Organic Chemistry: Formulas and Isomerism

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Questions and Answers

What does the empirical formula represent in a molecule?

It represents the simplest whole number ratio of atoms in a molecule.

What information does a molecular formula provide?

It gives the actual number of atoms of different elements in a molecule.

How does a displayed formula differ from a structural formula?

A displayed formula shows every atom and every bond, while a structural formula shows the arrangement of atoms without detailing every bond.

What is the suffix for a compound that is a carboxylic acid?

<p>The suffix is -oic acid.</p> Signup and view all the answers

Describe structural isomerism in your own words.

<p>Structural isomerism occurs when molecules have the same molecular formula but different structural arrangements.</p> Signup and view all the answers

What characterizes chain isomerism and give an example?

<p>Chain isomerism is characterized by hydrocarbons organized differently, such as branched chains, like butane and isobutane.</p> Signup and view all the answers

Define stereoisomerism and explain its significance.

<p>Stereoisomerism involves molecules that have the same structural and molecular formula but differ in spatial arrangement.</p> Signup and view all the answers

What is positional isomerism and how does it affect compound properties?

<p>Positional isomerism occurs when the functional group is attached to the main chain at different positions, altering the chemical properties.</p> Signup and view all the answers

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Study Notes

Empirical Formula

  • Simplest whole number ratio of atoms in a molecule

Molecular Formula

  • Gives the actual number of atoms of different elements in a molecule

Displayed Formula

  • Shows every atom and every bond in a molecule

Structural Formula

  • Shows arrangement of atoms in a molecule without showing every bond

Skeletal Formula

  • Drawn as lines with each vertex being a carbon atom
  • Carbon atoms not drawn, assumed each C atom has all unspecified bonds as C-H

Suffixes for Organic Compounds

  • No double bonds - -ane
  • At least one double bond - -ene
  • An alcohol - -ol
  • An aldehyde - -al
  • A ketone - -one
  • A carboxylic acid - -oic acid

Prefixes for Functional Groups

  • CH3 group - methyl-
  • C2H5 group - ethyl-
  • C3H7 group - propyl-
  • C4H9 group - butyl-
  • Cl group - chloro-
  • Br group - bromo-
  • I group - iodo-

Structural Isomerism

  • Molecules have the same molecular formula but different structural formula

Positional Isomerism

  • Functional group is attached to the main chain at a different place

Functional Group Isomerism

  • Same atoms but a different functional group due to a different arrangement of atoms

Chain Isomerism

  • Hydrocarbon chain organised differently e.g. branched chains

Stereoisomerism

  • Molecules have the same structural and molecular formula, but have a different arrangement of atoms in space

E-Z Isomerism

  • Different arrangement of atoms around a carbon-carbon double bond
  • Z - two highest priority groups on the same side of the double bond
  • E - two highest priority groups on opposite sides of the double bond
  • Priority is determined by atomic number, higher atomic number = higher priority

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