Organic Chemistry 331 - Chapter 6 Flashcards
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Questions and Answers

What is the organic product of the following reaction? Include hydrogen atoms in your structure.

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What is the product for the following reaction?

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Draw the structure of the alkene that reacts with HBr to give the alkyl bromide as the major organic product.

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For the following reaction, what are the first step's curved arrows and the organic and inorganic intermediate species?

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Draw the major organic product and select the correct IUPAC name for the organic reactant.

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What are the steps to add curved arrows to show the mechanism for the acid-catalyzed hydration of 3-methyl-1-butene?

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What is the organic product of the following reaction including hydrogen atoms in your structure?

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What is the neutral organic product of the following reaction?

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Draw the structures of the alkene and the alcohol that react to give the ether as the major organic product.

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What are the two major organic products of the following reaction?

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Draw the major organic product and select the correct IUPAC name for the organic reactant.

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Draw the structures of two stereoisomeric alkenes that would give 3-hexanol as the only major product.

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Draw the major organic product for each of the hydroboration-oxidation reactions.

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What details are necessary to show the mechanism for cyclohexene reacting with bromine?

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What is the product of the following reaction? Draw all hydrogen atoms.

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Draw the three alkenes of formula C5H10 that will form 2-methylbutane upon hydrogenation.

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For the following hydrogenation reaction, what is the correct organic product and its IUPAC name?

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For the following hydrogenation reaction, what is the correct product and its IUPAC name?

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What is the major organic product(s) and correct IUPAC name for the organic reactant?

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Predict the product of treating the given alkene with the specified reagent.

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What is the oxidation product of treating dihydronaphthalene with the reagents shown? Include H's on chirality centers.

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What is the oxidation product of treating the given alkene with the specified reagent?

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Identify the reactant, reagent, and solvent used to synthesize the product.

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Which reagents can be used to effect addition to a double bond?

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Complete the mechanism for the reaction by adding curved arrows with Hg(OAc)2, THF, H2O and NaBH4, OH-.

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Draw the structure of the Hg-containing compound and the final alcohol product.

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Study Notes

Organic Reaction Predictions

  • Predict products for various organic reactions, ensuring all hydrogen atoms are correctly represented on carbon atoms.
  • Identify mechanisms and include curved arrows to illustrate the flow of electrons during reactions.

Major Organic Products

  • Determine the major products formed from alkene reactions with agents like HBr, showing the structures clearly.
  • For reactions yielding multiple products, draw all possible major structures and indicate correct IUPAC naming.

Stereochemistry and Isomerism

  • Understand the formation of stereoisomers through reactions such as hydroboration followed by oxidation, specifically resulting in compounds like 3-hexanol.
  • Draw and differentiate between structural isomers that may lead to the same product upon hydrogenation.

Mechanistic Insights

  • Break down reactions step-by-step to illustrate intermediates and products, paying attention to nonbonding electrons and charge states.
  • Mechanisms often involve specific reactants and catalysts which influence the final products.

Specific Reactions & Conditions

  • Recognize key reagents (e.g., mCPBA for oxidation or hydroboration with alkaline H2O2).
  • Pay close attention to reaction conditions, such as temperatures and solvents, that can affect product formation.

Application of Reaction Types

  • Utilize transformation types (oxymercuration-demercuration, acid-catalyzed hydration) for selective product formation.
  • Understand how different reagents affect regioselectivity and stereoselectivity in product outcomes.

Product and Reactant Structures

  • Draw detailed structures for given products and corresponding reactants, ensuring clarity in presenting all hydrogen atoms.
  • Differentiate reactants, solvents, and products in complex reaction schemes for clarity on synthesis pathways.

Overall Reaction Understanding

  • Mastery of organic reactions includes predicting outcomes based on starting materials, mechanisms, reagents, and applying IUPAC naming conventions accurately.
  • Practice drawing mechanisms and major products consistently to reinforce learning and application of concepts.

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Test your knowledge of organic reactions with these flashcards from Organic Chemistry 331, Chapter 6. Focus on predicting organic products and including hydrogen atoms in your structures. This interactive quiz will help enhance your understanding of reaction mechanisms and product formation.

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