Modern Atomic Theory and Periodic Table
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Questions and Answers

What happens to the shielding effect as you move down a group in the periodic table?

  • It fluctuates.
  • It increases. (correct)
  • It stays the same.
  • It decreases.
  • What is the effect of increasing effective nuclear charge (Zeff) on ionic radius across a period?

  • Ionic radius increases.
  • Ionic radius becomes unpredictable.
  • Ionic radius decreases. (correct)
  • Ionic radius remains unchanged.
  • Which statement about cations is correct?

  • Cations have more electrons than their neutral counterparts.
  • Cations are negatively charged ions.
  • Cations lose electrons and are smaller than neutral atoms. (correct)
  • Cations gain electrons and become larger than neutral atoms.
  • Which characteristic distinguishes anions from neutral atoms?

    <p>Anions gain electrons and become larger than neutral atoms.</p> Signup and view all the answers

    What is the trend of ionization energy as you move across a period in the periodic table?

    <p>Ionization energy increases.</p> Signup and view all the answers

    How does ionic radius change as you move down a group?

    <p>Ionic radius increases.</p> Signup and view all the answers

    What happens to ionization energy as atomic radius decreases?

    <p>Ionization energy increases</p> Signup and view all the answers

    Which trend is observed for electron affinity across a period?

    <p>Electron affinity increases</p> Signup and view all the answers

    What role does the shielding effect play in relation to effective nuclear charge (Zeff)?

    <p>It decreases Zeff.</p> Signup and view all the answers

    What term describes the energy required to remove an electron from an atom?

    <p>Ionization energy.</p> Signup and view all the answers

    How does electronegativity trend as you move down a group in the periodic table?

    <p>Electronegativity decreases</p> Signup and view all the answers

    What effect does increasing atomic size have on ionization energy down a group?

    <p>Ionization energy decreases</p> Signup and view all the answers

    What is the relationship between effective nuclear charge (Zeff) and ionization energy in periods?

    <p>Zeff increases, ionization energy increases</p> Signup and view all the answers

    Which factor primarily influences the decrease in electron affinity down a group?

    <p>Increasing shielding effect</p> Signup and view all the answers

    What trend occurs for ionic radius when moving from left to right across a period?

    <p>Ionic radius decreases consistently</p> Signup and view all the answers

    In terms of ionic properties, how do cations compare to their parent atoms?

    <p>Cations are smaller than their parent atoms</p> Signup and view all the answers

    What happens to atomic radius as you move across a period from left to right?

    <p>It decreases</p> Signup and view all the answers

    Which statement correctly describes the trend of effective nuclear charge (Zeff) as you move across a period?

    <p>Zeff increases while core electrons remain constant</p> Signup and view all the answers

    How does the shielding effect impact the attraction force experienced by valence electrons as energy shells are added?

    <p>It decreases attraction force</p> Signup and view all the answers

    What is the relationship between cations and their ionic radius compared to their neutral atoms?

    <p>Cations are smaller than their neutral atoms</p> Signup and view all the answers

    What happens to atomic radius as you move down a group in the periodic table?

    <p>It increases</p> Signup and view all the answers

    Which of the following statements about ionization energy is true as you move down a group?

    <p>Ionization energy decreases</p> Signup and view all the answers

    What is the effect of adding more core electrons on the effective nuclear charge experienced by valence electrons?

    <p>It decreases the Zeff experienced</p> Signup and view all the answers

    Which of the following correctly states the trend of ionic radii for anions compared to their neutral atoms?

    <p>Anions are larger than their neutral atoms</p> Signup and view all the answers

    Study Notes

    Modern Atomic Theory

    • Investigation 1 Experience 4
    • The quantum mechanical model, similar to the Bohr model, restricts electron energies to specific values.
    • Crucially, the quantum mechanical model doesn't define a precise electron pathway around the nucleus.
    • For each energy level, an atomic orbital exists, where electron presence probability is high.

    Periodic Table

    • Atomic number order is crucial; periodic properties repeat accordingly.
    • Periods in the Periodic Table show a pattern in element properties' change across them. However, properties repeat regularly.
    • Elements in a group share identical properties.

    Shell Model

    • The shell model uses orbitals distinguished by letters and energy levels.
    • The s orbital holds up to 2 electrons with 1 orbital.
    • The p orbital holds up to 6 electrons with 3 orbitals.
    • The d orbital holds up to 10 electrons with 5 orbitals.
    • The f orbital holds up to 14 electrons with 7 orbitals.
    • Each orbital holds a maximum of 2 electrons.

    Electron Configuration using Crazy Arrows

    • Use arrow sequence to model electron positioning.
    • Stop when enough electrons are plotted based on the element.
    • Illustrates electron filling order through the arrows' trajectory.

    Calculating Valence Electrons

    • Group number minus 10 for groups 14-18 (except helium, which has 2).
    • Groups 3 to 12 are transition metals. Determining valence electrons is problematic here.

    Electrons in Atoms- Investigation 1 Experience 5

    • This topic is about the distribution of electrons in atoms.

    Lewis Dot Structure

    • To represent valence electrons, use the element symbol and dots around it.
    • Place a dot for each valence electron on each side of the element symbol.

    Orbital Notation

    • Model electron configurations by using arrows and boxes for orbitals.
    • s orbitals have 1 box, p orbitals have 3, d orbitals have 5, and f orbitals have 7.
    • Follow Hund's Rule, Pauli Exclusion Principle, and Aufbau's principle.

    Hund's Rule and Pauli's Exclusion Principle

    • Hund’s Rule: Electrons use separate orbitals before pairing up.
    • Pauli's Exclusion Principle: Each electron in an atom has a unique set of four quantum numbers.
    • Electrons occupy orbitals individually first before doubling up on the same orbital.

    Aufbau Principle

    • Electrons fill orbitals in order starting with the lowest energy level, then progressing to higher levels.
    • This is done by following the arrow configuration sequence.

    Noble Gas Notation

    • Summarizes electron configuration using noble gases' core electron configurations.
    • Identify the noble gas before the element of interest in the Periodic Table (precede it).
    • Place it in brackets, which represent core electrons.
    • Continue normal electron configuration from the preceding noble gas and add remaining electrons to fully describe the element's configuration.

    The Periodic Table: An Overview- Investigation 2 Experience 1

    • History of the Periodic Table's development.
    • Dmitri Mendeleev's role emphasized.

    The Modern Periodic Table

    • The modern periodic table organizes elements by increasing atomic number.
    • Elements with similar properties fall within the same group.
    • Across a period, properties change; down a group, recurring properties appear.

    The 3 Main Categories of the Periodic Table

    • Metals: Shiny, solid at room temp (except Hg), good conductors, malleable, ductile.
    • Non-Metals: Solids, liquids, gases, brittle, poor conductors.
    • Metalloids: Combine metal and non-metal characteristics.

    Atomic Radius

    • Half the distance between two identical nuclei.
    • Influenced by electron shells and effective nuclear charge.

    Atomic Radius Trend

    • Across a period, atomic radius decreases.
    • Down a group, atomic radius increases.

    Effective Nuclear Charge (Zeff)

    • The net positive charge experienced by an electron.
    • Calculated by subtracting the atomic number from the total number of electrons.
    • Core electrons are subtracted.

    Zeff Trend

    • Across a period, Zeff increases.
    • Down a group, Zeff is relatively constant.

    Shielding Effect (S.E)

    • Valence electrons are shielded by core electrons.
    • The greater the number of energy levels, the stronger the shielding effect.

    Shielding Effect Trend

    • Shielding effect increases down a group.
    • Shielding effect is relatively constant across a period because the number of energy shells remains the same.

    Cations and Anions

    • Cations form when atoms lose electrons, becoming positively charged.
    • Anions form when atoms gain electrons, becoming negatively charged.
    • Metals form cations; nonmetals form anions.

    Cations vs. Parent/Neutral Atom

    • Cations are smaller than their neutral atom counterparts.

    Anions vs. Parent/Neutral Atom

    • Anions are bigger than their neutral atom counterparts.
    • Anions gain electrons to reach a full outer shell and thus a negatively charged ion.

    Ionic Radius (l.r)

    • Measure of the ion's size (cation or anion).
    • Decreases across a period because of the increase in Zeff.
    • Increases down a group due to increased energy levels.

    Ionization Energy (I.E)

    • Energy required to remove an electron.
    • Easier to remove electrons from atoms with a larger size/lower Zeff.
    • Greater stability is associated with higher ionization energy.

    Size vs I.e Trend

    • As size decreases, ionization energy increases.
    • As size increases, ionization energy decreases.
    • Across a period ionization energy generally increases.
    • Down a group ionization energy generally decreases.

    Electron Affinity (EA)

    • Energy change when an atom gains an electron.
    • Generally more negative across a period.
    • Generally less negative down a group.

    Electron Affinity Trend

    • Across a period, electron affinity generally increases with increasing nuclear charge.
    • Down a group, electron affinity generally decreases due to increased atomic radius.

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