Organic Chemistry Synthesis and Properties Quiz
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Questions and Answers

What is the state of unbranched alkanes methane, ethane, propane, and butane at room temperature?

  • Solids
  • Gases (correct)
  • Plasmas
  • Liquids

Why do branched alkanes normally exhibit lower boiling points than unbranched alkanes of the same carbon content?

  • Due to greater van der Waals forces in unbranched alkanes (correct)
  • Due to lower van der Waals forces in unbranched alkanes
  • Due to the presence of triple bonds in unbranched alkanes
  • Due to the presence of double bonds in unbranched alkanes

Why are alkanes almost completely insoluble in water?

  • Due to weaker van der Waals forces between alkane and water molecules (correct)
  • Due to the presence of triple bonds in alkanes
  • Due to stronger van der Waals forces between alkane and water molecules
  • Due to the presence of double bonds in alkanes

What did Friedrich Wohler achieve in 1828?

<p>Synthesized an organic compound from an inorganic compound (D)</p> Signup and view all the answers

What is the general formula for open-chain alkanes?

<p>CnH2n + 2 (C)</p> Signup and view all the answers

What is the trend in boiling points of alkanes as the number of carbon atoms increases?

<p>Boiling point increases with more carbon atoms (C)</p> Signup and view all the answers

What functional group is formed by removing a hydrogen atom from the molecule of an alkane?

<p>Alkyl group (D)</p> Signup and view all the answers

Flashcards

State of unbranched alkanes (methane, ethane, propane, butane) at room temperature

Unbranched alkanes, methane, ethane, propane, and butane, are gases at room temperature.

Branched alkanes boiling point vs. unbranched

Branched alkanes have lower boiling points than unbranched alkanes with the same number of carbon atoms, due to weaker van der Waals forces.

Solubility of alkanes in water

Alkanes are almost completely insoluble in water due to weaker van der Waals forces between alkane and water molecules.

Wöhler's 1828 achievement

Wöhler synthesized an organic compound (urea) from an inorganic compound (ammonium cyanate).

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General formula for open-chain alkanes

The general formula for open-chain alkanes is CnH2n+2.

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Trend in alkane boiling points

As the number of carbon atoms in an alkane increases, the boiling point also increases.

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Functional group from removing an alkane H

Removing a hydrogen atom from an alkane molecule forms an alkyl group.

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Study Notes

States of Alkanes at Room Temperature

  • Methane, ethane, propane, and butane are all alkanes.
  • Methane (C1H4) and ethane (C2H6) are gases at room temperature.
  • Propane (C3H8) is a gas, but may be stored as a liquid under pressure.
  • Butane (C4H10) can exist as a gas at room temperature or as a liquid under pressure.

Boiling Points of Branched vs. Unbranched Alkanes

  • Branched alkanes typically have lower boiling points compared to unbranched alkanes with the same carbon count.
  • The branching in alkanes reduces surface area, resulting in weaker van der Waals forces.
  • Weaker intermolecular forces lead to lower energy required for boiling.

Insolubility of Alkanes in Water

  • Alkanes are predominantly nonpolar molecules due to their hydrocarbon nature.
  • Water is a polar solvent, and polar and nonpolar substances do not mix.
  • Alkanes' lack of polarity prevents them from forming hydrogen bonds with water.

Friedrich Wohler's Achievement in 1828

  • Friedrich Wohler synthesized urea from ammonium cyanate.
  • This reaction challenged the belief that organic compounds could only be produced by living organisms (vitalism).
  • Wohler's work marked a significant milestone in organic chemistry.

General Formula for Open-Chain Alkanes

  • The general formula for open-chain (straight-chain) alkanes is CnH2n+2.
  • "n" represents the number of carbon atoms in the alkane.

Trend in Boiling Points of Alkanes

  • As the number of carbon atoms in alkanes increases, boiling points generally rise.
  • Increased molecular weight and van der Waals interactions contribute to higher boiling points.

Functional Group from Alkanes

  • A functional group formed by removing one hydrogen atom from an alkane is called an alkyl group.
  • Alkyl groups serve as the backbone for many organic compounds, maintaining hydrocarbon characteristics.

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Description

Test your knowledge of organic chemistry with this quiz on the synthesis of organic compounds and the properties of carbon atoms. Explore the different classes of organic compounds and their functional groups, including alkyl groups and halides.

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