Materials Science Quiz on Thin Film Growth
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Questions and Answers

In a two-flow reactor system, what is the primary process that results in the creation of a solid material on the substrate?

  • Epitaxial growth (correct)
  • Self-limiting half reaction
  • Substrate lattice expansion
  • Controlled thermal decomposition
  • Which of the following accurately describes the first half-reaction in Atomic Layer Deposition (ALD) using the mentioned precursors?

  • AI(CH3)3 reacts with H2O to form a solid compound.
  • H2O reacts with the substrate to form a hydroxide layer.
  • AI(CH3)3 decomposes into AI and CH3, with AI depositing onto the substrate. (correct)
  • AI(CH3)3 deposits a layer of CH3 onto the substrate.
  • What is the significance of 'lattice matching' in the context of thin film growth?

  • It refers to the alignment of the Fermi levels of both the material and substrate.
  • It minimizes stress and defects by having similar crystal structures between the substrate and the deposited material. (correct)
  • It specifically changes the electron configuration in the material.
  • It ensures the substrate and the deposited material have dissimilar structures.
  • According to the provided information, which property best characterizes semiconductors with regards to temperature?

    <p>Lower temperatures result in lower conductivity while increased temperatures raise conductivity. (B)</p> Signup and view all the answers

    What does the Fermi level represent in a material?

    <p>An imaginary energy level where electrons are located at a certain temperature. (C)</p> Signup and view all the answers

    Which of the following represents the correct relationship between lattice parameters for a tetragonal crystal system?

    <p>$a = b \neq c$ and $α = β = γ = 90°$ (C)</p> Signup and view all the answers

    In the NaCl crystal structure, what type of sublattice is formed by the chloride ions (Cl)?

    <p>Face-centered cubic (B)</p> Signup and view all the answers

    What is the coordination number (CN) of the calcium (Ca) ion in the fluorite ($CaF_2$) crystal structure?

    <p>8 (B)</p> Signup and view all the answers

    In the perovskite structure ($ABO_3$), which of the following is a typical coordination number (CN) for the B cation (e.g., Ti)?

    <p>6 (D)</p> Signup and view all the answers

    Which of the following conditions is characteristic of a triclinic crystal system in terms of its lattice parameters?

    <p>$a \neq b \neq c$, $α\neq β\neq γ$ (C)</p> Signup and view all the answers

    Which of the following is NOT an example of a crystal structure with the same arrangement as NaCl?

    <p>CsCl (B)</p> Signup and view all the answers

    In the $CaF_2$ structure, if there are 8 fluoride ions ($F^-$) per unit cell, how many calcium ions ($Ca^{2+}$) are there per unit cell?

    <p>4 (A)</p> Signup and view all the answers

    Based on the Goldschmidt tolerance factor, what is a typical value range for the formation of a perovskite structure?

    <p>Between 0.9 and 1.0 (B)</p> Signup and view all the answers

    What is the coordination number (CN) of Zinc (Zn) in the Zinc blende (sphalerite) structure?

    <p>4 (C)</p> Signup and view all the answers

    Which of the following best describes the relationship between diamond and graphite?

    <p>They are polymorphs, with graphite being thermodynamically more stable than diamond. (C)</p> Signup and view all the answers

    Which process corresponds to the enthalpy change denoted as ΔΗ°(M, s)?

    <p>M(s) → M(g) (A)</p> Signup and view all the answers

    The crystal structure of Corundum (α-alumina) is characterized by which of the following arrangements?

    <p>Aluminum (Al) ions in octahedral holes within a hexagonal close-packed (hcp) array of oxygen (O) ions. (C)</p> Signup and view all the answers

    What does ΣΙΕ(M, g) represent in the context of lattice energy calculations?

    <p>The sum of ionization energies for the metal in its gaseous state. (A)</p> Signup and view all the answers

    What type of hybridization do the carbon atoms undergo, within the sheets of the graphite structure?

    <p>sp² (D)</p> Signup and view all the answers

    In the context of calculating the lattice energy of NaH, what is the correct order of steps?

    <p>Na(s) + 1/2 H₂(g) → Na(g) + H(g) → NaH(s) (D)</p> Signup and view all the answers

    In the context of perovskite structures, a 'B' atom with a charge of 2+ (B²⁺) would be found within which type of material?

    <p>(A*, B²⁺, O) (D)</p> Signup and view all the answers

    What is the typical structure of the ionic lattice, used in the example calculation, for NaH?

    <p>NaCl (C)</p> Signup and view all the answers

    Which of the following statements accurately describes a key difference between α-alumina and γ-alumina?

    <p>γ-alumina is less dense and has a more open structure compared to α-alumina. (B)</p> Signup and view all the answers

    What is the significance of the 'Born-Haber cycle' in the context of crystal structures?

    <p>It provides a method for estimating the lattice energy of an ionic compound. (A)</p> Signup and view all the answers

    What does the term 'n' represent in the Born-Landé equation?

    <p>Born exponent, related to the repulsion between ions. (B)</p> Signup and view all the answers

    What is are the units used for distance in the Born-Landé equation when performing calculations?

    <p>m (C)</p> Signup and view all the answers

    What is the main structural characteristic of the spinel structure?

    <p>It is a face-centered cubic (fcc) array of anions with cations occupying tetrahedral and octahedral holes. (B)</p> Signup and view all the answers

    Which material is used as a p-type dopant in the blue LED described?

    <p>Magnesium (Mg) (A)</p> Signup and view all the answers

    What is the primary purpose of Metal-Organic Chemical Vapor Deposition (MOCVD)?

    <p>To grow thin films with smooth surfaces. (C)</p> Signup and view all the answers

    What is the primary function of the YAG:Ce phosphor in a white LED?

    <p>To absorb blue light and convert it into a mixture of yellow, green, and blue light. (D)</p> Signup and view all the answers

    Which of the following describes a typical application of MOCVD?

    <p>Production of optoelectronic devices (C)</p> Signup and view all the answers

    What is the direction of current flow when a blue LED is forward biased?

    <p>From the p-type to the n-type material. (C)</p> Signup and view all the answers

    If a material has a band gap of $2.7 eV$, approximately what wavelength of light will it emit?

    <p>450 nm (C)</p> Signup and view all the answers

    What is the effect of applying a reverse bias to a P-N junction in an LED?

    <p>It prevents the flow of charge carriers across the junction. (C)</p> Signup and view all the answers

    What happens to the band gap of a quantum dot as its size decreases?

    <p>The band gap becomes larger. (B)</p> Signup and view all the answers

    In the light emission process of a quantum dot, what occurs during the 'recombination' phase?

    <p>An electron returns to the valence band, releasing a photon. (D)</p> Signup and view all the answers

    Why do quantum dots exhibit broad absorption spectra but narrow emission spectra?

    <p>Their quantized energy levels lead to narrow emission but can absorb a wide range of wavelengths (B)</p> Signup and view all the answers

    If the size of the nanocrystal is reduced, what happens to the energy of emitted light?

    <p>The energy increases resulting in a shorter wavelength. (C)</p> Signup and view all the answers

    What is the primary role of phosphors in lighting applications?

    <p>To convert light into specific wavelengths by absorbing high-energy photons (A)</p> Signup and view all the answers

    According to the particle in a box model, how does the size of the quantum dot ('a') in the energy equation $E = \frac{n^2 h^2}{8ma^2}$ relate to the confinement energy?

    <p>The smaller the size of 'a' the higher the confinement energy. (D)</p> Signup and view all the answers

    What is the effect of doping semiconductor nanocrystals with phosphorus?

    <p>It modifies their electronic and optical properties for tailored colours. (B)</p> Signup and view all the answers

    What does the term 'confinement energy' refer to in the context of quantum dots?

    <p>The additional energy a particle has due to its confinement within the quantum dot. (B)</p> Signup and view all the answers

    Flashcards

    Lattice System

    A classification of crystal lattices into seven distinct types based on symmetry and dimensions.

    Lattice Parameter

    The dimensions of a unit cell in a crystal lattice, described by edges 'a', 'b', 'c' and angles 'α', 'β', 'γ'.

    Cubic Crystal

    A crystal system where all sides are equal and angles between them are 90°.

    Tetragonal Lattice

    A lattice type where 'a' and 'b' are equal but differ in 'c' with all angles at 90°.

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    Body-Centered Cubic

    A type of crystal lattice with an atom in the center of the cube and atoms at each corner.

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    Perovskite Structure

    A crystal structure represented by the formula ABO3, where A and B are different cations.

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    Coordination Number

    The number of nearest neighbors surrounding an atom in a crystal structure.

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    Goldschmidt Tolerance Factor

    A measure used to determine the stability of perovskite structures based on ionic sizes.

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    Epitaxial Growth

    The process of growing a crystalline layer on a substrate with a similar crystal structure.

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    ALD (Atomic Layer Deposition)

    A technique using self-limiting reactions to deposit thin films one layer at a time.

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    Band Gap

    The energy difference between the valence band and the conduction band in semiconductors.

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    Fermi Level

    An imaginary marker indicating the energy levels of electrons in a material at a given temperature.

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    Lattice Matching

    When the crystal structure of one material aligns with another to allow for epitaxy.

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    P-Type Doping

    Doping GaN with magnesium to create positive charge carriers (holes).

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    N-Type Doping

    Doping semiconductor (GaN) with silicon or other group 2 or 4 elements to create negative charge carriers (electrons).

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    Forward Bias in LED

    Current flows from the positive side to the negative side, resulting in light emission.

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    Reverse Bias in LED

    No light emission occurs as current flows from negative to positive, preventing charge carrier movement.

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    YAG:Ce Phosphor

    When blue light hits this phosphor, it absorbs and re-emits light as a mixture perceived as white light.

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    Enthalpy of Atomization (M)

    Heat required to convert one mole of solid metal M(s) to gaseous metal M(g).

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    Enthalpy of Atomization (X)

    Heat required to convert one mole of molecular X2(g) to individual atoms X(g).

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    Ionization Energy (M)

    Total energy needed to remove electrons from gaseous metal M(g) to form M²+(g).

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    Lattice Energy (MX)

    Energy released when gaseous ions form an ionic solid MX(s).

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    Standard Enthalpy of Formation (ΔH°(MX))

    The ΔH change when one mole of a compound is formed from its elements in their standard states.

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    Electrostatic Model of Interaction Energy

    Formula to calculate potential energy between two charged ions based on their distance and charge.

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    Chemical Vapor Deposition (CVD)

    Process of depositing thin films on a substrate using gas-phase chemical reactions of precursors.

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    Metal-Organic Compounds in CVD

    Compounds used in CVD that combine metal with organic components for thin film deposition.

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    Diamond Structure

    Hardest natural substance with a covalent bond and tetrahedral coordination (CN=4).

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    Graphite Structure

    Carbon structure with sp² hybridization, known for conductivity and layer formation.

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    Zinc Blende Structure

    Crystal structure of ZnS with face-centered cubic (FCC) topology and tetrahedral holes.

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    Wurtzite Structure

    Hexagonal polymorph of ZnS with a similar structure to zinc blende.

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    Corundum

    A crystal structure made of Al2O3, extremely hard; forms rubies and sapphires.

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    Activated Alumina

    γ-Al2O3, a less dense, more reactive form of Al2O3 with an open structure.

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    Lattice Energy

    Energy required to break ionic compounds into gaseous ions.

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    Quantum Dots

    Nanoscale semiconductor particles that confine electrons and holes in a small region, leading to discrete energy levels.

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    Excitation

    The process where a photon moves an electron from the valence band to the conduction band, creating an electron-hole pair.

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    Recombination

    The process where electrons recombine with holes, releasing energy in the form of light (photon).

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    Tunable Emission

    The ability of quantum dots to emit light at varying wavelengths depending on their size.

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    Confinement Energy

    The additional energy required for particles confined in quantum dots, contributing to their unique properties.

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    Phosphor Substitutes

    Semiconductor nanocrystals used to convert light into specific wavelengths, often combined with traditional phosphors.

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    Phosphor-Doped Nanocrystals

    Semiconductor nanocrystals modified with phosphors to enhance optical properties and reduce defects.

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    Broad Absorption and Narrow Emission

    Quantum dots can absorb a wide range of light but emit a narrow peak, resulting in pure colors.

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    Study Notes

    Topic 2: From Crystals to LEDs

    • Energy consumption for light contributes to a total of 4% CO2 emissions and consumes 22% of the world's electricity.

    Introduction - LEDs & Other Lamps

    • Incandescent light bulbs have a lifespan of 1000 hours and produce 16 lumens per watt. They use an inert gas or vacuum.
    • Halogen lamps have lifespans between 2000 and 4000 hours, and produce 20-30 lumens per watt. Improvements include adding Iodine or Bromine to improve lifespan.
    • Compact fluorescent lamps (CFLs) have lifespans of 10,000 hours and produce 50-70 lumens per watt. Contain Mercury (Hg).
    • LEDs have lifespans of 50,000 hours and produce 200 lumens per watt. They last 23 years.

    Crystals

    • Crystals are solids where atoms, molecules, or ions form a highly ordered repeating pattern in all directions.
    • Unit cells are the smallest repeating units in a crystal lattice structure.

    Difference Between Square- & Hexagonal Packing

    • Square packing has a coordination number of 4.
    • Hexagonal packing has a coordination number of 6.
    • Square packing efficiency is 80%, and hexagonal is 90%.

    How to Pack Most Efficiently

    • Solid-state structures involve packing spheres.
    • Layer A, B, C is example of how sphere are packed.

    Close-Packed Structures (FCC & HCP)

    • Packing efficiency is about 74%.
    • Coordination number is 12.

    Voids in Close-Packed Structures

    • Octahedral holes have a coordination number of 6.
    • Tetrahedral holes have a coordination number of 4.
    • FCC structures have two different void types.

    Prototypical Crystal Structures

    • NaCl lattice: Sodium and chloride ions in a 1:1 stoichiometric ratio, face-centered cubic (fcc) structure.
    • CsCl structure: Cesium and chloride ions in a 1:1 ratio, body-centered cubic (bcc) structure.
    • CaF₂ structure: Calcium and fluoride ions in a 1:2 ratio, fluorite structure
    • CaTiO₃ structure: Calcium,titanium and oxygen, perovskite structure.

    Prototypical Crystal Structure: Diamond & Graphite

    • Diamond, hardest natural substance, strong covalent bonds, tetrahedral structure.
    • Graphite: Anisotropic material, layered structure, sp² hybridization.
    • Graphite readily conducts along a given plane(Sheet).

    Prototypical Crystal Structure: Zinc Blende/Wurtzite

    • Zinc Blende/Wurtzite (ZnS) is often found as a common constituent for LED devices.
    • Both are semiconductors.

    Prototypical Crystal Structure: Corundum

    • Corundum (Al₂O₃): Extremely hard, a hcp structure.
    • Used in applications like Ruby and Sapphire.

    Estimation of Lattice Energy

    • Born-Haber Cycle: A method to estimate the lattice energy using standard enthalpies of formation and atomization.
    • Key steps involve enthalpy changes associated with the formation of different elements and their compounds

    The Electrostatic Model

    • Describes the interaction energy between ions in an ionic crystal.
    • The Born-Landé equation provides a fundamental relationship between lattice constants, and ionic interaction energy.

    Intrinsic Semiconductors in Group 14

    • Silicon, germanium, and carbon all have intrinsic semiconducting properties.
    • The band gap values vary across the group (higher for Si, lower for Ge or C).
    • Different properties depend on bandgap energy (higher bandgap = less energy needed for an e- to jump).

    Doping of Semiconductors

    • Doping: intentionally adds small amounts of impurities to change electrical properties and conductivity of a material.
    • n-type doping: Adds extra electrons, causing an excess of negatively charged carriers.
    • p-type doping: Adds fewer electrons, causing an excess of positively charged carriers (holes).

    P-N Junction in a Blue LED

    • P-n junction is the boundary between p-type and n-type semiconductor regions.
    • Current flows in one direction when the forward bias is applied.
    • With forward bias a current is established due to a movement of charge carriers from one side to the other.

    Silicon for Solar Cells

    • Silicon is a crucial component in solar cells, playing a key role in converting sunlight to electricity.

    Quantum Dots

    • Quantum dots are nanoscale semiconductors that exhibit unique optical properties due to quantum confinement.
    • Their properties vary based on size, thus they exhibit tunable emission.

    Lead Sulfide and Lead Selenide Quantum Dots

    • Lead sulfide (PbS) and lead selenide (PbSe) are examples of quantum dots with specific optical properties.

    Phosphorous in Semiconductors

    • Phosphorus can be added to semiconductor materials to change their electronic and optical properties.

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    Description

    Test your knowledge on key concepts related to thin film growth and semiconductor properties. This quiz covers atomic layer deposition, crystal structures, and material characterization. Explore important terms and principles that govern material behavior at the nanoscale.

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