Matching System-Surrounding Diagrams to Chemical Reactions

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11 Questions

What is the correct system-surroundings diagram for the reaction 4 CO2 (g) + 6 H2O (g) → 2 C2H6 (g) + 7 O2 (g) at constant temperature and external pressure?

Sys-Surr Diagrams-4.jpg

Which system-surroundings diagram represents the forward chemical reaction H2 (g) + Br2 (l) → 2 HBr (g) at constant temperature and external pressure?

Sys-Surr Diagrams-4.jpg

What is the correct system-surroundings diagram for an air-filled balloon that contracts in volume when placed in a small amount of liquid nitrogen at –196 °C?

Sys-Surr Diagrams-1.jpg

Which system-surroundings diagram represents a cup of water that evaporates into a gas and releases to the atmosphere under constant atmospheric pressure?

Sys-Surr Diagrams-1.jpg

What is the sign of ΔH for the reaction 4 CO2 (g) + 6 H2O (g) → 2 C2H6 (g) + 7 O2 (g)?

Positive

What is the effect of the reaction H2 (g) + Br2 (l) → 2 HBr (g) on the system at constant temperature and external pressure?

Increase in volume

What is the sign of ΔS°sys for the reaction 2 C2H6 (g) + 7 O2 (g) → 4 CO2 (g) + 6 H2O (g)?

Negative

At what temperature is the reaction 2 H (g) → H2 (g) spontaneous?

All temperatures

What is the sign of ΔS°surr for the compression of gas in a closed system?

Negative

Under what conditions is the reaction CO2 (s) → CO2 (g) spontaneous?

High temperatures

What is the relationship between ΔS°sys and ΔS°surr during the reaction 2 C2H6 (g) + 7 O2 (g) → 4 CO2 (g) + 6 H2O (g)?

ΔS°sys is negative, ΔS°surr is positive

Identify the correct system-surrounding diagrams for given chemical reactions. This quiz tests your understanding of thermodynamics and reaction systems. Choose the correct diagram for each reaction, considering the effects on volume and pressure.

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