Mastering Coordination Compounds

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Questions and Answers

Which orbitals are electrons removed from first in transition elements?

  • 3s
  • 4p
  • 4s (correct)
  • 3d

In coordination compounds, what is a complex ion composed of?

  • A central transition metal and counter ions
  • A central transition metal and ligands (correct)
  • A central transition metal and anions
  • A central transition metal and cations

What are counter ions in coordination compounds?

  • Metal cations that serve as the central atom
  • Anions/cations needed to balance the charge of the compound
  • Neutral molecules or anions that can be used to form bonds to the central metal ion
  • Ions outside brackets that are free and uncomplexed (correct)

What is a ligand in coordination compounds?

<p>A neutral molecule or anion that can be used to form bonds to the central metal ion (D)</p> Signup and view all the answers

What is the requirement for a molecule to be a ligand in coordination compounds?

<p>It must contain at least one lone pair of electrons (C)</p> Signup and view all the answers

Flashcards

Which orbitals lose electrons first in transition elements?

4s orbitals are the first to lose electrons.

What is a complex ion?

A central transition metal surrounded by ligands.

What are counter ions?

Ions that balance the charge of the complex, residing outside the coordination sphere.

What is a ligand?

A molecule or ion that binds to a central metal atom/ion.

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Ligand Requirement

It must have at least one lone pair of electrons to donate.

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Study Notes

Transition Elements

  • In transition elements, electrons are removed from the outermost d subshell first, followed by the s subshell.

Coordination Compounds

  • A complex ion is composed of a central metal atom or ion bonded to one or more neutral molecules or negative ions, known as ligands.

Counter Ions

  • Counter ions are ions that are not directly bonded to the central metal atom or ion in a coordination compound, but rather are present to balance the charge of the complex ion.

Ligands

  • A ligand is a neutral molecule or negative ion that is bonded to the central metal atom or ion in a coordination compound.
  • The requirement for a molecule to be a ligand is that it must have at least one unshared pair of electrons that can be used to form a coordinate covalent bond with the central metal atom or ion.

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