Podcast
Questions and Answers
How many electrons are shared in a single covalent bond?
How many electrons are shared in a single covalent bond?
- One
- Three
- Two (correct)
- Four
What is the VSEPR number (number of electron domains) of PF3, where P is the central atom?
What is the VSEPR number (number of electron domains) of PF3, where P is the central atom?
- 3
- 4 (correct)
- 2
- 5
Based on VSEPR theory, what is the molecular geometry of PF3 (phosphorus trifluoride)?
Based on VSEPR theory, what is the molecular geometry of PF3 (phosphorus trifluoride)?
- Tetrahedral
- Trigonal Planar
- Bent
- Trigonal Pyramidal (correct)
What is the molecular geometry and polarity of water (Hâ‚‚O)?
What is the molecular geometry and polarity of water (Hâ‚‚O)?
Which intermolecular forces (IMFs) are present in a 20% MgClâ‚‚ aqueous solution?
Which intermolecular forces (IMFs) are present in a 20% MgClâ‚‚ aqueous solution?
Which of the following molecules does NOT exhibit dipole-dipole forces?
Which of the following molecules does NOT exhibit dipole-dipole forces?
What type of crystalline solid is graphite?
What type of crystalline solid is graphite?
Which three elements, when bonded to hydrogen, can participate in hydrogen bonding?
Which three elements, when bonded to hydrogen, can participate in hydrogen bonding?
Which of the following substances is expected to have the highest boiling point?
Which of the following substances is expected to have the highest boiling point?
According to the phase diagram, what phase exists at 10 atm and 300 K?
According to the phase diagram, what phase exists at 10 atm and 300 K?
What phase change occurs when mothballs gradually disappear from a cabinet without leaving a liquid residue?
What phase change occurs when mothballs gradually disappear from a cabinet without leaving a liquid residue?
On a phase diagram, what point represents the triple point?
On a phase diagram, what point represents the triple point?
How many liters of 16 M stock solution are needed to prepare 8.00 L of a 0.50 M nitric acid solution?
How many liters of 16 M stock solution are needed to prepare 8.00 L of a 0.50 M nitric acid solution?
If a 1.00 L solution of NaCl is diluted to 1.80 L, what changes?
If a 1.00 L solution of NaCl is diluted to 1.80 L, what changes?
What is the molarity of a solution containing 0.444 mol of CoClâ‚‚ in 654 mL of solution?
What is the molarity of a solution containing 0.444 mol of CoClâ‚‚ in 654 mL of solution?
Convert 199 parts per million (ppm) to parts per billion (ppb).
Convert 199 parts per million (ppm) to parts per billion (ppb).
What is the mass percent of a solution containing 9 g of solute dissolved in 100 g of solvent?
What is the mass percent of a solution containing 9 g of solute dissolved in 100 g of solvent?
To which group in the periodic table does the octet rule generally apply most directly?
To which group in the periodic table does the octet rule generally apply most directly?
In a thin-layer chromatography experiment with a polar solvent, three dyes separate on the TLC plate. If the solvent front is at 10 cm, the blue dye is at 8 cm, the purple dye is at 6 cm, and the red dye is at 2 cm from the origin, which dye is likely the least polar?
In a thin-layer chromatography experiment with a polar solvent, three dyes separate on the TLC plate. If the solvent front is at 10 cm, the blue dye is at 8 cm, the purple dye is at 6 cm, and the red dye is at 2 cm from the origin, which dye is likely the least polar?
What is considered to be the value of standard atmospheric pressure?
What is considered to be the value of standard atmospheric pressure?
What type of crystalline solid is table salt (NaCl)?
What type of crystalline solid is table salt (NaCl)?
Which of the following compounds would you expect to exhibit hydrogen bonding?
Which of the following compounds would you expect to exhibit hydrogen bonding?
Consider a closed system containing a mixture of ice, water, and water vapor at equilibrium. If the temperature is increased slightly, what will initially happen to the partial pressure of the water vapor?
Consider a closed system containing a mixture of ice, water, and water vapor at equilibrium. If the temperature is increased slightly, what will initially happen to the partial pressure of the water vapor?
A solution is prepared by dissolving 25.0 g of glucose (C6H12O6) in 250.0 mL of water. Given the molar mass of glucose is 180.16 g/mol, what is the molality of the solution?
A solution is prepared by dissolving 25.0 g of glucose (C6H12O6) in 250.0 mL of water. Given the molar mass of glucose is 180.16 g/mol, what is the molality of the solution?
When KNO3 is dissolved in water, the solution becomes noticeably colder. What can be concluded about the dissolution of KNO3?
When KNO3 is dissolved in water, the solution becomes noticeably colder. What can be concluded about the dissolution of KNO3?
Which of the following phase transitions releases the most energy per mole of substance?
Which of the following phase transitions releases the most energy per mole of substance?
Which factor primarily determines the strength of London Dispersion Forces in a molecule?
Which factor primarily determines the strength of London Dispersion Forces in a molecule?
Which statement best describes the vapor pressure of a liquid?
Which statement best describes the vapor pressure of a liquid?
A solution is prepared by dissolving a nonvolatile solute in a volatile solvent. Which of the following statements is TRUE regarding the vapor pressure of the solution?
A solution is prepared by dissolving a nonvolatile solute in a volatile solvent. Which of the following statements is TRUE regarding the vapor pressure of the solution?
What is the primary reason that representative elements follow the octet rule?
What is the primary reason that representative elements follow the octet rule?
Which of the following statements accurately describes the relationship between interparticle forces and viscosity?
Which of the following statements accurately describes the relationship between interparticle forces and viscosity?
Which type of intermolecular force is primarily responsible for the high boiling point of water compared to other molecules of similar size?
Which type of intermolecular force is primarily responsible for the high boiling point of water compared to other molecules of similar size?
Which of the following contributes most to the surface tension of a liquid?
Which of the following contributes most to the surface tension of a liquid?
What happens to the solubility of most solid solutes in water as the temperature of the water increases?
What happens to the solubility of most solid solutes in water as the temperature of the water increases?
Which of the following statements is true regarding the effect of pressure on the solubility of gases in liquids?
Which of the following statements is true regarding the effect of pressure on the solubility of gases in liquids?
Which type of solid generally has the lowest melting point?
Which type of solid generally has the lowest melting point?
Which of the following properties is colligative?
Which of the following properties is colligative?
Which of the following is an example of a covalent network solid?
Which of the following is an example of a covalent network solid?
Under what conditions does a real gas behave most ideally?
Under what conditions does a real gas behave most ideally?
Flashcards
Electrons in a bond
Electrons in a bond
Every bond, represented by a line, means two electrons being shared.
VSEPR number
VSEPR number
The VSEPR number is the total number of electron domains around the central atom, including both bonding and non-bonding (lone pairs) domains.
Molecular geometry
Molecular geometry
Molecular geometry describes the shape of a molecule, considering the positions of the atoms, but ignoring the lone pairs.
Water's geometry and polarity
Water's geometry and polarity
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IMFAs in MgCl2 solution
IMFAs in MgCl2 solution
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IMFAs in Hydrocarbons
IMFAs in Hydrocarbons
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Graphite crystalline solid type
Graphite crystalline solid type
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Elements forming H-bonds
Elements forming H-bonds
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Highest boiling point compound
Highest boiling point compound
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Phase at 10 atm, 300 K
Phase at 10 atm, 300 K
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Disappearing mothballs phase change
Disappearing mothballs phase change
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Meaning of triple point
Meaning of triple point
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How much of a 16 M stock solution of nitric acid needs to be used to make 8.00L of a 0.50M solution?
How much of a 16 M stock solution of nitric acid needs to be used to make 8.00L of a 0.50M solution?
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What changes when diluting?
What changes when diluting?
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Determine the molarity
Determine the molarity
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Convert parts per million to parts per billion
Convert parts per million to parts per billion
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Calculate the mass percentage
Calculate the mass percentage
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Elements conforming the octet rule
Elements conforming the octet rule
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Polarity order in chromatography
Polarity order in chromatography
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Value of normal pressure
Value of normal pressure
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Study Notes
Midterms review
- In a chemical bond, two electrons are shared.
- VSEPR number, electron domains, is the count of domains around the atom in the center of the molecular structure.
- A domain can be a non-bonding lone pair or a bond.
Molecular Geometry
- Molecular geometry for a compound with 4 electron domains, where 1 is a no-bonding lone pair and 3 are bonding domains, is trigonal pyramidal.
- Water's molecular geometry is bent and it is polar.
- Types of Intermolecular Forces of Attraction:
- Ion-dipole
- Hydrogen bonding
- Dipole-dipole
- London Dispersion Forces
Hydrocarbons
- Hydrocarbons contain only C and H, and are therefore nonpolar.
- The only IMFA present in a hydrocarbon is LDF.
- Graphite is a covalent network crystalline solid.
- Fluorine, oxygen, and nitrogen can form hydrogen bonds when bonded with hydrogen.
- Ethyl Alcohol (CH3OH) has the the highest boiling point of:
- Methane (CH4) because it's a hydrocarbon, nonpolar, and only has LDF, which is the weakest
- Carbon Dioxide (CO2) because it's polar and has dipole-dipole (weaker than Hydrogen bonds)
- Hydroiodic acid (HI)because it's polar and has dipole-dipole (weaker than Hydrogen bonds)
- Ethyl Alcohol (CH3OH) has the OH bonds and Hydrogen bonding, and those are strongest among the choices.
Phase at 10 atm, 300 K
- The phase at 10 atm and 300 K is liquid.
- Sublimation occurs when a mothball disappears over time.
- Solid-gas: sublimation
- Gas-solid: deposition
- Solid-liquid: melting
- Liquid-solid: freezing
- Liquid-gas: evaporation
- Gas-liquid: condensation
Triple point
- On a phase diagram, the triple point, where all three phases coexist or are in equilibrium, is letter D.
Dilution
- To determine how much of stock solution is needed to make a solution:
- M1V1=M2V2
- For example to make 8.00L of a .5M solution from a 16M stock solution will require .25M
- In diluting solution, the Liters of solution amount changes, because diluting increases the amount of solvent
Molarity
- Molarity (M) is calculated using: mol solute/Liter solution
- Example: The molarity of .444 mol of CoCl2 in 654 mL of solution is .679 M
Conversions and Percents
- 199 ppm = 199,000 ppb
- 1 ppm = 10^3 ppb
- Mass percent = (mass of solute/mass of solution) x 100%
- Example: Mass percent if you have 9 g of solute and 100 g of solvent is 8.26%.
- The mass of solution if 109 g (100g of solvent + 9 g of solute)
Octet Rule
- Representative Elements. The elements in the s-block and p-block of the periodic table, generally follow the octet rule.
- In a polar solvent, polar substances travel farther from the origin than nonpolar substances; red is the least polar.
- Normal atmospheric pressure is 1 atm.
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