Organic Chemistry: Molecular Bonding & Formulas

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Questions and Answers

Which type of carbon-carbon bond has the shortest length and highest strength?

  • Single Bond
  • Double Bond
  • Ionic Bond
  • Triple Bond (correct)

In organic chemistry, carbon is typically tetravalent, meaning it forms four bonds.

True (A)

Provide the molecular formula for butyric acid.

C4H8O2

A carbon-hydrogen bond is considered a ______ single bond.

<p>non-polar</p> Signup and view all the answers

Match the following elements with their typical valency in organic compounds:

<p>Hydrogen = Monovalent (1) Oxygen = Divalent (2) Nitrogen = Trivalent (3) Carbon = Tetravalent (4)</p> Signup and view all the answers

Which of the following is an example of a condensed formula?

<p>CH3CH2CH2COOH (D)</p> Signup and view all the answers

In a skeletal formula, carbon atoms and most hydrogen atoms are explicitly drawn.

<p>False (B)</p> Signup and view all the answers

What term describes double bonds separated by a single bond?

<p>Conjugated (D)</p> Signup and view all the answers

What is the valency of halogens?

<p>Monovalent</p> Signup and view all the answers

In which arrangement are three double bonds located next to each other?

<p>Cumulative (C)</p> Signup and view all the answers

Flashcards

Single Bond

A bond where a single pair of electrons is shared between two atoms; C-H is an example.

Double Bond

Bond in which two pairs of electrons are shared between two atoms.

Triple Bond

A bond in which three pairs of electrons are shared between two atoms.

Isolated Double Bonds

Double bonds separated by more than one single bond.

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Conjugated Double Bonds

Double bonds separated by exactly one single bond.

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Cumulative Double Bonds

Double bonds that are directly adjacent to each other.

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Molecular Formula

Chemical formula that indicates only the type and number of atoms in a molecule, but does not show the bonding pattern.

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Empirical Formula

Shows the simplest whole number ratio of atoms in a compound.

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Condensed Formula

Atoms are listed in a way that suggests the structure, but does not show bonds.

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Displayed/Structural Formula

Shows all atoms and bonds to clearly show the connectivity of the molecule.

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Study Notes

  • Covalent bonds predominate

  • C-H is a single bond

  • C=C is a double bond

  • ≡C≡ is a triple bond

  • C-H is single and non-polar

  • C⁺ δ⁻Cl ⁻ single bond

  • Length: Single bond is the longest, triple bond is the shortest

  • Strength: Single bond is the weakest, triple bond is the strongest

Position of Double Bonds

  • Isolated double bonds: =C-C-C=C
  • Conjugated bond: =C-C=C
  • Cumulative: =C=C=

Number of Bonds Elements Can Have

  • Carbon: tetravalent (4)
  • Hydrogen: monovalent (1)
  • Oxygen, Sulfur: divalent (2)
  • Nitrogen: trivalent (3)
  • Halogens: monovalent (1)

Formulas in Organic Chemistry

  • Molecule = butyric acid

  • Molecular formula: C₄H₈O₂

  • Empirical formula (ratio): C₂H₄O

  • Condensed formula: CH₃CH₂CH₂COOH

  • Displayed (structural) formula: H-C-C-C-C=O with Hydrogens attached appropriately

  • Structural formula: CH₃-CH₂-CH₂-C

  • Skeletal formula: Zig-zag line with O attached

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