Organic Chemistry: Type of Reactions and Alcohol Classification

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Questions and Answers

What color change would indicate a positive phenol test using pH paper?

  • Red to blue
  • Yellow to blue
  • Blue to red (correct)
  • Blue to green

What color change would signify a positive phenol test using Ferric Chloride?

  • Orange to black
  • Green to red
  • Pale yellow to purple (correct)
  • Clear to blue

Which test would confirm the presence of Methyl Ketone?

  • Ferric Chloride Test - Blue to red
  • Tollen’s Test (AgNH3, NaOH) - Silver mirror
  • Iodoform test (I2, NaOH) - Colorless to cloudy pale yellow (correct)
  • Phenol test - Blue to red

Which compound would not react with Br2?

<p>Alcohol (B)</p> Signup and view all the answers

Select the product of the reactions shown in questions 7-9.

<p>Option A (C)</p> Signup and view all the answers

What is the IUPAC name of the compound 2,3-dimethylpentane?

<p><strong>2,3-dimethylpentane</strong> (A)</p> Signup and view all the answers

Which type of reaction is demonstrated in questions 7-9?

<p>Addition reaction (B)</p> Signup and view all the answers

What is the oxidation product (X) of the given reaction?

<p>3 (C)</p> Signup and view all the answers

Which alcohol would not react with CrO42-?

<p>12 (B)</p> Signup and view all the answers

Which compound will react with Fe+3 ion in iron(III) chloride solution to give a purple color?

<p>C (D)</p> Signup and view all the answers

What is the name of the compound shown in the image?

<p>5-methylpentanone (D)</p> Signup and view all the answers

What is the IUPAC name of the given compound?

<p>2-methylbutanone (C)</p> Signup and view all the answers

What functional group is identified by the suffix '-ide' in the chemical name?

<p>Alkyl Halide (A)</p> Signup and view all the answers

In Lewis structures, what does the presence of a carbonyl group signify?

<p>Presence of C-(COO)-C bond (D)</p> Signup and view all the answers

What color change indicates a positive result in a bromine test for alkenes and alkynes?

<p>Orange to colorless (B)</p> Signup and view all the answers

Which compound undergoes a color change from orange to greenish blue in a Chromic Acid test?

<p>3° Alcohol (A)</p> Signup and view all the answers

What is the main product of combustion reactions of hydrocarbons?

<p>$CO_2$ and $H_2O$ (B)</p> Signup and view all the answers

Which functional group contains a bond -(COX)?

<p>Acid Halide (B)</p> Signup and view all the answers

What type of reaction is showcased in questions 7-9?

<p>Addition reaction (B)</p> Signup and view all the answers

Which compound(s) exemplifies a primary alcohol?

<p>Compound A (C)</p> Signup and view all the answers

What is the oxidation product (X) in the provided reaction?

<p>Aldehyde (A)</p> Signup and view all the answers

Which alcohol would not react with CrO4^2-?

<p>Tertiary alcohol (C)</p> Signup and view all the answers

What statement accurately describes the solubility of alcohols?

<p>Polarity of hydroxyl group makes alcohols to be soluble in water by forming hydrogen bonds (D)</p> Signup and view all the answers

Which compound reacts with Fe^3+ ions to give a purple color in FeCl3 solution?

<p>Compound C (B)</p> Signup and view all the answers

Which compound would form a yellow solid in the iodoform test but not react with Benedict’s reagent?

<p>Compound Y (D)</p> Signup and view all the answers

What is the product of the reactions shown in questions 20 and 21 from compounds A-D?

<p>Cannot be determined from the information given (A)</p> Signup and view all the answers

Which structural formula corresponds to the IUPAC name 'Propene'?

<p>A (A)</p> Signup and view all the answers

Which compound falls under the functional group 'Amphiphile'?

<p>Compound X (D)</p> Signup and view all the answers

Which compound is classified as an 'Amine'?

<p>Compound Z (C)</p> Signup and view all the answers

Which compound is likely to be classified as an 'Alkene'?

<p>Compound Y (B)</p> Signup and view all the answers

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Study Notes

Functional Groups

  • Identify functional groups presented in Lewis, Condensed, and Line-angle (skeletal) structures
  • Identify functional groups by suffix in chemical names
  • Examples of functional groups:
    • Ketone: contains C-(C=O)-C bonds
    • Aldehyde: contains C-(C=O)-H bonds
    • Alkyl Halide: X: Br – alkyl bromide, X: Cl – alkyl chloride, X: I – alkyl iodide, X: F – alkyl fluoride
    • Carboxylic Acid: contains C-(COOH) bond
    • Ester: contains C-(COO)-C bond
    • Amide: contains C-(CO2N)- bond
    • Nitrile: contains -(CN) bond
    • Acid Halide: contains -(COX) bond
    • Acid Anhydride: contains -(CO)O(CO)- bond

Lewis to Condensed Structures

  • Be able to match Lewis structure to the correct condensed structure and vice-versa

Safety Materials

  • Review safe practices for being in the laboratory

Reactions and Test Results

  • Hydrocarbons: Combustion
    • Balance combustion reactions
    • Products: carbon dioxide (CO2) and water (H2O)
  • Alkanes: Radical Halogenation (UV light)
    • Predict brominated products
  • Alkene/Alkynes (unsaturation)
    • Bromine test (no UV): Orange → colorless (POSITIVE test)
    • Baeyer's Test (Potassium Permanganate): Purple → brown (POSITIVE test)
  • Alcohols
    • Identify 1°, 2°, and 3° alcohols
    • Chromic Acid (H2CrO4) test: orange → greenish blue (POSITIVE test)
    • Phenol test: pH paper (Blue → RED, POSITIVE test)
    • Phenol test: Ferric Chloride (pale yellow → purple, POSITIVE test)
  • Aldehydes and Ketones
    • Methyl Ketone: Iodoform test (I2, NaOH) (colorless → cloudy pale yellow, POSITIVE test)
    • Aldehyde: Tollen's Test (AgNH3, NaOH) (→ silver mirror, POSITIVE test)

Exam Questions

  • Classification of compounds according to their functional groups
  • IUPAC naming of compounds
  • Predicting products of reactions
  • Identifying type of reaction (Elimination, Addition, Replacement, etc.)
  • Solubility of alcohols
  • Reactivity of compounds with certain reagents (Br2, Fe+3, etc.)

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