Medical Chemistry L2: Periodic Table of Elements

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Questions and Answers

What is the primary basis for organizing elements in the Periodic Table?

  • Similar chemical properties (correct)
  • Geographical abundance
  • Increasing size of atoms
  • Atomic mass only

Which of the following statements about metals is NOT correct?

  • They are often malleable and shiny.
  • They form positive ions when reacting.
  • They are usually solid at room temperature.
  • They are poor conductors of electricity. (correct)

What is the relative atomic mass of oxygen?

  • 14.007 uma
  • 16.00 uma
  • 15.9994 uma (correct)
  • 12.011 uma

What mass unit is one twelfth the mass of a carbon-12 atom called?

<p>Atomic mass unit (u or uma) (A)</p> Signup and view all the answers

Which property is associated with metalloids?

<p>Intermediate electrical conductivity (C)</p> Signup and view all the answers

Which scientist is NOT credited with the independent cataloging of elements?

<p>John Dalton (C)</p> Signup and view all the answers

What reaction characteristic describes how metals behave?

<p>Forming positive ions (D)</p> Signup and view all the answers

What is the relationship between the mass of a proton and an electron?

<p>Proton mass is 1836 times greater than electron mass (B)</p> Signup and view all the answers

What primarily affects the increase in electron affinity across a period?

<p>Increase in effective nuclear charge (B)</p> Signup and view all the answers

Which of the following characteristics is NOT associated with non-metals?

<p>Positive electron affinities (B)</p> Signup and view all the answers

What type of cation do alkali metals typically form?

<p>Cations with a +1 charge (B)</p> Signup and view all the answers

The most electronegative element is:

<p>Fluorine (F) (A)</p> Signup and view all the answers

Which group of metals is characterized by having two electrons in their outer shell?

<p>Alkaline Earth Metals (A)</p> Signup and view all the answers

What is a common characteristic of transition metals?

<p>They have multiple oxidation states (D)</p> Signup and view all the answers

Which statement about halogens is true?

<p>They are highly reactive non-metals. (C)</p> Signup and view all the answers

What happens to the ionic radius when an atom forms a cation?

<p>The ionic radius decreases. (B)</p> Signup and view all the answers

What is the effect of increasing nuclear charge on ionization energy across a period?

<p>Ionization energy increases. (B)</p> Signup and view all the answers

Which statement about electron affinity is correct?

<p>It is the energy change associated with acquiring an electron. (D)</p> Signup and view all the answers

How does the atomic radius compare to the cation radius?

<p>The atomic radius is larger than the cation radius. (C)</p> Signup and view all the answers

What happens to the first ionization energy as you move down a group in the periodic table?

<p>It decreases. (A)</p> Signup and view all the answers

What is the significance of measuring ionization energy experimentally?

<p>It reveals the energies of electronic levels of an atom. (C)</p> Signup and view all the answers

Why do anions have a larger ionic radius compared to their atomic radius?

<p>The addition of electrons increases the electron cloud and distance from the nucleus. (B)</p> Signup and view all the answers

What is the characteristic of the second ionization energy compared to the first ionization energy for an atom?

<p>It is always higher than the first ionization energy. (C)</p> Signup and view all the answers

How many groups are present in the modern periodic table design?

<p>18 (D)</p> Signup and view all the answers

What is the filling order for the s and p orbitals in the modern periodic table?

<p>s orbitals can hold 2 electrons, p orbitals can hold 6 (B)</p> Signup and view all the answers

Which block in the periodic table contains elements with their outermost electrons in the s orbitals?

<p>s-block (B)</p> Signup and view all the answers

What characterizes elements within the same group of the periodic table?

<p>Similar outer electron configurations (C)</p> Signup and view all the answers

What is the total number of columns in the d-block of the periodic table?

<p>10 (D)</p> Signup and view all the answers

In the context of periodic table organization, what does moving from left to right across a period indicate?

<p>Increasing atomic number (C)</p> Signup and view all the answers

How many columns are available for f orbitals in the periodic table?

<p>14 (A)</p> Signup and view all the answers

Which group in the periodic table is commonly referred to as group 0?

<p>Noble gases (B)</p> Signup and view all the answers

What primarily characterizes the transition metals in the d-block?

<p>They can form multiple oxidation states. (D)</p> Signup and view all the answers

How does the atomic radius change as you move down a group in the periodic table?

<p>It increases. (D)</p> Signup and view all the answers

What effect does the increase in effective nuclear charge have as you move across a period?

<p>It causes the atomic radius to decrease. (B)</p> Signup and view all the answers

How do electrons in the same shell affect each other's repulsive forces?

<p>They do not effectively shield each other from the nucleus. (B)</p> Signup and view all the answers

What happens to the ionic radius when an atom gains electrons?

<p>It increases compared to the atomic radius. (B)</p> Signup and view all the answers

What is the primary reason for the size increase of an atom as you move down a group?

<p>The addition of inner shell electrons that provides more shielding. (D)</p> Signup and view all the answers

Which of the following statements is true regarding the f-block elements?

<p>They consist of the actinide and lanthanide series. (D)</p> Signup and view all the answers

Why do elements of the d-block show little variation in atomic radii across the series?

<p>The filling of d orbitals does not affect size significantly. (B)</p> Signup and view all the answers

Flashcards

d-block elements

Transition metals located in the central part of the periodic table, filling 10 electrons into the five d orbitals.

f-block elements

Elements at the bottom of the periodic table, filling 14 electrons into the seven f orbitals.

Atomic radius

Half the distance between the nuclei of two identical atoms bonded together.

Trend of Atomic Radius

Increases down a group and decreases across a period due to changes in nuclear charge and electron shielding.

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Ionic radius

The size of an ion compared to its neutral atom.

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Anion Size

Addition of electrons increases ionic radius due to increased electron-electron repulsion.

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Cation Size

Loss of electrons decreases ionic radius due to increased effective nuclear charge.

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Effective Nuclear charge

The attraction between the nucleus and outermost electrons, affected by the number of protons and shielding by inner electrons.

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Periodic Table

A chart that organizes all known chemical elements based on their properties.

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Periods

Horizontal rows in the periodic table. Elements in the same period have different properties but share the same number of electron shells.

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Groups

Vertical columns in the periodic table. Elements in the same group have similar chemical properties because they have the same number of valence electrons.

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Metals

Elements that are typically shiny, malleable, and good conductors of electricity. They form positive ions when reacting.

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Non-metals

Elements that are usually gases or brittle solids, poor conductors of electricity, and form negative ions when reacting.

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Metalloids

Elements that have properties of both metals and non-metals. They are semiconductors used in technology.

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Atomic Mass Unit (u or uma)

The standard unit used to measure the relative atomic mass of elements. It's defined as 1/12 the mass of a carbon-12 atom.

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Relative Atomic Mass

The ratio of the mass of an atom to the atomic mass unit. It tells us how many times the mass of an atom is greater than one twelfth of the mass of a carbon-12 atom.

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Cation Radius

The ionic radius of a cation is smaller than its atomic radius because the loss of electrons leads to a stronger attraction between the remaining electrons and the nucleus, pulling them closer.

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Anion Radius

The ionic radius of an anion is larger than its atomic radius because the gain of electrons leads to a weaker attraction between the electrons and the nucleus, pushing them further out.

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First Ionization Energy

The energy required to remove one electron from a neutral atom in its gaseous state.

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First Ionization Energy Trend (Across Period)

First ionization energy generally increases across a period because effective nuclear charge increases, making it harder to remove an electron.

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First Ionization Energy Trend (Down a Group)

First ionization energy generally decreases down a group because the atomic radius increases, making it easier to remove an electron from a larger atom.

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Electron Affinity

The change in energy that occurs when an atom gains an electron in its gaseous state.

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Electronegativity

The tendency of an atom to attract electrons in a chemical bond.

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Electronegativity scale

Measured on the Pauling scale, with fluorine (F) being the most electronegative element and cesium (Cs) being the least.

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Electron affinity across a period

Across a period (left to right), electron affinity generally increases due to the increasing effective nuclear charge, making the atom more attractive to electrons.

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Electron affinity down a group

Down a group, electron affinity generally decreases due to the increasing distance between the nucleus and the outer electron shell.

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Group (Periodic Table)

A set of elements with similar chemical properties due to the same outermost electron configuration, arranged in columns of the periodic table.

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Valence Electrons and Chemical Similarity

Elements in a group, also known as a family, have the same number of valence electrons, resulting in similar chemical behavior.

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Period (Periodic Table)

Periods are horizontal rows of the periodic table.They represent elements with increasing numbers of electron shells.

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Electron Shell

Represents the outermost energy level where electrons are present in an atom.

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Periodic Table Blocks

The four main block structures on the periodic table (s, p, d, and f) reflect different types of atomic orbitals and their capacity to hold electrons.

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Aufbau Principle

The systematic filling of atomic orbitals in an atom, as determined by the order of increasing energy levels.

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Study Notes

Medical Chemistry L2

  • The lecturer is Professor Dr. Giovanni N. Roviello
  • The course is for Geomedi University, Tbilisi, Georgia
  • Topic: Periodic Table of Elements

Periodic Table of Elements

  • A catalog of all known elements
  • Organized by characteristics
  • Similar elements in the same column
  • Elements with increasing mass placed sequentially
  • Developed independently by Dmitri Mendeleev and Lothar Meyer

Arrangement of elements in the periodic table

  • Periods: Horizontal rows, increasing atomic size
  • Groups: Vertical columns, similar chemical properties (state of matter, reactivity)

Types of Elements

  • Metals: Solids at room temperature, good conductors of electricity, malleable, shiny, form positive ions
  • Non-metals: Gases or solids at room temperature, poor conductors of electricity, form negative ions
  • Metalloids: Have intermediate properties, semiconductors used in technology.

Elementary Properties of atoms-Mass

  • The mass of particles are: -Proton: 1.672623 x 10⁻²⁷ kg -Neutron: 1.674929 x 10⁻²⁷ kg -Electron: 9.1093690 x 10⁻³¹ kg
  • Proton mass is 1836 times greater than electron mass

Atomic Mass Unit (UMA)

  • Atomic masses in kilograms are very small
  • Relative atomic masses are compared to a reference value, the atomic mass unit (uma): -One twelfth of the mass of a carbon-12 atom (1.66 x 10⁻²⁷ kg)
  • Relates atomic mass to carbon-12

Periodic Table History and Modern Periodic Table

  • Mendeleev (1869) based classification on chemical properties
  • Meyer (1869) based classification on physical properties
  • Modern table reflects atomic structure insights and quantum theory
  • Organizes elements according to electron orbital filling principles (Aufbau Principle)

Blocks in the Periodic Table

  • Four blocks (s, p, d, f) correspond to orbital types
  • Number of columns in each block corresponds to the number of electrons that can be accommodated in the relevant orbital subshells.
    • s-block: 2 columns
    • p-block: 6 columns
    • d-block: 10 columns
    • f-block: 14 columns

Groups and Periods in the Periodic Table

  • Groups: Columns; Elements share similar outer electron configuration and have similar properties
  • Periods: Rows; Atomic number increases from left to right indicating the addition of one proton and electron

Periodic Properties- Atomic Radius

  • Half the distance between two identical bonded atoms
  • Increases down a group (due to new electron shells)
  • Decreases across a period (due to increased nuclear charge, less shielding)

Periodic Properties- Ionic Radius

  • Radius of an ion
  • Increases down a group; Increases going left
  • Decreases going across a period
  • Cations (loss of electrons) are smaller; Anions (gain of electrons) are larger

Periodic Properties- Ionization Energy

  • Energy required to remove an electron from a neutral atom
  • Higher across a period because of stronger attraction to nucleus
  • Lower down a group as the atom increases in size and electrons are further from the positively charged nucleus.

Periodic Properties- Electron Affinity

  • Energy change associated with acquiring an electron
  • Increases across a period (due to increased nuclear charge)
  • Decreases down a group as the atom size increases, decreased attraction

Electronegativity

  • Atom's ability to attract electrons in a bond
  • Based on values of first ionization energy and electron affinity
  • Highest electronegativity is for fluorine
  • Lowest is for cesium

Classification of Elements

  • Metals (e.g., Iron, Copper, Gold)
  • Non-metals (e.g., Oxygen, Chlorine)
  • Metalloids (e.g., Silicon, Boron)

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