Lipids: Oils, Waxes, and Biosynthesis

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Questions and Answers

What is the key distinction between fixed oils/fats and waxes in terms of chemical composition?

  • Waxes contain both glycerol and long-chain fatty acids, while fixed oils/fats only have fatty acids.
  • Fixed oils and fats are derived from animal sources, whereas waxes are plant-based.
  • Fixed oils and fats contain glycerol, while waxes contain higher molecular weight alcohols. (correct)
  • Waxes are composed of saturated fatty acids, while fixed oils/fats are unsaturated.

Which of the following is a characteristic of oils obtained by expression in hydraulic presses?

  • Solvents are typically used in the 'cold-pressed' extraction method.
  • Oils extracted with heat are known as 'virgin oils'.
  • Oils extracted without heat are known as 'cold-pressed oils'. (correct)
  • Heat extraction always results in a lower quality oil with higher free fatty acid content.

What does a high saponification value indicate about a substance?

  • A large number of milligrams of potassium hydroxide are required to neutralize the free acids and saponify the esters. (correct)
  • A high degree of unsaturation.
  • A large amount of free fatty acids.
  • A low melting point.

How is the biosynthesis of fatty acid moieties primarily carried out in living organisms?

<p>A series of reactions involving enzyme complexes, ATP, NADPHâ‚‚, Mn++, and carbon dioxide. (B)</p> Signup and view all the answers

In the context of lipid biosynthesis, what is the role of malonyl-CoA?

<p>Its malonyl portion serves as the source of the 2-carbon biosynthetic units. (D)</p> Signup and view all the answers

What is the purpose of hydrogenating fixed oils?

<p>To convert unsaturated glycerides to saturated glycerides, resulting in semisolid fats. (C)</p> Signup and view all the answers

How are sulfated or sulfonated oils produced, and what is a key requirement during their production?

<p>By reacting sulfuric acid with the oil while maintaining low temperatures. (B)</p> Signup and view all the answers

Castor oil is obtained from Ricinus communis. What is a notable characteristic regarding the seed?

<p>The seed contains ricin, a toxic lectin. (C)</p> Signup and view all the answers

Which of the following is a grade of olive oil produced by extracting the pulp with carbon disulfide?

<p>&quot;Sulfur&quot; oil (C)</p> Signup and view all the answers

What accounts for the excellent stability of sesame oil?

<p>A phenolic constituent, sesamol. (D)</p> Signup and view all the answers

For what purpose is ethodized oil used?

<p>As a radiopaque diagnostic aid. (D)</p> Signup and view all the answers

Why are the seeds of Theobroma cacao roasted?

<p>To lose water and develop their characteristic odor and taste. (B)</p> Signup and view all the answers

What is a primary use for cocoa butter in pharmaceuticals?

<p>As a suppository base. (B)</p> Signup and view all the answers

Which of these is a key characteristic of lanolin that makes it useful in topical applications?

<p>It is water-absorbable. (D)</p> Signup and view all the answers

How are Stearic acids usually obtained?

<p>Hydrolysis of fats or oils. (B)</p> Signup and view all the answers

What advantage do Isopropyl myristate and isopropyl palmitate have over naturally-sourced vegetable oils?

<p>They are less oleaginous and less prone to oxidation. (C)</p> Signup and view all the answers

What is the primary method for obtaining undecylenic acid, a common ingredient in anti-fungal products?

<p>Pyrolysis of ricinoleic acid from castor oil. (B)</p> Signup and view all the answers

Besides being an emollient what other property makes cetyl alcohol useful in pharmaceutical preparations?

<p>Emulsifying Aid. (B)</p> Signup and view all the answers

What is liquid wax, as opposed to triglycerides?

<p>Jojoba oil (B)</p> Signup and view all the answers

What is the primary use for yellow wax?

<p>A stiffening agent in ointments. (D)</p> Signup and view all the answers

What has been found in human semen could produce contraction and relaxation of the human uterus?

<p>Prostaglandins (C)</p> Signup and view all the answers

Why is prostaglandin E1 used over other kinds of prostaglandins?

<p>Inhibits the effects of platelet aggregation (D)</p> Signup and view all the answers

Which statement accurately reflects the relationship between acids and iodine number?

<p>Iodine number measures degree of unsaturation, while acids help quantify the amount of free fatty acids present. (D)</p> Signup and view all the answers

An analysis reveals a lipid sample rich in saturated long-chain glycerides at room temperature. Which extraction method most likely separated this sample?

<p>Rendering at normal temperatures. (C)</p> Signup and view all the answers

Following lipid extraction of peanuts, the remaining "peanut oil cake" finds a particular secondary application--what is it?

<p>High-value livestock food by-product. (D)</p> Signup and view all the answers

Flashcards

Lipids (fixed oils, fats, and waxes)

Esters of long-chain fatty acids and alcohols.

Fixed Oils

Liquid at normal temperatures; they are a type of lipid.

Fats

Semisolid or solid at ordinary temperatures; they are a type of lipid.

Acid value/number

Number of mg of potassium hydroxide to neutralize free fatty acids in 1g of substance.

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Saponification Value

Indicates milligrams of potassium hydroxide needed to neutralize free acids and saponify in 1g.

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Iodine Number

Indicates grams of iodine absorbed by 100g of substance, shows unsaturation.

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Virgin Oil / Cold-Pressed Oil

Vegetable oils obtained by cold pressing.

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Rendering

Separating animal fats from tissues by heating.

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Glycerides

Fatty acid esters of glycerol.

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Acyl-CoA Formation

The first step in production of a mono-unsaturated acid.

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Drying Ability

Oils are classified based on this.

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Hydrogenation

Produce semisolid fats that are used extensively as cooking fats and shortenings.

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Sulfated/Sulfonated Oils

Reacting sulfuric acid with oil to add acid to double bond

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Fixed oils and fats

Has surfactant properties and finds industrial application.

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Castor Oil

Stimulant cathartic.

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Olive Oil

Used as a setting retardant for dental cements.

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Soybean Oil

Important food and forage crop, with lots of uses.

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Sesame Oil

Seed contains sesamol, giving excellent stability.

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Almond Oil

Obtained from varieties of prunus amygdalus.

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Coconut Oil

Used for high quality soaps and shampoos.

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Beeswax

Solid varying in color from yellow to grayish brown

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Prostaglandins

C20 lipid metabolites formed from essential acids.

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Prostaglandin F2α

Uterine stimulant for terminating 2nd-trimester pregnancy.

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Prostaglandin E2

Uterine stimulant differing from PGF2a by having keto group.

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Prostaglandin E1

Maintains patent ductus arteriosus.

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