Grade 12 Chemistry: Molecular Structures
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Questions and Answers

Which molecule exhibits a tetrahedral shape?

  • NH₃
  • CO₂
  • CH₄ (correct)
  • H₂O

What intermolecular force is most significant in liquid HF?

  • London dispersion forces
  • Hydrogen bonding (correct)
  • Dipole-dipole interactions
  • Ionic bonding

What is the molecular geometry of SF₆?

  • Trigonal bipyramidal
  • Tetrahedral
  • Square planar
  • Octahedral (correct)

Which molecule contains a coordinate covalent bond?

<p>NH₄⁺ (C)</p> Signup and view all the answers

Explain why water (H₂O) has a bent shape instead of a linear shape.

<p>Water has a bent shape due to the presence of two bonding pairs and two lone pairs of electrons around the central oxygen atom. These four electron pairs repel each other, resulting in a tetrahedral electron pair geometry. However, the molecular geometry is bent because only the positions of the atoms are considered.</p> Signup and view all the answers

Compare and contrast the bond polarity and molecular polarity of CH₄ and NH₃.

<p>Both C-H bonds in CH₄ and N-H bonds in NH₃ are polar due to the difference in electronegativity between the atoms. However, CH₄ is nonpolar because its tetrahedral symmetry causes the bond dipoles to cancel out. NH₃ is polar because it has a trigonal pyramidal shape and a lone pair, resulting in a net dipole moment.</p> Signup and view all the answers

Describe the concept of hybridization and determine the hybridization of the central atom in NH₃.

<p>Hybridization is the mixing of atomic orbitals to form new hybrid orbitals suitable for bonding. In NH₃, the nitrogen atom is $sp^3$ hybridized. One s orbital and three p orbitals mix to form four $sp^3$ hybrid orbitals. One contains a lone pair, and the other three form bonds with hydrogen atoms.</p> Signup and view all the answers

Graphite does not conduct electricity while diamond does because they are different elements

<p>False (B)</p> Signup and view all the answers

Consider the molecule XeF₄. Is the molecule is polar or nonpolar?

<p>XeF₄ is nonpolar. Although the Xe-F bonds are polar, the square planar geometry of the molecule causes the bond dipoles to cancel each other out, resulting in a net dipole moment of zero.</p> Signup and view all the answers

Flashcards

Methane (CH₄) Shape

Tetrahedral, bond angle of 109.5 degrees.

Ammonia (NH₃) Shape

Trigonal pyramidal, bond angle of 107 degrees.

Water (H₂O) Shape

Bent, bond angle of 104.5 degrees.

Coordinate Covalent Bond

A bond formed when one atom provides both electrons for the shared pair.

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Tetrahedral Shape Hybridization

sp³ hybridization

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HF Intermolecular Force

The strongest intermolecular force in liquid HF due to hydrogen bonded to a highly electronegative fluorine.

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Graphite Conductivity

Carbon atoms are sp² hybridized, forming strong covalent bonds in a planar arrangement, electrons delocalize.

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Trigonal Planar Hybridization

sp² hybridization.

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SF₆ Molecular Geometry

Octahedral

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Hybridization of N in NH₃

sp³ hybridization

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Study Notes

  • Grade 12 Chemistry practice test focuses on structures and properties of molecules.
  • The test includes multiple-choice, short-answer, and diagram-based questions.
  • The duration of the test is 1 hour.

Multiple Choice Questions

  • Question 1 asks to identify the molecule with a tetrahedral shape, with the correct answer being methane (CH₄).
  • Question 2 asks to identify the strongest intermolecular force in liquid HF, with the correct answer being hydrogen bonding.
  • Question 3 asks to identify the hybridization state corresponding to a molecule with a trigonal planar shape, with the correct answer being sp².
  • Question 4 asks to identify the correct molecular geometry of SF₆, with the correct answer being octahedral.
  • Question 5 asks to identify the molecule containing a coordinate covalent bond, with the correct answer being NH₄⁺ (ammonium ion).

Short Answer Questions

  • Question 6 requires explaining why water (H₂O) has a bent shape rather than a linear shape.
  • Question 7 requires drawing the Lewis structure for CO₃²⁻ (carbonate ion) and describing its molecular geometry.
  • Question 8 involves comparing and contrasting the bond polarity and molecular polarity of CH₄ and NH₃.
  • Question 9 requires describing the concept of hybridization and determining the hybridization of the central atom in NH₃.
  • Question 10 asks to explain why graphite conducts electricity while diamond does not, even though both are forms of carbon.

Diagrams & 3D Structures

  • Question 11 requires drawing the 3D structures of methane (CH₄), ammonia (NH₃), and water (H₂O), and identifying their bond angles.
  • Question 12 requires drawing a diagram that shows the coordinate covalent bond formation in NH₄⁺ (ammonium ion).

3D Molecular Structures

  • Methane (CH₄) has a tetrahedral shape with a bond angle of 109.5°.
  • Ammonia (NH₃) has a trigonal pyramidal shape with a bond angle of 107°.
  • Water (H₂O) has a bent shape with a bond angle of 104.5°.

Bonus Question

  • Question 13 focuses on the molecule XeF₄; it requires drawing its Lewis structure, identifying its molecular shape, determining the hybridization of Xe, and explaining whether the molecule is polar or nonpolar.

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Description

This practice test for Grade 12 Chemistry focuses on the structures and properties of molecules. It features multiple-choice and short-answer questions. Topics include molecular shapes, intermolecular forces, and hybridization.

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