Metallic Carbonyls and Electronic Configuration Quiz
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Questions and Answers

What do metallic carbonyls contain?

  • Hydrogen atoms attached to carbon and oxygen atoms
  • Metallic ions bonded to carbon and oxygen atoms
  • Lone pairs of electrons on carbon and oxygen atoms (correct)
  • Double bonds between carbon and oxygen atoms

In which oxidation state is the metal atom in metallic carbonyls said to be?

  • Negative
  • Zero (correct)
  • Variable
  • Positive

What type of carbonyl contains only one metallic atom per molecule?

  • Polynuclear carbonyls
  • Heteronuclear carbonyls
  • Mononuclear (or monomeric) carbonyls (correct)
  • Bridged carbonyls

What is the general method of preparation for simple carbonyls like nickel tetracarbonyl?

<p>Direct combination of nickel with carbon monoxide at suitable temperature and pressure (A)</p> Signup and view all the answers

What do polynuclear carbonyls contain?

<p>Two or more metallic atoms per molecule (C)</p> Signup and view all the answers

What is the general formula for polynuclear carbonyls?

<p>Ni(CO) Fe, (CO), Co, (CO), Fe, (CO),2.Co.(CO) (B)</p> Signup and view all the answers

Which metal compound has a tetrahedral shape due to sp³ hybridization of the metal atom?

<p>Nickel tetracarbonyl Ni(CO) (A)</p> Signup and view all the answers

Why is Iron pentacarbonyl Fe(CO) diamagnetic?

<p>Due to dsp hybridization of the iron atom (C)</p> Signup and view all the answers

What is the coordination number of iron in Fe_{2}(CO)_{9}?

<p>7 (A)</p> Signup and view all the answers

In polynuclear carbonyls, what does each Fe-atom link to in Fe_{2}(CO)_{9}?

<p>Three bridging C=O groups by a coordinate bond (B)</p> Signup and view all the answers

What is the basis of classification for different types of silicates?

<p>The shape of SiO4 anions (D)</p> Signup and view all the answers

Why are some silicates insoluble in water?

<p>As a result of the great strength of Si-O bond (A)</p> Signup and view all the answers

What causes the formation of SiO4 anions?

<p>The ap³ hybridisation of Si atom (D)</p> Signup and view all the answers

What is the shape of SiO4 anions?

<p>Tetrahedral (C)</p> Signup and view all the answers

How are all silicates similar in terms of their anion composition?

<p>They all contain SiO4 anions (C)</p> Signup and view all the answers

What type of silicates contain discrete SiO4 tetrahedral anions?

<p>Pyrosilicates (B)</p> Signup and view all the answers

Which type of silicates are known for their extensive industrial use as abrasives?

<p>Chain silicates (B)</p> Signup and view all the answers

In which type of silicates are the SiO4 tetrahedral units arranged in a cycliz like structure?

<p>Cyclic or ring silicates (B)</p> Signup and view all the answers

Which silicate type contains the discrete Si2O2^{6-} anion formed by joining two SiO4 tetrahedral units through one oxygen atom?

<p>Pyrosilicates (B)</p> Signup and view all the answers

What do zeolites primarily consist of, and what characteristic feature do they possess?

<p>Alumina and a three-dimensional network with open structure (B)</p> Signup and view all the answers

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