativity difference than an ionic bond, indicating a partial transfer of electrons and both ionic and covalent character.

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    Study Notes

    Chapter 12 - Chemical Bonding

    • Chemical bonding involves forces holding atoms together, forming compounds or units.
    • Atoms bond via electron transfer (ionic) or sharing (covalent).
    • Ionic compounds are formed from metals and non-metals.
    • Covalent compounds are formed from non-metals.
    • Compounds achieve stable electron configurations by following the octet rule (except hydrogen which follows the duet rule).

    Part 1 - Chemical Bonding

    • Elements react to become stable.
    • Metals lose electrons to form positive ions (cations).
    • Nonmetals gain electrons to form negative ions (anions).
    • Ionic bonds result from the electrostatic attraction of oppositely charged ions.
    • Different elements gain/lose different numbers of electrons to achieve stable configurations.

    Part 2 - Electronegativity

    • Electronegativity (EN) is an atom's ability to attract shared electrons.
    • EN increases across a period (left to right) but decreases down a group.
    • Fluorine has the highest EN (4.0), while cesium and francium have the lowest (0.7).
    • Differences in EN determine bond polarity.

    Part 3 - Bond Polarity and Dipole Moment

    • Polar covalent bonds occur when atoms share electrons unequally due to differences in EN.
    • A dipole moment reflects the unequal distribution of charge within a molecule, with charges denoted by δ+ (partial positive) and δ- (partial negative).
    • A dipole moment is a measure of charge separation within a molecule.

    Part 4 - Lewis Structures

    • Lewis structures illustrate the bonding arrangements in molecules/ions using dots to represent valence electrons.

    Part 5 - Shapes of Molecules (VSEPR)

    • VSEPR theory predicts molecular shapes based on electron pair repulsion.

    Ionic Compounds

    • Ionic compounds are typically crystalline solids at room temperature.
    • They have high melting points.
    • They conduct electricity when molten or dissolved.
    • Formulas are in simplest ratios.

    Molecular Compounds

    • Molecular compounds have varying states of matter at room temperature.
    • They have relatively low melting points.
    • They are typically poor conductors of electricity.
    • Formulas represent the exact composition of the molecule.

    Stable Compounds

    • Stable compounds form when atoms achieve a noble gas electron configuration (same number of electrons as the noble gas).

    Isoelectronic Series

    • Isoelectronic series is a series of ions/atoms that have the same number of electrons.

    Bond Character

    • Bonds can be pure covalent, pure ionic, or have some character of both covalent and ionic.
    • Difference in EN (∆EN) determines the bond character.
    • Greater ∆EN means more significant ionic character.

    Examples of Ionic Compounds

    • Sodium Chloride(NaCl)
    • Has a melting point of 801°C.
    • Is a good conductor of electricity when molten or aqueous.

    Examples of Molecular Compounds

    • Carbon Dioxide(CO2)
    • Has a melting point of -78°C.
    • Is a poor conductor of electricity.

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