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Questions and Answers
In a two-flow reactor system, what is the primary process that results in the creation of a solid material on the substrate?
In a two-flow reactor system, what is the primary process that results in the creation of a solid material on the substrate?
Which of the following accurately describes the first half-reaction in Atomic Layer Deposition (ALD) using the mentioned precursors?
Which of the following accurately describes the first half-reaction in Atomic Layer Deposition (ALD) using the mentioned precursors?
What is the significance of 'lattice matching' in the context of thin film growth?
What is the significance of 'lattice matching' in the context of thin film growth?
According to the provided information, which property best characterizes semiconductors with regards to temperature?
According to the provided information, which property best characterizes semiconductors with regards to temperature?
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What does the Fermi level represent in a material?
What does the Fermi level represent in a material?
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Which of the following represents the correct relationship between lattice parameters for a tetragonal crystal system?
Which of the following represents the correct relationship between lattice parameters for a tetragonal crystal system?
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In the NaCl crystal structure, what type of sublattice is formed by the chloride ions (Cl)?
In the NaCl crystal structure, what type of sublattice is formed by the chloride ions (Cl)?
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What is the coordination number (CN) of the calcium (Ca) ion in the fluorite ($CaF_2$) crystal structure?
What is the coordination number (CN) of the calcium (Ca) ion in the fluorite ($CaF_2$) crystal structure?
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In the perovskite structure ($ABO_3$), which of the following is a typical coordination number (CN) for the B cation (e.g., Ti)?
In the perovskite structure ($ABO_3$), which of the following is a typical coordination number (CN) for the B cation (e.g., Ti)?
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Which of the following conditions is characteristic of a triclinic crystal system in terms of its lattice parameters?
Which of the following conditions is characteristic of a triclinic crystal system in terms of its lattice parameters?
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Which of the following is NOT an example of a crystal structure with the same arrangement as NaCl?
Which of the following is NOT an example of a crystal structure with the same arrangement as NaCl?
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In the $CaF_2$ structure, if there are 8 fluoride ions ($F^-$) per unit cell, how many calcium ions ($Ca^{2+}$) are there per unit cell?
In the $CaF_2$ structure, if there are 8 fluoride ions ($F^-$) per unit cell, how many calcium ions ($Ca^{2+}$) are there per unit cell?
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Based on the Goldschmidt tolerance factor, what is a typical value range for the formation of a perovskite structure?
Based on the Goldschmidt tolerance factor, what is a typical value range for the formation of a perovskite structure?
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What is the coordination number (CN) of Zinc (Zn) in the Zinc blende (sphalerite) structure?
What is the coordination number (CN) of Zinc (Zn) in the Zinc blende (sphalerite) structure?
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Which of the following best describes the relationship between diamond and graphite?
Which of the following best describes the relationship between diamond and graphite?
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Which process corresponds to the enthalpy change denoted as ΔΗ°(M, s)?
Which process corresponds to the enthalpy change denoted as ΔΗ°(M, s)?
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The crystal structure of Corundum (α-alumina) is characterized by which of the following arrangements?
The crystal structure of Corundum (α-alumina) is characterized by which of the following arrangements?
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What does ΣΙΕ(M, g) represent in the context of lattice energy calculations?
What does ΣΙΕ(M, g) represent in the context of lattice energy calculations?
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What type of hybridization do the carbon atoms undergo, within the sheets of the graphite structure?
What type of hybridization do the carbon atoms undergo, within the sheets of the graphite structure?
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In the context of calculating the lattice energy of NaH, what is the correct order of steps?
In the context of calculating the lattice energy of NaH, what is the correct order of steps?
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In the context of perovskite structures, a 'B' atom with a charge of 2+ (B²⁺) would be found within which type of material?
In the context of perovskite structures, a 'B' atom with a charge of 2+ (B²⁺) would be found within which type of material?
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What is the typical structure of the ionic lattice, used in the example calculation, for NaH?
What is the typical structure of the ionic lattice, used in the example calculation, for NaH?
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Which of the following statements accurately describes a key difference between α-alumina and γ-alumina?
Which of the following statements accurately describes a key difference between α-alumina and γ-alumina?
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What is the significance of the 'Born-Haber cycle' in the context of crystal structures?
What is the significance of the 'Born-Haber cycle' in the context of crystal structures?
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What does the term 'n' represent in the Born-Landé equation?
What does the term 'n' represent in the Born-Landé equation?
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What is are the units used for distance in the Born-Landé equation when performing calculations?
What is are the units used for distance in the Born-Landé equation when performing calculations?
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What is the main structural characteristic of the spinel structure?
What is the main structural characteristic of the spinel structure?
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Which material is used as a p-type dopant in the blue LED described?
Which material is used as a p-type dopant in the blue LED described?
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What is the primary purpose of Metal-Organic Chemical Vapor Deposition (MOCVD)?
What is the primary purpose of Metal-Organic Chemical Vapor Deposition (MOCVD)?
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What is the primary function of the YAG:Ce phosphor in a white LED?
What is the primary function of the YAG:Ce phosphor in a white LED?
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Which of the following describes a typical application of MOCVD?
Which of the following describes a typical application of MOCVD?
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What is the direction of current flow when a blue LED is forward biased?
What is the direction of current flow when a blue LED is forward biased?
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If a material has a band gap of $2.7 eV$, approximately what wavelength of light will it emit?
If a material has a band gap of $2.7 eV$, approximately what wavelength of light will it emit?
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What is the effect of applying a reverse bias to a P-N junction in an LED?
What is the effect of applying a reverse bias to a P-N junction in an LED?
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What happens to the band gap of a quantum dot as its size decreases?
What happens to the band gap of a quantum dot as its size decreases?
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In the light emission process of a quantum dot, what occurs during the 'recombination' phase?
In the light emission process of a quantum dot, what occurs during the 'recombination' phase?
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Why do quantum dots exhibit broad absorption spectra but narrow emission spectra?
Why do quantum dots exhibit broad absorption spectra but narrow emission spectra?
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If the size of the nanocrystal is reduced, what happens to the energy of emitted light?
If the size of the nanocrystal is reduced, what happens to the energy of emitted light?
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What is the primary role of phosphors in lighting applications?
What is the primary role of phosphors in lighting applications?
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According to the particle in a box model, how does the size of the quantum dot ('a') in the energy equation $E = \frac{n^2 h^2}{8ma^2}$ relate to the confinement energy?
According to the particle in a box model, how does the size of the quantum dot ('a') in the energy equation $E = \frac{n^2 h^2}{8ma^2}$ relate to the confinement energy?
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What is the effect of doping semiconductor nanocrystals with phosphorus?
What is the effect of doping semiconductor nanocrystals with phosphorus?
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What does the term 'confinement energy' refer to in the context of quantum dots?
What does the term 'confinement energy' refer to in the context of quantum dots?
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Flashcards
Lattice System
Lattice System
A classification of crystal lattices into seven distinct types based on symmetry and dimensions.
Lattice Parameter
Lattice Parameter
The dimensions of a unit cell in a crystal lattice, described by edges 'a', 'b', 'c' and angles 'α', 'β', 'γ'.
Cubic Crystal
Cubic Crystal
A crystal system where all sides are equal and angles between them are 90°.
Tetragonal Lattice
Tetragonal Lattice
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Body-Centered Cubic
Body-Centered Cubic
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Perovskite Structure
Perovskite Structure
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Coordination Number
Coordination Number
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Goldschmidt Tolerance Factor
Goldschmidt Tolerance Factor
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Epitaxial Growth
Epitaxial Growth
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ALD (Atomic Layer Deposition)
ALD (Atomic Layer Deposition)
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Band Gap
Band Gap
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Fermi Level
Fermi Level
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Lattice Matching
Lattice Matching
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P-Type Doping
P-Type Doping
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N-Type Doping
N-Type Doping
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Forward Bias in LED
Forward Bias in LED
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Reverse Bias in LED
Reverse Bias in LED
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YAG:Ce Phosphor
YAG:Ce Phosphor
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Enthalpy of Atomization (M)
Enthalpy of Atomization (M)
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Enthalpy of Atomization (X)
Enthalpy of Atomization (X)
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Ionization Energy (M)
Ionization Energy (M)
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Lattice Energy (MX)
Lattice Energy (MX)
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Standard Enthalpy of Formation (ΔH°(MX))
Standard Enthalpy of Formation (ΔH°(MX))
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Electrostatic Model of Interaction Energy
Electrostatic Model of Interaction Energy
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Chemical Vapor Deposition (CVD)
Chemical Vapor Deposition (CVD)
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Metal-Organic Compounds in CVD
Metal-Organic Compounds in CVD
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Diamond Structure
Diamond Structure
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Graphite Structure
Graphite Structure
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Zinc Blende Structure
Zinc Blende Structure
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Wurtzite Structure
Wurtzite Structure
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Corundum
Corundum
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Activated Alumina
Activated Alumina
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Lattice Energy
Lattice Energy
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Quantum Dots
Quantum Dots
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Excitation
Excitation
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Recombination
Recombination
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Tunable Emission
Tunable Emission
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Confinement Energy
Confinement Energy
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Phosphor Substitutes
Phosphor Substitutes
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Phosphor-Doped Nanocrystals
Phosphor-Doped Nanocrystals
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Broad Absorption and Narrow Emission
Broad Absorption and Narrow Emission
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Study Notes
Topic 2: From Crystals to LEDs
- Energy consumption for light contributes to a total of 4% CO2 emissions and consumes 22% of the world's electricity.
Introduction - LEDs & Other Lamps
- Incandescent light bulbs have a lifespan of 1000 hours and produce 16 lumens per watt. They use an inert gas or vacuum.
- Halogen lamps have lifespans between 2000 and 4000 hours, and produce 20-30 lumens per watt. Improvements include adding Iodine or Bromine to improve lifespan.
- Compact fluorescent lamps (CFLs) have lifespans of 10,000 hours and produce 50-70 lumens per watt. Contain Mercury (Hg).
- LEDs have lifespans of 50,000 hours and produce 200 lumens per watt. They last 23 years.
Crystals
- Crystals are solids where atoms, molecules, or ions form a highly ordered repeating pattern in all directions.
- Unit cells are the smallest repeating units in a crystal lattice structure.
Difference Between Square- & Hexagonal Packing
- Square packing has a coordination number of 4.
- Hexagonal packing has a coordination number of 6.
- Square packing efficiency is 80%, and hexagonal is 90%.
How to Pack Most Efficiently
- Solid-state structures involve packing spheres.
- Layer A, B, C is example of how sphere are packed.
Close-Packed Structures (FCC & HCP)
- Packing efficiency is about 74%.
- Coordination number is 12.
Voids in Close-Packed Structures
- Octahedral holes have a coordination number of 6.
- Tetrahedral holes have a coordination number of 4.
- FCC structures have two different void types.
Prototypical Crystal Structures
- NaCl lattice: Sodium and chloride ions in a 1:1 stoichiometric ratio, face-centered cubic (fcc) structure.
- CsCl structure: Cesium and chloride ions in a 1:1 ratio, body-centered cubic (bcc) structure.
- CaF₂ structure: Calcium and fluoride ions in a 1:2 ratio, fluorite structure
- CaTiO₃ structure: Calcium,titanium and oxygen, perovskite structure.
Prototypical Crystal Structure: Diamond & Graphite
- Diamond, hardest natural substance, strong covalent bonds, tetrahedral structure.
- Graphite: Anisotropic material, layered structure, sp² hybridization.
- Graphite readily conducts along a given plane(Sheet).
Prototypical Crystal Structure: Zinc Blende/Wurtzite
- Zinc Blende/Wurtzite (ZnS) is often found as a common constituent for LED devices.
- Both are semiconductors.
Prototypical Crystal Structure: Corundum
- Corundum (Al₂O₃): Extremely hard, a hcp structure.
- Used in applications like Ruby and Sapphire.
Estimation of Lattice Energy
- Born-Haber Cycle: A method to estimate the lattice energy using standard enthalpies of formation and atomization.
- Key steps involve enthalpy changes associated with the formation of different elements and their compounds
The Electrostatic Model
- Describes the interaction energy between ions in an ionic crystal.
- The Born-Landé equation provides a fundamental relationship between lattice constants, and ionic interaction energy.
Intrinsic Semiconductors in Group 14
- Silicon, germanium, and carbon all have intrinsic semiconducting properties.
- The band gap values vary across the group (higher for Si, lower for Ge or C).
- Different properties depend on bandgap energy (higher bandgap = less energy needed for an e- to jump).
Doping of Semiconductors
- Doping: intentionally adds small amounts of impurities to change electrical properties and conductivity of a material.
- n-type doping: Adds extra electrons, causing an excess of negatively charged carriers.
- p-type doping: Adds fewer electrons, causing an excess of positively charged carriers (holes).
P-N Junction in a Blue LED
- P-n junction is the boundary between p-type and n-type semiconductor regions.
- Current flows in one direction when the forward bias is applied.
- With forward bias a current is established due to a movement of charge carriers from one side to the other.
Silicon for Solar Cells
- Silicon is a crucial component in solar cells, playing a key role in converting sunlight to electricity.
Quantum Dots
- Quantum dots are nanoscale semiconductors that exhibit unique optical properties due to quantum confinement.
- Their properties vary based on size, thus they exhibit tunable emission.
Lead Sulfide and Lead Selenide Quantum Dots
- Lead sulfide (PbS) and lead selenide (PbSe) are examples of quantum dots with specific optical properties.
Phosphorous in Semiconductors
- Phosphorus can be added to semiconductor materials to change their electronic and optical properties.
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Description
Test your knowledge on key concepts related to thin film growth and semiconductor properties. This quiz covers atomic layer deposition, crystal structures, and material characterization. Explore important terms and principles that govern material behavior at the nanoscale.