Membrane Transport Phenomena Quiz

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Questions and Answers

What is the role of the gel-layer resistance next to the membrane in ultrafiltration units?

Decreases the concentration gradient

Facilitates solvent flux

Enhances solute back diffusion

Increases resistance to solvent flux (correct)

In the gel-polarized regime, what determines the solvent flux in ultrafiltration units?

Pressure difference

Concentration gradient

Back diffusion equation (correct)

Gel-layer resistance

What type of solutions have experimental data confirmed the use of Eq.(24.5-6) for in ultrafiltration units?

Dilute solutions only

Macromolecular and colloidal solutions (correct)

Homogeneous solutions

Inorganic solutions

What does a reverse osmosis membrane allow to pass through while impeding the passage of other substances?

Solvent only Signup and view all the answers

Which factor plays a critical role in determining the volume of pure solvent water associated with a certain amount of solute in reverse osmosis?

Temperature Signup and view all the answers

What size of suspended materials can be removed using reverse osmosis according to the text?

Smaller than 1 micron Signup and view all the answers

Which membrane configuration has the highest ratio of membrane area per unit volume?

Hollow-fiber Signup and view all the answers

What is the typical pressure drop range for ultrafiltration units?

5-100 psi Signup and view all the answers

In the flux equation for ultrafiltration, what can be neglected?

Osmotic pressure Signup and view all the answers

What phenomenon occurs when the solute concentration builds up at the membrane surface?

Concentration polarization Signup and view all the answers

What happens to the solvent flux as the pressure drop increases?

It increases Signup and view all the answers

What is the primary effect of a higher convective transport of the solute to the membrane?

The concentration of the solute increases at the membrane surface Signup and view all the answers

What is the relationship between the convective flux and the diffusion flux at steady state?

The convective flux is equal to the diffusion flux Signup and view all the answers

What is the effect of further increases in pressure drop on the ultrafiltration process?

It decreases the solvent flux through the membrane Signup and view all the answers

Which equation describes the relationship between the mass-transfer coefficient and the solute concentration at the membrane surface?

$N_w/ = k_c (c_s/c_p)$ Signup and view all the answers

What is the effect of concentration polarization on the ultrafiltration process?

It decreases the solvent flux through the membrane Signup and view all the answers

Study Notes

Convective Transfer and Gel-Layer Resistance

In the gel-polarized regime, the net flux of solute by convective transfer equals the back diffusion of solute into the bulk solution due to the polarized concentration gradient.
The added gel-layer resistance next to the membrane causes an increased resistance to solvent flux, which is determined by 𝑁𝑤 = ∆𝑃 1 𝐴𝑤 + 𝑅𝑔.
The solvent flux in this regime is independent of pressure difference and is determined by the back diffusion equation.

Reverse Osmosis Membrane Process

In reverse osmosis, a spontaneous transport of solvent occurs from a dilute solute or salt solution to a concentrated solute or salt solution across a semipermeable membrane.
The osmotic pressure is given by the equation π = nRT / Vm, where n is the number of kg mol of solute, Vm is the volume of pure solvent water, R is the gas law constant, and T is temperature in K.

Ultrafiltration

In ultrafiltration, the membrane does not allow passage of the solute, which is generally a macromolecule.
The flux equation for ultrafiltration is 𝑁𝑤 = 𝐴𝑤(∆𝑃), since the osmotic pressure is very low and can be neglected.
Ultrafiltration units operate at a lower pressure drop (5-100 psi) compared to reverse osmosis (400-2000 psi).

Concentration Polarization

In ultrafiltration, the solute is rejected by the membrane and accumulates at the surface of the membrane, leading to concentration polarization.
As pressure drop increases and/or concentration of the solute increases, concentration polarization occurs, which is more severe than in reverse osmosis.
The convective flux equals the diffusion flux at steady state: 𝑁𝑤𝐶 ρ = − 𝐷𝐴𝐵 𝑑𝑐 / 𝑑𝑥.

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Description

Test your knowledge on convective transport and diffusion of solutes in membrane processes. Understand the relationship between convective flux and diffusion flux at steady state. Practice integrating the given transport equation for solute concentration.