Organic Chemistry: Acid-Catalyzed Reactions and Oxidation
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Questions and Answers

What type of reaction is used to form diols from alkenes?

  • Elimination reaction
  • Reduction reaction
  • Oxidation reaction (correct)
  • Substitution reaction
  • Which of the following is NOT a common electrophile source mentioned in the text?

  • NaOH (correct)
  • HBr
  • Br₂
  • H₂SO₄
  • In an electrophilic addition reaction, what type of intermediate is formed when the double bond is broken?

  • Radical
  • Enol
  • Carbanion
  • Carbocation (correct)
  • Which type of carbocation is the most stable according to the text?

    <p>Tertiary</p> Signup and view all the answers

    In an electrophilic addition reaction of a hydrogen halide, which product will be the major product?

    <p>The product formed via the most stable carbocation</p> Signup and view all the answers

    What is the purpose of the acid catalyst in the reaction shown in the first example?

    <p>To stabilize the carbocation intermediate</p> Signup and view all the answers

    What is the primary reason for the limited rotation around a carbon-carbon double bond?

    <p>The presence of a π-bond</p> Signup and view all the answers

    Which of the following best describes the geometry around the carbon atoms in a carbon-carbon double bond?

    <p>Trigonal planar</p> Signup and view all the answers

    How does bromine water react with alkenes (compounds with carbon-carbon double bonds)?

    <p>Bromine water changes color from orange-brown to colorless</p> Signup and view all the answers

    What type of stereoisomerism is observed in alkenes due to the limited rotation around the carbon-carbon double bond?

    <p>E-Z isomerism</p> Signup and view all the answers

    Which type of species is attracted to the high electron density of a carbon-carbon double bond?

    <p>Electrophiles</p> Signup and view all the answers

    What type of bond is formed between the carbon atoms in a carbon-carbon double bond?

    <p>A single σ-bond and a single π-bond</p> Signup and view all the answers

    What is the key feature of an electrophilic addition reaction involving alkenes?

    <p>The double bond is broken and replaced with single bonds to other atoms</p> Signup and view all the answers

    What is the purpose of using a nickel catalyst in the hydrogenation of alkenes to produce alkanes?

    <p>To increase the rate of the reaction and make it more efficient</p> Signup and view all the answers

    Which of the following statements about the test for unsaturation using bromine water is correct?

    <p>The bromine water is an electrophilic reagent that adds to the $\pi$ bond of the alkene</p> Signup and view all the answers

    What is the key difference between the products formed in the reactions of alkenes with halogens versus hydrogen halides?

    <p>Reaction with halogens produces di-substituted haloalkanes, while reaction with hydrogen halides produces mono-substituted haloalkanes</p> Signup and view all the answers

    What is the primary purpose of using catalytic hydrogenation in the manufacture of margarine from unsaturated vegetable oils?

    <p>To convert the unsaturated fatty acids into saturated fatty acids for a longer shelf life</p> Signup and view all the answers

    What is the key structural difference between alcohols and haloalkanes?

    <p>Alcohols contain a hydroxyl (-OH) group, while haloalkanes contain a halogen (e.g., Cl, Br, I) functional group</p> Signup and view all the answers

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