Modern Atomic Theory and Electrons

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Questions and Answers

How did Thomson's experiments with cathode ray tubes contribute to the understanding of atomic structure?

  • They revealed the existence of electrons, negatively charged particles present in all atoms. (correct)
  • They demonstrated that atoms are indivisible and the smallest unit of matter.
  • They led to the discovery of the neutron and its role in atomic mass.
  • They proved that atoms have a dense, positively charged nucleus.

How did Rutherford's gold foil experiment change the atomic model?

  • It demonstrated a small, dense, positively charged nucleus.
  • Both B and C (correct)
  • It revealed that atoms are mostly empty space.
  • It confirmed the plum pudding model by showing electrons are evenly distributed.

Which statement accurately describes the behavior of atoms during chemical and nuclear reactions, according to modern atomic theory?

  • Atoms are always conserved; they can neither be subdivided nor destroyed in any reaction.
  • Atoms cannot be subdivided in ordinary chemical reactions, but they can be changed in nuclear reactions. (correct)
  • Atoms can be subdivided during ordinary chemical reactions, but are conserved in nuclear reactions.
  • Atoms are only conserved in reactions involving radioactive isotopes.

How does the mass number of an atom relate to the number of protons and neutrons in its nucleus?

<p>Mass number equals the sum of protons and neutrons. (C)</p> Signup and view all the answers

What is the main difference between isotopes of the same element?

<p>Different number of neutrons. (D)</p> Signup and view all the answers

How is the atomic mass of an element calculated considering the existence of isotopes?

<p>It is the weighted average of the masses of all naturally occurring isotopes. (A)</p> Signup and view all the answers

Which of the following statements accurately describes a conclusion drawn from the study of electrons?

<p>Electrons have such little mass that atoms must contain other more massive particles. (C)</p> Signup and view all the answers

If an atom has an atomic number of 20, what does this indicate?

<p>The total number of protons in the nucleus is 20. (D)</p> Signup and view all the answers

How does the periodic table organize elements based on their atomic structure?

<p>Elements are arranged by increasing atomic number, which reflects the number of protons. (D)</p> Signup and view all the answers

Consider an isotope of oxygen with 8 protons and 10 neutrons. What is its mass number?

<p>18 (D)</p> Signup and view all the answers

Why is the nucleus considered to contain most of the mass of an atom?

<p>All of the above. (D)</p> Signup and view all the answers

How do the properties of atoms of one element compare to those of another element?

<p>Atoms of any one element differ in properties from atoms of another element. (B)</p> Signup and view all the answers

What experimental evidence led Rutherford to conclude that the nucleus of an atom is positively charged?

<p>The deflection of a few alpha particles in the gold foil experiment. (A)</p> Signup and view all the answers

Which of the following is a correct pairing of a subatomic particle with its corresponding charge?

<p>Electron: -1 (A)</p> Signup and view all the answers

Which property of cathode rays was observed to be consistent, regardless of the element used in the cathode ray tube?

<p>Their properties were identical, indicating identically charged electrons. (A)</p> Signup and view all the answers

Flashcards

Atomic Theory

Atoms cannot be subdivided, created, or destroyed in ordinary chemical reactions, but they can be in nuclear reactions.

Atomic mass uniqueness

Each element has a unique, characteristic average mass.

Isotopes

Atoms of the same element can differ in mass due to isotopes.

Electron properties

Cathode rays have identical properties regardless of the element used to produce them; all elements contain identically charged electrons.

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Atomic neutrality

Atoms are neutral, so they must contain positive particles (protons) to balance the negative charge of electrons.

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Massive atom components

Electrons have very little mass, implying atoms must contain other, heavier particles.

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Nucleus

The central core of an atom made of protons and neutrons.

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Rutherford's gold foil findings

Most particles passed through, some were deflected, and very few were greatly deflected.

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Nucleus properties

The nucleus is small, dense, and positively charged.

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Electron

Negatively charged particle; found in electron cloud.

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Proton

Positively charged particle; found in the nucleus.

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Neutron

Neutral particle; found in the nucleus.

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Atomic number (Z)

The number of protons in the nucleus of an atom.

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Mass number

The number of protons and neutrons in the nucleus of an isotope.

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Isotopes definition

Atoms of the same element with different numbers of neutrons, leading to different masses.

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Study Notes

  • Students must know how to relate an element's place on the periodic table to its atomic number and mass.
  • It is crucial to know that an atom's nucleus is far smaller than the overall atom but comprises most of its mass.

Modern Atomic Theory

  • In normal chemical reactions, atoms cannot be created, divided, or destroyed.
  • Atoms can change in nuclear reactions.
  • Each element has an average mass unique to it.
  • Atoms of different elements differ in property.

Discovery of the Electron

  • J.J. Thomson used a cathode ray tube in 1897 to identify negatively charged particles.
  • Cathode ray tubes run electricity through a low-pressure gas.

Conclusions from Electron Study

  • Cathode rays' properties are the same no matter the element used to create them.
  • All elements have identically charged electrons.
  • The presence of positive particles is vital to balance the negative charge of electrons since atoms are neutral.
  • Atoms contain other particles that account for the bulk of the mass because electrons have minimal mass.

Thomson’s Atomic Model

  • Electrons are like plums in a positively charged "pudding" - the "plum pudding" model.

Rutherford’s Gold Foil Experiment

  • Rutherford's experiment utilized alpha particles, which are helium nuclei.
  • Alpha particles were directed at a thin gold sheet.
  • Particle strikes were noted on a screen

Rutherford’s Findings

  • The majority of particles passed straight through the gold foil.
  • Deflection occurred in a small number of particles.
  • Only a few particles experienced considerable deflections.
  • The nucleus is small, dense and positively charged.

Atomic Particles

Particle Charge Mass # Location
Electron -1 0 Electron cloud
Proton +1 1 Nucleus
Neutron 0 1 Nucleus

Atomic Number

  • The atomic number (Z) indicates the number of protons in an element's atom's nucleus and is unique for each element.
  • Carbon has 6 protons and an atomic number of 6.
  • Phosphorus has 15 protons and an atomic number of 15.
  • Gold has 79 protons and an atomic number of 79.

Mass Number

  • The mass number equals the number of protons plus neutrons in an isotope's nucleus.
  • Oxygen-18 has 8 protons, 10 neutrons, and a mass number of 18.
  • Arsenic-75 has 33 protons, 42 neutrons, and a mass number of 75.
  • Phosphorus-31 has 15 protons, 16 neutrons, and a mass number of 31.

Isotopes

  • Isotopes refer to atoms of the same element but with varying numbers of neutrons, resulting in different masses.
  • Hydrogen-1 (protium) has 1 proton, 1 electron, and 0 neutrons.
  • Hydrogen-2 (deuterium) has 1 proton, 1 electron, and 1 neutron.
  • Hydrogen-3 (tritium) has 1 proton, 1 electron, and 2 neutrons.

Atomic Masses

  • Atomic mass represents the average mass of an element's naturally occurring isotopes.
  • Carbon-12 has 6 protons and 6 neutrons, comprising 98.89% of naturally occurring carbon.
  • Carbon-13 has 6 protons and 7 neutrons, accounting for 1.11% of carbon found in nature.
  • Carbon-14 consists of 6 protons and 8 neutrons, making up less than 0.01% of carbon in nature.

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