Orbital Hybridization 2

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Questions and Answers

What is the hybridization of the carbon atom in CF4?

  • sp
  • sp2
  • sp3 (correct)
  • sp3d

Which molecule is incorrectly matched with its molecular geometry?

  • CF4 - tetrahedral
  • BeBr2 - linear
  • NH3 - tetrahedral
  • H2O - tetrahedral (correct)

Identify the molecular shape of NF3.

  • Trigonal planar
  • Octahedral
  • Bent
  • Trigonal pyramidal (correct)

How many sigma (σ) and pi (π) bonds are present in a molecule with a triple bond?

<p>1 σ, 2 π (C)</p> Signup and view all the answers

Which of the following represents a linear arrangement of atoms?

<p>CO2 (B)</p> Signup and view all the answers

Which type of hybridization occurs in the carbon atom of ethylene (C2H4)?

<p>sp2 (A)</p> Signup and view all the answers

What is the geometry of AsF5?

<p>Trigonal bipyramidal (C)</p> Signup and view all the answers

Which of the following statements about sigma and pi bonds is incorrect?

<p>Single bonds consist of both sigma and pi bonds. (D)</p> Signup and view all the answers

What is the hybridization of carbon in chloroform (CHCl3)?

<p>sp3 (A)</p> Signup and view all the answers

What is the molecular geometry of a compound with sp2 hybridization?

<p>Trigonal planar (B)</p> Signup and view all the answers

In which molecular shape do bond angles of around 90 degrees and 120 degrees exist?

<p>Trigonal bipyramidal (A)</p> Signup and view all the answers

What characterizes a sigma bond compared to a pi bond?

<p>Sigma bonds involve the end-to-end overlap of orbitals. (D)</p> Signup and view all the answers

Which type of hybridization involves the bonding of six equivalent orbitals?

<p>sp3d2 (A)</p> Signup and view all the answers

How many equivalent bonds does a carbon atom typically form when it is sp3 hybridized?

<p>4 (B)</p> Signup and view all the answers

In ethene (C2H4), what type of bonding is present between the two carbon atoms?

<p>One sigma and one pi bond (C)</p> Signup and view all the answers

What is the bond angle in a tetrahedral molecular geometry?

<p>109.5 degrees (B)</p> Signup and view all the answers

What hybridization is observed in phosphorus pentachloride (PCl5)?

<p>sp3d (B)</p> Signup and view all the answers

In the molecular geometry of SF6, which of the following describes the spatial arrangement of the hybrid orbitals?

<p>Octahedral (C)</p> Signup and view all the answers

What is the bond angle between the axial and equatorial bonds in PCl5?

<p>90 degrees (C)</p> Signup and view all the answers

In the Lewis structure of Boron trifluoride (BF3), how many valence electrons does boron have?

<p>3 (B)</p> Signup and view all the answers

What type of hybridization is required for the bonding in Boron trifluoride?

<p>sp2 (A)</p> Signup and view all the answers

Which of the following statements is true regarding sp3d hybridization?

<p>It involves the mixing of one s, three p, and one d orbital. (B)</p> Signup and view all the answers

What shape does SF6 exhibit due to its hybridization?

<p>Octahedral (C)</p> Signup and view all the answers

Which hybrid orbital arrangement allows for bond angles of 120 degrees in a molecule?

<p>Trigonal planar (B)</p> Signup and view all the answers

What is the hybridization and bond arrangement of the carbon atom in a molecule with a C≡C triple bond?

<p>The carbon atom is sp hybridized and has a linear bond arrangement.</p> Signup and view all the answers

In the molecule CF4, how many sigma bonds are formed, and what is the hybridization of the carbon atom?

<p>CF4 has 4 sigma bonds and the carbon atom is sp3 hybridized.</p> Signup and view all the answers

Describe the number and type of bonds associated with the carbon atom in a C=O double bond.

<p>The carbon atom forms 3 sigma bonds and 1 pi bond in a C=O double bond.</p> Signup and view all the answers

In the hybridization of phosphorus in PCl5, what geometry do the hybrid orbitals achieve?

<p>The hybrid orbitals achieve a trigonal bipyramidal geometry.</p> Signup and view all the answers

What incorrect molecular geometry is associated with NH3 according to the content provided?

<p>NH3 is incorrectly said to have a tetrahedral geometry.</p> Signup and view all the answers

How does the electron configuration of sulfur contribute to its hybridization in SF6?

<p>Sulfur has six valence electrons and undergoes hybridization to form six sp3d2 orbitals.</p> Signup and view all the answers

How many sigma and pi bonds are found in the molecule C≡C?

<p>C≡C contains 1 sigma bond and 2 pi bonds.</p> Signup and view all the answers

Which type of hybridization is required for the bonding in PF3, and what is its molecular geometry?

<p>PF3 has sp3 hybridization and a trigonal pyramidal molecular geometry.</p> Signup and view all the answers

Explain the significance of electron promotion in the formation of sp3d hybrid orbitals in PCl5.

<p>Electron promotion allows phosphorus to use its 3d orbitals in bonding, enabling it to form five equivalent bonds.</p> Signup and view all the answers

Identify the hybridization of the carbon atom in ethylene (C2H4) and describe its bond types.

<p>The carbon atom in ethylene is sp2 hybridized, forming 4 sigma bonds and 1 pi bond.</p> Signup and view all the answers

Describe how the hybridization of boron in boron trifluoride contributes to its reactivity.

<p>Boron in BF3 hybridizes to form sp2 orbitals and has a sextet, making it an electron-deficient Lewis acid.</p> Signup and view all the answers

What is the molecular geometry of a molecule with sp hybridization and how does it compare to sp3?

<p>A molecule with sp hybridization is linear, while sp3 hybridization results in a tetrahedral geometry.</p> Signup and view all the answers

Why does the octet rule not apply to the hybridization of d orbitals?

<p>The octet rule is more applicable to main group elements, and d orbitals can accommodate more than eight electrons.</p> Signup and view all the answers

What shape does SF6 have and how is it related to its hybridization?

<p>SF6 has an octahedral shape due to its sp3d2 hybridization.</p> Signup and view all the answers

Which elements have their d orbitals involved in hybridization for forming PCl5?

<p>The phosphorus atom utilizes its 3d orbitals in the hybridization for PCl5.</p> Signup and view all the answers

What is the hybridization and shape of the central atom in Boron trifluoride?

<p>Boron trifluoride (BF3) has an sp2 hybridization and a trigonal planar shape.</p> Signup and view all the answers

Describe the bond angles associated with sp3 hybridization.

<p>The bond angles associated with sp3 hybridization are approximately 109.5 degrees.</p> Signup and view all the answers

How many equivalent bonds does a carbon atom form when it is sp2 hybridized, and what is the resulting geometry?

<p>A carbon atom that is sp2 hybridized forms three equivalent bonds, resulting in a trigonal planar geometry.</p> Signup and view all the answers

Given that a carbon atom in a molecule has a C=C double bond, what is its hybridization and shape?

<p>The carbon atom with a C=C double bond is sp2 hybridized and exhibits a trigonal planar shape.</p> Signup and view all the answers

What is the hybridization and arrangement of the five orbitals in a molecule with trigonal bipyramidal geometry?

<p>Trigonal bipyramidal geometry corresponds to sp3d hybridization.</p> Signup and view all the answers

Identify the hybridization of the central atom in a tetrahedral molecule and the typical bond angle.

<p>In a tetrahedral molecule, the central atom is sp3 hybridized, and the typical bond angle is about 109.5 degrees.</p> Signup and view all the answers

In the hybridization of a molecule with six equivalent bonds, what is the hybridization and molecular shape?

<p>The hybridization is sp3d2, corresponding to an octahedral shape.</p> Signup and view all the answers

What is the significance of the octet rule in determining the hybridization of the central atom in chloroform (CHCl3)?

<p>The central carbon atom in chloroform obeys the octet rule by forming four equivalent bonds, which means it is sp3 hybridized.</p> Signup and view all the answers

Flashcards

Sp2 hybridization

A carbon atom forming 3 equivalent bonds and a double bond, uses sp2 hybrid orbitals.

Sp hybridization

A carbon atom forming 1 bond with a terminal carbon, 1 with adjacent carbon and 2 more bonds with the terminal carbon uses sp hybrid orbitals.

Sigma (σ) bonds

A covalent bond formed by head-on or end-to-end overlap of atomic orbitals.

Pi (Ï€) bonds

A covalent bond formed by side-to-side overlap of atomic orbitals.

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Incorrectly matched molecule geometry (central atom)

In the given options for this question - CF4 - tetrahedral, BeBr2 - linear, H2O - tetrahedral, NH3 - tetrahedral, PF3 - octahedral, only PF3 has an incorrect match

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Incorrect molecular geometries

NF3 - trigonal planar is incorrect. Other listed molecules have correct matches.

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Linear molecule

A molecule with an arrangement of atoms along a straight line, like in Carbon Dioxide (CO2).

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Sp3 hybridization

Used by the carbon atom in forming 4 single bonds, as in CF4 molecule

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Orbital hybridization in Boron trifluoride

Boron trifluoride (BF3) has sp2 hybridization, meaning the boron atom uses 2 p orbitals and 1 s orbital to form 3 equivalent hybrid orbitals.

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Orbital Hybridization Summary

Different numbers of electron orbitals around an atom result in unique hybridisation and shapes.

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Chloroform's Hybridization

Chloroform (CHCl3) has a central carbon atom with four equivalent bonds, which results in sp3 hybridization.

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Hybridization in Carbon-Carbon Bonds

Different arrangements of bonds around carbon atoms influence the hybridization, directly impacting molecular shapes.

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Central Atom Bonding

The number of bonds formed by a central atom determines its hybridization.

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Why does the octet rule fail with d orbitals?

The octet rule, which predicts that atoms gain or lose electrons to achieve a stable outer shell with eight electrons, works well with p orbitals but not with d orbitals.

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What is sp3d hybridization?

In sp3d hybridization, one s, three p and one d atomic orbital on a central atom combine to form five equivalent hybrid orbitals. This allows the atom to form five bonds, like in PCl5.

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Describe the shape of PCl5.

PCl5 has a trigonal bipyramidal shape. There are three equatorial P-Cl bonds in the same plane at 120° angles, and two axial P-Cl bonds perpendicular to this plane at 90° angles.

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What is sp3d2 hybridization?

In sp3d2 hybridization, one s, three p and two d atomic orbitals on a central atom combine to form six equivalent hybrid orbitals. This allows the atom to form six bonds, like in SF6.

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What is the shape of SF6?

SF6 has an octahedral shape with bond angles of 90° between the six hybrid orbitals.

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Why is Boron trifluoride (BF3) an electrophile?

Boron has only three valence electrons and needs two more to achieve the stable octet configuration. This electron deficiency makes BF3 an electrophile, meaning it seeks electrons to form bonds.

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What is the shape of a molecule with sp3 hybridization?

A molecule with sp3 hybridization will have a tetrahedral shape with bond angles of approximately 109.5 degrees.

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What is the shape of a molecule with sp2 hybridization?

A molecule with sp2 hybridization will have a trigonal planar shape, with bond angles of 120 degrees.

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How do central atoms influence molecule shape?

The number of bonds a central atom forms directly influences its hybridization and ultimately the shape of the molecule.

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What are the key factors that determine hybridization?

The number of bonds an atom forms and the presence of lone pairs contribute to determining hybridization.

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What is the shape of PCl5?

PCl5 has a trigonal bipyramidal shape. There are three equatorial P-Cl bonds in the same plane at 120° angles, and two axial P-Cl bonds perpendicular to this plane at 90° angles.

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How does the geometry of BF3 explain its reactivity?

The trigonal planar geometry of BF3, with 120° bond angles, arises from its sp2 hybridization. This geometry leaves the boron atom with an empty p orbital, which can readily accept electrons from other molecules, making BF3 an electrophile.

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What does it mean for a molecule to be in a 'ground state'?

A molecule in its ground state is at its lowest energy level, with its electrons occupying the lowest possible energy orbitals. This is the most stable configuration.

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Sp2 Hybridization (C=C)

A carbon atom forming 3 equivalent bonds and a double bond utilizes sp2 hybrid orbitals. This results in a trigonal planar geometry around the carbon atom with bond angles close to 120 degrees.

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Sp Hybridization (C≡C)

A carbon atom forming one sigma bond with a terminal carbon, one sigma bond with an adjacent carbon, and two additional sigma bonds with the terminal carbon utilizes sp hybrid orbitals. This leads to a linear geometry.

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Molecular Geometry of PF3

PF3 has a tetrahedral electron geometry but a trigonal pyramidal molecular geometry due to the lone pair on the phosphorus atom which repels the bonding pairs.

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NF3 Molecular Geometry

NF3 has a trigonal pyramidal molecular geometry due to the lone pair on the nitrogen atom, which repels the fluorine atoms.

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Linear Molecule (CO2)

A molecule with an arrangement of atoms along a straight line. This arrangement arises from the sp hybridization of the central atom.

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Sp3 Hybridization (CF4)

The carbon atom in CF4 utilizes sp3 hybrid orbitals to form four equivalent single bonds to the fluorine atoms, giving it a tetrahedral geometry.

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Study Notes

Orbital Hybridization

  • Orbital hybridization is the mixing of atomic orbitals to form new hybrid orbitals. This is important for understanding molecular shapes and bonding.
  • The octet rule works well when involving p orbitals, but not with d orbitals.
  • Phosphorus in PCI5 uses sp³d hybridization, forming 5 equivalent bonds with 5 chlorine atoms.
  • The five sp³d orbitals are directed towards the corners of a trigonal bipyramid.
  • Three orbitals are in the same plane (120°) – equatorial P-Cl bonds.
  • The remaining two are perpendicular (90°) to this plane (axial P-Cl bonds).

sp³d² Hybridization - SF₆

  • Sulfur in SF₆ uses sp³d² hybridization.
  • The six sp³d² orbitals are directed towards the corners of an octahedron.
  • Sulfur hexafluoride (SF₆) has an octahedral shape, with a bond angle of 90° between hybrid orbitals.

Orbital Hybridization of Lewis Acid - Boron Trifluoride

  • Boron in BF₃ has 3 electrons in the outer shell [2s² 2p¹].
  • Every fluorine atom satisfies the octet rule.
  • Boron is deficient of 2 electrons (sextet), making it electrophilic.
  • Boron trifluoride has a trigonal planar geometry with bond angles of 120°.
  • P orbitals are in white, sp² orbitals are gray.

Orbital Hybrids Summary

  • Summary table correlating number of hybrid orbitals required with molecular geometry, hybrid type, and bond angles (Linear, Trigonal Planar, Tetrahedral, Trigonal Bipyramidal, and Octahedral).

Worked Example - Chloroform (CHCl₃)

  • Carbon (central atom) forms 4 equivalent bonds and obeys the octet rule.
  • Carbon is therefore sp³ hybridized, exhibiting tetrahedral geometry and approximately 109° bond angles.

Worked Examples - Predicting Hybridization, Shape, and Bond Angles of Carbon Atoms

  • Various examples illustrate how to predict hybridization, shape, and bond angles of carbon atoms based on the number of bonds they form, including single, double, and triple bonds.

Worked Examples - How Many σ and π Bonds?

  • Worked examples demonstrating the calculation of sigma (σ) and pi (Ï€) bonds based on orbital overlap (sp³ with sp³ and sp³ with s, sp² with sp², sp² with sp³, sp³ & s, overlap of pâ‚‚ with pâ‚‚ orbitals)
  • Detailed calculation and descriptions for various molecular structures.

Worked Examples - Choosing Incorrectly Matched Molecules

  • Questions providing options for molecules and their corresponding electronic geometries (CFâ‚„-tetrahedral, BeBrâ‚‚-linear, Hâ‚‚O-tetrahedral, NH₃-tetrahedral, PF₃-octahedral) to identify the incorrectly matched molecule.

Worked Examples - Finding Linear Arrangement Molecules

  • Questions provide a list of molecules to identify which has a linear arrangement of component atoms.

Worked Examples - Determining Hybrid Orbitals

  • Identifying the hybrid orbitals (sp, sp², sp³, sp³d, sp³d²) utilized by carbon atoms in various molecules, including CFâ‚„, molecules.

Worked Examples - Hybridisation of AB₃ Molecule

  • Determining the hybridization of the central atom (A) in an AB3 molecule having two lone pairs.

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