Nitric Acid Production and Safety Procedures
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Questions and Answers

What is the reaction for producing nitric acid from potassium nitrate and sulfuric acid?

The reaction is $KNO_3 + H_2SO_4 ightarrow KHSO_4 + HNO_3$.

Why is it important to maintain the temperature below 200°C during the nitric acid preparation?

The temperature must remain below 200°C to prevent decomposition, which forms a hard crust that is difficult to remove.

What are some safety precautions that must be taken during the nitric acid lab preparation?

Safety precautions include using proper safety equipment, ensuring all apparatus is made of glass, and avoiding temperatures above 200°C.

What observable characteristics indicate the purity of nitric acid?

<p>Pure nitric acid is colorless, while commercial samples are yellowish due to nitrogen dioxide.</p> Signup and view all the answers

What type of materials should be avoided in the apparatus during the preparation of nitric acid?

<p>Avoid using rubber and cork, as they can be damaged by the corrosive vapours of nitric acid.</p> Signup and view all the answers

What is the primary reactant in the first step of Ostwald's process for manufacturing nitric acid?

<p>Ammonia ($NH_3$)</p> Signup and view all the answers

What is produced when nitrogen monoxide ($NO$) is oxidized in the second step of the Ostwald's process?

<p>Nitrogen dioxide ($NO_2$)</p> Signup and view all the answers

In the absorption tower, which reactants combine to form nitric acid ($HNO_3$)?

<p>Nitrogen dioxide ($NO_2$), water ($H_2O$), and oxygen ($O_2$)</p> Signup and view all the answers

What occurs when nitric acid is heated, according to the test for its identification?

<p>It produces brown fumes due to decomposition.</p> Signup and view all the answers

Why is it important to cool gases before they enter the oxidation chamber in the Ostwald's process?

<p>To ensure complete oxidation occurs.</p> Signup and view all the answers

What are the oxidizing properties of nitric acid?

<p>Nitric acid is a very good oxidizing agent.</p> Signup and view all the answers

What happens when nitric acid reacts with carbon?

<p>4 HNO₃ + C → CO₂ + H₂O + 4 NO₂.</p> Signup and view all the answers

How does nitric acid react with copper?

<p>It produces Cu(NO₃)₂, NO₂, and H₂O, resulting in reddish-brown fumes.</p> Signup and view all the answers

Which metals do not react with nitric acid?

<p>Gold and platinum do not react with nitric acid.</p> Signup and view all the answers

What is the result of the reaction between iron(II) sulfate and nitric acid?

<p>The reaction produces iron(III) sulfate and water.</p> Signup and view all the answers

What is the nickname given to sulphuric acid and why?

<p>'King of chemicals' due to its widespread use and importance in industry, and 'oil of vitriol' because of its historical preparation from green vitriol.</p> Signup and view all the answers

Write the chemical equation for the production of sulphuric acid using sulphur and nitric acid.

<p>The equation is: <code>S + 6HNO₃ → H₂SO₄ + 6NO₂ + 2H₂O</code>.</p> Signup and view all the answers

Describe the hydrolysis reaction that produces sulphuric acid from sulphur trioxide.

<p>The reaction is: <code>SO₃ + H₂O → H₂SO₄</code>.</p> Signup and view all the answers

How is sulphur dioxide produced from the roasting of sulphur?

<p>It is produced according to the reaction: <code>S + O₂ → SO₂</code>.</p> Signup and view all the answers

What is the chemical equation for producing sulphur dioxide by roasting iron pyrite?

<p>The equation is: <code>FeS₂ + O₂ → Fe₂O₃ + SO₂</code>.</p> Signup and view all the answers

What type of acid is sulfuric acid and what does 'di-basic' mean?

<p>Sulfuric acid is a strong di-basic acid, meaning it can donate two protons (H+) per molecule.</p> Signup and view all the answers

Describe the reaction of sulfuric acid with sodium chloride.

<p>The reaction produces hydrochloric acid (HCl) and sodium hydrogen sulfate (NaHSO4).</p> Signup and view all the answers

How does sulfuric acid act as an oxidizing agent with carbon?

<p>Sulfuric acid reacts with carbon to produce carbon dioxide (CO2), water (H2O), and sulfur dioxide (SO2).</p> Signup and view all the answers

What is produced when hydrogen sulfide reacts with sulfuric acid?

<p>The reaction produces sulfur (S), water (H2O), and sulfur dioxide (SO2).</p> Signup and view all the answers

What is the significance of sulfuric acid's non-volatile nature?

<p>Its non-volatile nature means it does not easily vaporize, making it useful in various chemical processes.</p> Signup and view all the answers

What is the purpose of drying gases using concentrated sulfuric acid?

<p>To remove impurities such as arsenic oxide from the gases.</p> Signup and view all the answers

Why is the catalytic oxidation of sulfur dioxide important in the production of sulfur trioxide?

<p>It converts sulfur dioxide and oxygen into sulfur trioxide, which is crucial for manufacturing sulfuric acid.</p> Signup and view all the answers

What occurs when sulfur trioxide is directly mixed with water?

<p>A dense mist of sulfuric acid is formed due to the highly exothermic reaction.</p> Signup and view all the answers

What is formed when sulfur dioxide is absorbed in concentrated sulfuric acid?

<p>Pyrosulfuric acid, also known as oleum, is formed.</p> Signup and view all the answers

What happens when water is added to oleum?

<p>It forms sulfuric acid through dilution.</p> Signup and view all the answers

What is a dehydrating agent and give an example?

<p>A dehydrating agent removes chemically combined water elements. An example is the reaction <code>C₁₂H₂₂O₁₁ → 12C + 11H₂O</code>.</p> Signup and view all the answers

How do drying agents differ from dehydrating agents?

<p>Drying agents remove moisture without changing the chemical composition, while dehydrating agents cause a chemical change. This means drying is a physical change, and dehydration is a chemical change.</p> Signup and view all the answers

What observable reaction occurs when barium chloride is added to sulfuric acid?

<p>A white precipitate of barium sulfate (BaSO₄) is formed.</p> Signup and view all the answers

What color change indicates the presence of sulfur dioxide in potassium permanganate solution?

<p>Sulfur dioxide turns the orange acidified potassium permanganate solution to colorless.</p> Signup and view all the answers

What is the role of CuSO₄·5H₂O in dehydration reactions?

<p>CuSO₄·5H₂O acts as a dehydrating agent by releasing water, transforming into CuSO₄.</p> Signup and view all the answers

How does sulfur dioxide act as both an oxidizing and reducing agent?

<p>Sulfur dioxide can donate electrons (reducing agent) and accept electrons (oxidizing agent) depending on the reaction conditions.</p> Signup and view all the answers

What is the product of the reaction between sulfur dioxide and water?

<p>The product is sulfuric acid (H₂SO₄) and nascent hydrogen.</p> Signup and view all the answers

What color change occurs when potassium dichromate reacts with sulfur dioxide in sulfuric acid?

<p>The solution changes from orange to green.</p> Signup and view all the answers

Why is sulfur dioxide preferred for bleaching delicate materials?

<p>Sulfur dioxide is a mild bleaching agent that does not damage delicate fibers compared to stronger oxidizers.</p> Signup and view all the answers

What is formed when barium chloride reacts with sulfuric acid?

<p>Barium sulfate (BaSO₄), which is a white precipitate.</p> Signup and view all the answers

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