Molecular Geometry: VSEPR Theory

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18 Questions

What is the bond angle for a molecule with a linear shape?

180°

Which molecule has a trigonal planar shape?

BF3

What is the bond angle in a molecule with a tetrahedral shape?

109.5°

Which molecule has a trigonal pyramidal shape?

NH3

How many bond angles does a molecule with an octahedral shape have?

90°

Which type of bond is formed when two atoms share electrons equally?

Non-polar covalent bond

What does the VSEPR theory help predict in chemistry?

Molecular shapes

In the context of chemistry, what is the main purpose of completing a 3D drawing of a molecule?

To visualize its shape and structure

Which aspect of a molecule is determined by its bond angles?

Hybridization

What property of a molecule is defined by whether it is polar or non-polar?

Solubility

Which theory can be used to predict the 3D shapes of molecules resulting from hybridization?

VBT (Valence Bond Theory)

How does understanding the polarity of a solid influence its properties?

It affects its crystal lattice structure

What is responsible for the formation of London dispersion forces?

Instantaneous dipoles induced by moving electrons

Which intermolecular force has the greatest strength?

Hydrogen bonding

What property of a substance increases as the atoms in its molecule get larger?

Polarizability

Why do water droplets bead?

Because of hydrogen bonding

What is the primary intermolecular force responsible for surface tension?

Hydrogen bonding

Which type of composite material consists of two or more materials that remain separate and distinct from each other?

Heterogeneous composite

Study Notes

Electron Pair Repulsion

  • Bonded and lone pair electrons move apart to lessen repulsive forces between them
  • This leads to specific molecular shapes

Molecular Shapes

  • Linear: 180° bond angle, ex. BeCl2
  • Trigonal Planar: 120° bond angles, ex. BF3
  • Tetrahedral: 109.5° bond angles, ex. CH4
  • Trigonal Bipyramidal: bond angles of 90° and 120°, ex. PCl5
  • Octahedral: bond angles of 90°, ex. SF6
  • Trigonal Pyramidal: bond angles of 107°, ex. NH3
  • Bent: bond angles 104.5°, ex. H2O

VSEPR Theory

  • Predicts the arrangement of electrons around each atom individually
  • Then, combines these arrangements to predict molecular shape

Multiple Central Atoms

  • Predict the arrangement of electrons around each atom individually
  • Then, combine these arrangements to predict molecular shape

Double and Triple Bonds

  • Shorter and stronger than single bonds
  • Behave similarly in regards to 3-dimensional shape of the molecule

Electronegativity and Bond Polarity

  • Two types of covalent bonds: non-polar (equal sharing of electrons) and polar (unequal sharing of electrons)
  • Electronegativity is the ability of an atom to attract electrons in a covalent bond

Intermolecular Forces

  • London Dispersion Forces: weak, momentary forces between non-polar molecules
  • Dipole-Dipole Forces: between polar molecules
  • Hydrogen Bonding: strongest intermolecular force
  • Intermolecular forces affect physical properties, such as melting/boiling point, viscosity, solubility, and surface tension

Learn about molecular geometry through VSEPR theory, which explains how bonded and lone pair electrons arrange themselves around a central atom to minimize repulsive forces. Explore different molecular shapes such as linear, trigonal planar, tetrahedral, trigonal bipyramidal, and octahedral. Understand concepts like bond angles and the use of wedge and dash notation.

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