Negative Deviations from Raoult's Law Quiz
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Questions and Answers

What is the reason for negative deviations from Raoult's law?

  • Weaker intermolecular forces between similar molecules (correct)
  • Stronger intermolecular forces between similar molecules
  • Increased vapor pressure
  • Formation of azeotropes

What type of azeotrope forms when solutions show a large positive deviation from Raoult’s law?

  • Constant boiling azeotrope
  • Minimum boiling azeotrope (correct)
  • Ideal azeotrope
  • Maximum boiling azeotrope

What happens to the vapor pressure in a mixture that exhibits negative deviation from Raoult's law?

  • Becomes infinite
  • Decreases (correct)
  • Increases
  • Remains constant

Which pair of molecules exhibits negative deviation from Raoult's law due to hydrogen bonding?

<p>Phenol and aniline (C)</p> Signup and view all the answers

Which pair of molecules is mentioned to form a solution with negative deviation from Raoult's law in the text?

<p>Phenol and aniline (C)</p> Signup and view all the answers

Why is it not possible to separate components by fractional distillation in case of azeotropes?

<p>Components have similar boiling points (B)</p> Signup and view all the answers

How does the addition of acetone to ethanol affect the hydrogen bonding in the solution?

<p>Reduces hydrogen bonding (A)</p> Signup and view all the answers

What is the cause of positive deviations from Raoult's law?

<p>Weaker solute-solvent interactions (C)</p> Signup and view all the answers

In a solution that shows negative deviation from Raoult's law, what can be said about the intermolecular interactions?

<p>Solute-solvent interactions are stronger than solute-solute interactions (B)</p> Signup and view all the answers

Which type of solution shows positive deviations from Raoult's law according to the text?

<p>Mixtures of ethanol and acetone (B)</p> Signup and view all the answers

What can be inferred about a solution that shows a negative deviation from Raoult's law based on the text provided?

<p>Stronger solute-solute interactions than solvent-solvent interactions (C)</p> Signup and view all the answers

What is the composition of the azeotrope formed by nitric acid and water?

<p>32% nitric acid and 68% water by mass (C)</p> Signup and view all the answers

What effect does weaker intermolecular interactions have on vapor pressure in a solution showing positive deviation from Raoult's law?

<p>Increases vapor pressure (A)</p> Signup and view all the answers

Which class of solutions forms maximum boiling azeotropes at specific compositions?

<p>Solutions showing large negative deviation from Raoult's law (C)</p> Signup and view all the answers

What happens when an azeotrope composition is reached during fractional distillation?

<p>The liquid and vapor have the same composition (C)</p> Signup and view all the answers

In Raoult's law, what does a negative deviation indicate about the molecular interactions in the solution?

<p>Stronger intermolecular interactions than expected (A)</p> Signup and view all the answers

Which property of solutions is associated with the elevation of the boiling point of the solvent?

<p>Elevation of boiling point of the solvent (D)</p> Signup and view all the answers

What is the key characteristic of an azeotrope?

<p>Fixed composition in liquid and vapor phases (D)</p> Signup and view all the answers

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