Optical Isomers and Racemates in Chemical Reactions

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

Which carboxylic acid derivative is more reactive than carboxylic acids?

  • Alcohols
  • Acyl chlorides (correct)
  • Acid anhydrides
  • Esters

What is the product when propan-1-ol undergoes a reaction with 2[H]?

  • 2-hydroxypropanenitrile
  • Propan-2-ol
  • hydroxynitrile
  • Propanone (correct)

What happens when an acyl chloride reacts with water?

  • Forms carboxylic acid and HCl gas (correct)
  • Forms ketone and water
  • Forms alcohol and HCl gas
  • Forms ester and water

Which condition is required for the addition of hydrogen cyanide to carbonyls to form hydroxynitriles?

<p>Room temperature and pressure (B)</p> Signup and view all the answers

Which carboxylic acid derivative undergoes a change to form esters when reacting with alcohol?

<p>Acid anhydrides (A)</p> Signup and view all the answers

What type of mechanism is involved in the reaction of carbonyl compounds with hydrogen cyanide?

<p>Nucleophilic addition (C)</p> Signup and view all the answers

Which compound undergoes the Iodoform test and forms CHI3 as a yellow crystalline precipitate?

<p>Ethanal (C)</p> Signup and view all the answers

In the presence of dilute sodium hydroxide under reflux conditions, which product is formed from methyl propanoate and NaOH?

<p>Sodium propanoate (A)</p> Signup and view all the answers

Which carboxylic acid derivative is resistant to attack by weak nucleophiles like alcohols?

<p>Acyl chlorides (A)</p> Signup and view all the answers

In which type of mechanism is the extra KCN used to increase the concentration of CN- ion nucleophile for the first step?

<p>SN2 mechanism (B)</p> Signup and view all the answers

What is the orange precipitate formed when 2,4-DNP reacts with aldehydes and ketones?

<p>Orange precipitate is not formed (C)</p> Signup and view all the answers

What type of reaction occurs when RCOCl reacts with water?

<p>Nucleophilic addition (C)</p> Signup and view all the answers

In the formation of a racemate through nucleophilic addition of HCN to aldehydes and ketones, why is a racemate formed?

<p>The attacking species approaches the trigonal planar carbonyl from both sides, leading to an equal chance of either enantiomer forming. (C)</p> Signup and view all the answers

How does the SN1 mechanism differ from the SN2 mechanism in terms of intermediates formation?

<p>SN1 mechanism forms intermediates, while SN2 mechanism does not. (A)</p> Signup and view all the answers

Why does the formation of a racemate occur in the reaction involving a haloalkane with the OH- ion using the SN1 mechanism?

<p>The reaction occurs via a transition state resulting in a racemate. (A)</p> Signup and view all the answers

What is a characteristic feature of a trigonal planar reactant or intermediate that leads to the formation of a racemate in certain chemical reactions?

<p>It allows attacking species to approach from both sides equally. (A)</p> Signup and view all the answers

How does the formation of a racemate affect the optical activity of the resulting product?

<p>A racemate reduces optical activity to zero. (A)</p> Signup and view all the answers

If a chiral reactant is used in a reaction, what would be the result in terms of enantiomer formation?

<p>A racemate would still be formed due to the nature of chiral compounds. (B)</p> Signup and view all the answers

Flashcards are hidden until you start studying

More Like This

Use Quizgecko on...
Browser
Browser