Organic Chemistry Overview and Naming

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Questions and Answers

What is produced when ethene reacts with bromine?

  • Ethanol
  • Polyethene
  • Brine
  • 1,2-dibromoethane (correct)

What conditions facilitate the hydration of alkenes to produce alcohols?

  • High temperature and low pressure
  • High temperature and high pressure with phosphoric (V) acid (correct)
  • Room temperature and atmospheric pressure
  • Low temperature and low pressure

Which type of reaction involves alkenes combining to form long molecules?

  • Addition polymerisation (correct)
  • Decomposition reaction
  • Addition reaction
  • Substitution reaction

What is the role of phosphoric (V) acid in the hydration of alkenes?

<p>It acts as a catalyst (A)</p> Signup and view all the answers

What is the chemical formula for ethene?

<p>C2H4 (D)</p> Signup and view all the answers

What is the result of the catalytic addition of steam to ethene?

<p>Ethanol and carbon dioxide (A)</p> Signup and view all the answers

Which microorganisms are involved in the fermentation of glucose?

<p>Yeast (A)</p> Signup and view all the answers

What happens to the solubility of alcohols as the number of carbon atoms in the molecule increases?

<p>It decreases (B)</p> Signup and view all the answers

Which of the following is NOT a use of ethanol?

<p>In plastic production (D)</p> Signup and view all the answers

Which alcohol has the molecular formula C3H7OH?

<p>Propanol (C)</p> Signup and view all the answers

What is the effect on the boiling point of alcohols as the carbon chain length increases?

<p>Boiling point increases (A)</p> Signup and view all the answers

Which of the following statements is true about the fermentation of glucose?

<p>It produces ethanol and carbon dioxide (A)</p> Signup and view all the answers

What is the structural formula of methanol?

<p>H3C-OH (D)</p> Signup and view all the answers

Which carboxylic acid has the highest boiling point?

<p>Butanoic acid (B)</p> Signup and view all the answers

What is the product when ethanoic acid reacts with sodium hydroxide?

<p>Sodium acetate and water (C)</p> Signup and view all the answers

What type of acid are carboxylic acids classified as?

<p>Weak acids (A)</p> Signup and view all the answers

Which process is used to produce an ester from a carboxylic acid?

<p>Esterification (A)</p> Signup and view all the answers

What is the role of concentrated sulfuric acid in the reaction between ethanoic acid and ethanol?

<p>As a catalyst (B)</p> Signup and view all the answers

Which of the following statements about carboxylic acids is incorrect?

<p>They completely ionize in solution. (B)</p> Signup and view all the answers

When carboxylic acids react with carbonates, what gas is released?

<p>Carbon dioxide (C)</p> Signup and view all the answers

Which of the following carboxylic acids has the lowest boiling point?

<p>Methanoic acid (C)</p> Signup and view all the answers

What type of reaction do alkenes primarily undergo?

<p>Addition reactions (B)</p> Signup and view all the answers

Which statement accurately describes the reactivity of alkanes?

<p>They are generally unreactive. (A)</p> Signup and view all the answers

How does the flammability of alkenes compare to that of alkanes?

<p>Alkenes produce a smokier flame. (A)</p> Signup and view all the answers

What characteristic feature do alcohols possess?

<p>Hydroxyl group (D)</p> Signup and view all the answers

What is the general formula for alcohols?

<p>C_nH_2n+1OH (C)</p> Signup and view all the answers

What type of reaction do alkanes undergo with aqueous bromine?

<p>No reaction (A)</p> Signup and view all the answers

Which of the following statements about polymerisation is true?

<p>Alkenes can undergo polymerisation. (B)</p> Signup and view all the answers

What differentiates alkanes from alkenes in terms of molecular structure?

<p>Alkanes contain single bonds. (D)</p> Signup and view all the answers

Which compound has a boiling point of 97°C?

<p>Propanol (D)</p> Signup and view all the answers

What is produced when ethanol undergoes combustion?

<p>Carbon dioxide and water vapour (C)</p> Signup and view all the answers

What is the primary product of the complete oxidation of a primary alcohol?

<p>Carboxylic acid (D)</p> Signup and view all the answers

Which alcohol is slightly soluble in water?

<p>Butanol (C)</p> Signup and view all the answers

Which reagents are needed for the oxidation of ethanol?

<p>Oxygen and heat (B)</p> Signup and view all the answers

What is the solubility of methanol in water?

<p>Very soluble (D)</p> Signup and view all the answers

Which of the following statements correctly describes the physical state of alcohols at room temperature?

<p>All alcohols are liquids (B)</p> Signup and view all the answers

Which alcohol has the highest boiling point according to the provided data?

<p>Butanol (B)</p> Signup and view all the answers

Which molecular formula corresponds to butene?

<p>C4H8 (D)</p> Signup and view all the answers

Which structural formula represents propene?

<p>H H H C C C H H (B)</p> Signup and view all the answers

What is the boiling point of methylpropene?

<p>-6.9 áµ’C (C)</p> Signup and view all the answers

What state are ethene, propene, and butene at room temperature?

<p>Gases (D)</p> Signup and view all the answers

Which of the following is a characteristic of butene?

<p>Linear structure (D)</p> Signup and view all the answers

Which is the correct molecular formula for ethene?

<p>C2H4 (C)</p> Signup and view all the answers

Which structural formula depicts the correct arrangement of carbon atoms in butene?

<p>H H C C C C H H H (C)</p> Signup and view all the answers

Which of the following correctly describes the relationship between butene and methylpropene?

<p>Methylpropene is a branched-chain version of butene (D)</p> Signup and view all the answers

What is the molecular formula for propene?

<p>C3H6 (D)</p> Signup and view all the answers

Which factor distinguishes straight-chain alkenes from branched-chain alkenes?

<p>Arrangement of carbon atoms (C)</p> Signup and view all the answers

Flashcards

Bromination of Alkenes

A chemical reaction where an alkene reacts with bromine, resulting in the formation of a dibromoalkane. This reaction can be used to detect the presence of unsaturated hydrocarbons.

Addition Reaction: Hydration of Alkenes

A type of chemical reaction where two or more molecules combine to form a larger molecule, without the loss of any atoms. In this case, alkenes react with water in the presence of an acid catalyst, forming an alcohol.

Addition Polymerisation

A type of addition reaction where many small alkene molecules join together to form a long chain polymer. This reaction requires high temperature, pressure, and a catalyst.

Alkene

A compound containing a carbon-carbon double bond (C=C).

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Polymer

A large molecule formed by the joining of many smaller repeating units called monomers.

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Alkanes' Reactivity

Alkanes are generally unreactive due to strong C-H bonds.

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Alkenes Reactivity

Alkenes are highly reactive due to the presence of a double bond, making them susceptible to attack by other molecules.

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Substitution Reaction

A type of reaction where an atom or group of atoms in a molecule is replaced by another atom or group.

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Addition Reaction

A type of reaction where a molecule is added to a double or triple bond.

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Alcohols

Alcohols are a type of organic compound that contain a hydroxyl (-OH) functional group.

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Ethanol Production: Fermentation

Ethanol can be produced through fermentation of sugars by yeast.

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What is an alkene?

A hydrocarbon containing a carbon-carbon double bond.

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What is ethene?

The simplest alkene with the molecular formula C2H4.

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What is the general molecular formula for alkenes?

The molecular formula of an alkene can be represented as CnH2n, where 'n' represents the number of carbon atoms.

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What is a structural formula?

A structural representation of a molecule that shows the arrangement of atoms and bonds in space.

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What is structural isomerism?

A type of isomerism where the arrangement of atoms and bonds is different.

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What are structural isomers?

Isomers that have the same molecular formula but different arrangements of atoms and bonds in space.

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What is butene?

A straight-chain alkene with the molecular formula C4H8.

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What is methylpropene?

A branched-chain alkene with the molecular formula C4H8, a structural isomer of butene.

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How do the physical properties of alkenes vary?

The physical properties of alkenes are influenced by the number of carbon atoms and the presence of the double bond.

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What is a dot and cross diagram?

A diagram that represents the arrangement of electrons in a molecule, showing shared and unshared electrons.

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Catalytic Hydration of Ethene

The process where ethene reacts with steam in the presence of a catalyst (phosphoric acid) and high temperature and pressure to produce ethanol.

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Fermentation of Glucose

A process where microorganisms (like yeast) break down glucose in the absence of oxygen, resulting in the production of ethanol and carbon dioxide.

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Uses of Ethanol

Ethanol is a versatile chemical with various applications, including as an ingredient in alcoholic beverages, a solvent for various substances, and a biofuel.

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Methanol (CH3OH)

Methanol is the simplest alcohol, having one carbon atom and a hydroxyl group (OH).

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Ethanol (C2H5OH)

Ethanol has two carbon atoms and a hydroxyl group (OH).

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Propanol (C3H7OH)

Propanol has three carbon atoms and a hydroxyl group (OH).

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Butanol (C4H9OH)

Butanol has four carbon atoms and a hydroxyl group (OH).

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Physical Properties of Alcohols

As the carbon chain in alcohols gets longer, their solubility in water decreases, while their boiling point increases.

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How does the force of attraction between molecules change going down the homologous series of alcohols?

The attraction between molecules in a substance increases as you move down the homologous series of alcohols (methanol, ethanol, propanol, butanol, etc.) because the molecules become larger and have stronger temporary dipole-induced dipole interactions, leading to higher boiling points and changed solubility.

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What is an alcohol?

Alcohols are organic compounds containing a hydroxyl (-OH) functional group attached to a carbon atom. This functional group imparts unique properties to alcohols.

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What is the product of the complete oxidation of a primary alcohol?

The complete oxidation of a primary alcohol, such as ethanol, results in the formation of a carboxylic acid and water. The process involves the breaking of C-H bonds and the formation of C=O bonds.

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What happens when alcohols combust?

Combustion of alcohols is a reaction with oxygen to produce carbon dioxide and water vapor. This exothermic reaction releases energy in the form of heat and light.

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How does the solubility of alcohols in water change with increasing chain length?

Solubility of alcohols in water decreases as the hydrocarbon chain length increases. The -OH group contributes to water solubility, but the longer non-polar hydrocarbon chain reduces it.

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What is a primary alcohol?

Primary alcohols have the -OH group attached to a carbon atom that is directly bonded to only one other carbon atom. This structural feature differentiates them from secondary and tertiary alcohols.

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Draw the structural formula of an alcohol with the molecular formula C4H10O.

The structural formula for an alcohol with the molecular formula C4H10O can be represented as CH3CH2CH2CH2OH (butanol). It is a primary alcohol with four carbon atoms.

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Give 1 physical property & 1 chemical property of butanol (C4H10O)

Butanol is a liquid at room temperature and is slightly soluble in water due to its longer carbon chain. It undergoes combustion to produce carbon dioxide, water, and energy. This is a chemical property.

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Carboxylic Acids: Weak Acids

Carboxylic acids are weak acids that only partially ionize in water, meaning they release hydrogen ions (H+) to a limited extent. This is represented by the equilibrium reaction of ethanoic acid, where it exists in both ionized and unionized forms.

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Boiling Point Trends in Carboxylic Acids

The boiling point of carboxylic acids increases as the carbon chain length increases. This is because the intermolecular forces (forces between molecules) become stronger with a longer chain. Larger molecules have more surface contact and stronger van der waals forces.

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Reactions of Carboxylic Acids

Carboxylic acids react with various substances due to their acidic nature. They react with reactive metals, carbonates, and bases, producing salts and other products. This is due to the presence of a carboxyl group (COOH) which can donate a proton (H+).

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Esterification Reaction

Carboxylic acids react with alcohols (like ethanol) in the presence of an acid catalyst (e.g., concentrated sulfuric acid) to form esters and water. This reaction is called esterification.

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Carboxylates: Salts of Carboxylic Acids

The salts produced from reactions of carboxylic acids with metals or bases are called carboxylates. For example, sodium ethanoate is a carboxylate salt formed from the reaction of ethanoic acid with sodium hydroxide.

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Solubility of Carboxylic Acids

Carboxylic acids are generally soluble in water due to the formation of hydrogen bonds between the carboxyl group (COOH) and the water molecules. However, solubility decreases as the carbon chain length increases.

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Ethanoic Acid: A Weak Acid

Ethanoic acid is a weak acid. It ionizes only partially in aqueous solution, meaning it doesn't fully break down into its ions.

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Ethanoates: Salts of Ethanoic acid

The salts of ethanoic acid are specifically called ethanoates. Sodium ethanoate and magnesium ethanoate are examples of such salts.

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Study Notes

Organic Chemistry Overview

  • Organic chemistry is the study of carbon-containing compounds.
  • Organic compounds can be naturally occurring (e.g., proteins, glucose) or synthetic (e.g., plastics, detergents, medicines).
  • Hydrocarbons are organic compounds containing only carbon and hydrogen.
  • Other elements, such as oxygen, nitrogen, and sulfur, can also be present in organic compounds.

Homologous Series

  • A homologous series is a family of organic compounds with the same functional group and similar chemical properties.
  • Alkanes, alkenes, alcohols, and carboxylic acids are examples of homologous series.

Functional Groups

  • A functional group is an atom or group of atoms that gives a molecule its characteristic properties.
  • Alkanes do not have functional groups; they only have C-C and C-H bonds.
  • Alkenes contain carbon-carbon double bonds.
  • Alcohols contain a hydroxyl group (-OH).
  • Carboxylic acids contain a carboxyl group (-COOH).

Naming Organic Compounds

  • The names of organic compounds are made of two parts:
    • A prefix, which indicates the number of carbon atoms.
      • Examples: Meth-, Eth-, Prop-, But-.
    • A suffix, which indicates the homologous series the compound belongs to.
      • Examples: -ane (alkane), -ene (alkene), -ol (alcohol), -oic acid (carboxylic acid).

Alkanes

  • Alkanes are a homologous series of saturated hydrocarbons.
  • They only contain carbon-carbon single bonds.
  • The general formula for alkanes is CnH2n+2, where n is the number of carbon atoms.
  • Examples: Methane (CH4), Ethane (C2H6), Propane (C3H8), Butane (C4H10).
  • Properties include low melting and boiling points, insolubility in water, and solubility in organic solvents.
  • Melting and boiling points increase as the number of carbon atoms increases.

Alkenes

  • Alkenes are a homologous series of unsaturated hydrocarbons.
  • They contain one or more carbon-carbon double bonds.
  • The general formula for alkenes is CnH2n, where n is the number of carbon atoms.
  • Examples: Ethene (C2H4), Propene (C3H6), Butene (C4H8).
  • Properties include being gases at room temperature, boiling points increase as the number of carbon atoms increases, and they undergo addition reactions.

Alcohols

  • Alcohols are a homologous series of organic compounds containing a hydroxyl functional group (-OH).
  • The general formula for alcohols is CnH2n+1OH, where n is the number of carbon atoms.
  • Examples: Methanol (CH3OH), Ethanol (C2H5OH), Propanol (C3H7OH), Butanol (C4H9OH).
  • Properties include varying solubility in water (decreasing as the number of carbon atoms increases), increasing boiling points as the number of carbon atoms increases.

Carboxylic Acids

  • Carboxylic acids are a homologous series of organic acids containing a carboxyl functional group (-COOH).
  • The general formula for carboxylic acids is CnH2n+1COOH, where n is the number of carbon atoms.
  • Examples: Methanoic acid (HCOOH), Ethanoic acid (CH3COOH), Propanoic acid (C2H5COOH), Butanoic acid (C3H7COOH).
  • Properties include being weak acids, increasing boiling points as the number of carbon atoms increases, and being soluble in water.
  • Carboxylic acids can be produced by oxidizing alcohols.

Addition Reactions

  • Addition reactions involve adding atoms or groups of atoms to a molecule.
  • Alkenes and some other unsaturated organic compounds undergo addition reactions readily.

Esterification

  • Carboxylic acids and alcohols react with a catalyst to form esters and water. Esters are used extensively in perfumes and flavorings.

Isomerism

  • Isomers are compounds with the same molecular formula but different structural formulas, resulting in different physical properties (e.g., melting point, boiling point).
  • Alkanes can have structural isomers.

Complete Combustion of Alkanes and Alkenes

  • Both groups produce carbon dioxide and water when burnt in excess oxygen.

Questions

  • Some questions regarding the structures, properties, and reactions of organic compounds are included in the slides.

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