Limiting Reactants and Stoichiometry

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Questions and Answers

What is the limiting reactant in a chemical reaction?

  • The reactant that runs out first. (correct)
  • The reactant that is in excess.
  • The product with the highest yield.
  • The catalyst that speeds up the reaction.

What are the products of the reaction between zinc and hydrochloric acid?

  • Hydrogen gas and zinc chloride (correct)
  • Zinc oxide and water
  • Water and zinc chloride
  • Chlorine gas and zinc hydroxide

Which ratio is used to identify the limiting reactant?

  • Quantity of product per coefficient in the balanced equation.
  • Quantity of reactant per product formed.
  • Quantity of reactant per total number of atoms in the reaction.
  • Quantity of reactant per coefficient in the balanced equation. (correct)

In the reaction Zn + 2HCl → H₂ + ZnCl₂, if you have 12 atoms of zinc and 8 molecules of HCl, which is the limiting reactant?

<p>Hydrochloric acid (C)</p> Signup and view all the answers

If you have 3 moles of zinc and 4 moles of HCl, which is the limiting reactant?

<p>Hydrochloric acid (D)</p> Signup and view all the answers

What is the first step in determining the limiting reactant when given the mass of reactants?

<p>Divide the mass by the molar mass to convert to moles. (C)</p> Signup and view all the answers

What is the molar mass of zinc (Zn)?

<p>65.39 g/mol (B)</p> Signup and view all the answers

What are the products of the reaction between ethane and oxygen gas?

<p>Carbon dioxide and water (C)</p> Signup and view all the answers

In the reaction 2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O, if you have 5 moles of ethane and 16 moles of oxygen gas, which is the limiting reactant?

<p>Oxygen gas (C)</p> Signup and view all the answers

What is the molar mass of oxygen gas (Oâ‚‚)?

<p>32 g/mol (B)</p> Signup and view all the answers

How do you convert moles of a reactant to moles of a product?

<p>Multiply by the ratio of coefficients from the balanced equation. (D)</p> Signup and view all the answers

What is the molar mass of ethane (C₂H₆)?

<p>30.068 g/mol (C)</p> Signup and view all the answers

What is the molar mass of water (Hâ‚‚O)?

<p>18.016 g/mol (B)</p> Signup and view all the answers

In the reaction 2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O, if you have 30 grams of ethane and 84 grams of oxygen gas, which reactant is the limiting reactant?

<p>Oxygen gas (D)</p> Signup and view all the answers

What is the theorerical yield?

<p>The maximum amount of product that can be formed in a reaction. (A)</p> Signup and view all the answers

What is the balanced chemical equation for the reaction between zinc and hydrochloric acid?

<p>Zn + 2HCl -&gt; Hâ‚‚ + ZnClâ‚‚ (B)</p> Signup and view all the answers

How do you convert grams of a substance to moles?

<p>Divide grams by molar mass (C)</p> Signup and view all the answers

In the reaction 2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O, what is the coefficient for oxygen gas?

<p>7 (C)</p> Signup and view all the answers

Which of the following does the limiting reactant determine?

<p>The theorerical yield of the product (B)</p> Signup and view all the answers

What is the balanced chemical equation for the reaction between ethane and oxygen gas?

<p>2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O (B)</p> Signup and view all the answers

How does the coefficient of a reactant in a balanced equation relate to determining the limiting reactant?

<p>You divide the number of moles by the coefficient. (A)</p> Signup and view all the answers

In the reaction Zn + 2HCl → H₂ + ZnCl₂, what is the coefficient of HCl?

<p>2 (C)</p> Signup and view all the answers

What is the definition of molar mass?

<p>The mass of one mole of a substance (C)</p> Signup and view all the answers

Which of the following steps is crucial in solving stoichiometry problems involving limiting reactants?

<p>Balancing the chemical equation (C)</p> Signup and view all the answers

What happens to the excess reactant in a chemical reaction?

<p>It remains after the reaction is complete (C)</p> Signup and view all the answers

Why is it important to identify the limiting reactant in a chemical reaction?

<p>To determine the amount of product that can be formed (C)</p> Signup and view all the answers

In the balanced equation 2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O, how many moles of water are produced for every 2 moles of ethane consumed?

<p>6 moles (A)</p> Signup and view all the answers

Which unit is used to express molar mass?

<p>Grams per mole (g/mol) (A)</p> Signup and view all the answers

What is the formula for calculating moles from grams?

<p>Moles = Grams / Molar Mass (B)</p> Signup and view all the answers

In the reaction Zn + 2HCl → H₂ + ZnCl₂, if you start with 65.39 grams of zinc and excess HCl, approximately how many moles of zinc chloride (ZnCl₂) can be produced?

<p>1 mole (C)</p> Signup and view all the answers

In the balanced equation 2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O, how many moles of oxygen are required to react completely with 2 moles of ethane?

<p>7 moles (C)</p> Signup and view all the answers

What term describes a reactant that is not completely used up in a chemical reaction?

<p>Excess reactant (C)</p> Signup and view all the answers

In stoichiometry, what does the term 'coefficient' refer to?

<p>The number of moles of a substance in a balanced equation (C)</p> Signup and view all the answers

For the reaction Zn + 2HCl → H₂ + ZnCl₂, if you have 2 moles of Zn, how many moles of HCl are needed for a complete reaction?

<p>4 moles (B)</p> Signup and view all the answers

In the reaction 2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O, if you have 14 moles of O₂, how many moles of CO₂ can be produced?

<p>8 moles (C)</p> Signup and view all the answers

What is the first step in determining the limiting reactant if you are given grams of each reactant?

<p>Convert grams to moles for each reactant (D)</p> Signup and view all the answers

In the reaction Zn + 2HCl → H₂ + ZnCl₂, what is the molar ratio of Zn to HCl?

<p>1:2 (C)</p> Signup and view all the answers

Which of the following is true regarding the limiting reactant?

<p>It is completely consumed in the reaction. (A)</p> Signup and view all the answers

How does the limiting reactant affect the amount of product formed?

<p>It determines the maximum amount of product that can be formed. (B)</p> Signup and view all the answers

Flashcards

Limiting Reactant

The reactant that is completely consumed in a chemical reaction, determining the maximum amount of product formed.

Reaction of Zinc and HCl

Zinc reacts with hydrochloric acid to produce hydrogen gas and zinc chloride.

Identifying the Limiting Reactant

Divide the quantity of each reactant by its coefficient in the balanced equation; the smallest result indicates the limiting reactant.

Reaction of Ethane and Oxygen

Ethane reacts with oxygen to produce carbon dioxide and water.

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Theoretical Yield

The maximum amount of product that can be formed in a reaction, determined by the limiting reactant.

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Excess Reactant

The reactant that remains after the limiting reactant is completely consumed.

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Limiting Reactant Calculation

Convert grams to moles using the molar mass, then divide by the stoichiometric coefficient.

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Mole Ratio Comparison

Compare the ratio of moles to coefficients for each reactant to identify which one is the limiting reactant.

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Gram to Gram Conversion

Convert the given mass of each reactant to grams of the same product, use molar mass and stoichiometry.

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Study Notes

Limiting Reactants Introduction

  • The discussion focuses on identifying limiting reactants and solving stoichiometry problems involving them.

Reaction of Zinc and Hydrochloric Acid

  • Zinc reacts with aqueous hydrochloric acid (HCl) to produce hydrogen gas (Hâ‚‚) and zinc chloride (ZnClâ‚‚).
  • The balanced chemical reaction is: Zn + 2HCl → Hâ‚‚ + ZnClâ‚‚

Identifying the Limiting Reactant

  • The limiting reactant is the one that runs out first in a reaction.
  • To identify it, find the lowest quantity per coefficient ratio.

Situation A: 12 Atoms of Zinc and 8 Molecules of HCl

  • Divide the quantity of each reactant by its coefficient in the balanced equation.
  • For zinc: 12 atoms / 1 (coefficient of Zn) = 12
  • For HCl: 8 molecules / 2 (coefficient of HCl) = 4
  • HCl has the lowest quantity per coefficient ratio, making it the limiting reactant.

Situation B: 3 Moles of Zinc and 4 Moles of HCl

  • Divide the number of moles of each reactant by its coefficient.
  • For zinc: 3 moles / 1 = 3
  • For HCl: 4 moles / 2 = 2
  • HCl has the lower ratio (2 < 3), thus HCl is the limiting reactant.
  • The ratio is 1:2, so 1 mol of zinc reacts with 2 mols of HCl
  • 2 mols of Zinc will react with 4 mols of HCl
  • We don't have 6 mols of HCl so we run out of HCl first

Situation C: 40 Grams of Zinc and 56 Grams of HCl

  • Convert grams to moles by dividing by the molar mass.
  • Molar mass of zinc (Zn) is 65.39 g/mol.
  • Molar mass of HCl is approximately 36.458 g/mol.
  • Moles of zinc = 40 g / 65.39 g/mol ≈ 0.6117 moles
  • Moles of HCl = 56 g / 36.458 g/mol ≈ 1.536 moles
  • Divide the moles by the coefficients:
  • For zinc: 0.6117 moles / 1 = 0.6117
  • For HCl: 1.536 moles / 2 = 0.768
  • Zinc has the lower ratio, so zinc is the limiting reactant

Reaction of Ethane and Oxygen Gas

  • Ethane (Câ‚‚H₆) reacts with oxygen gas (Oâ‚‚) to produce carbon dioxide (COâ‚‚) and water (Hâ‚‚O).
  • The balanced chemical equation is: 2Câ‚‚H₆ + 7Oâ‚‚ → 4COâ‚‚ + 6Hâ‚‚O

Part A: Limiting Reactant and Moles of CO2 Produced

  • Given 5 moles of ethane and 16 moles of oxygen gas.
  • Method 1: Find the limiting reactant by comparing the mole per coefficient ratio.
  • For ethane: 5 moles / 2 = 2.5
  • For Oâ‚‚: 16 moles / 7 ≈ 2.29
  • Oâ‚‚ has the lower ratio, so Oâ‚‚ is the limiting reactant.
  • Method 2: Convert the moles of each reactant to moles of product (COâ‚‚), with reactant producing less product = limiting reacant
  • Convert moles of ethane to moles of COâ‚‚: 5 moles Câ‚‚H₆ * (4 moles COâ‚‚ / 2 moles Câ‚‚H₆) = 10 moles COâ‚‚
  • Convert moles of Oâ‚‚ to moles of COâ‚‚: 16 moles Oâ‚‚ * (4 moles COâ‚‚ / 7 moles Oâ‚‚) ≈ 9.14 moles COâ‚‚
  • Oâ‚‚ produces less COâ‚‚, therefore theorerical yield of CO2 is 9.14 moles
  • The reactant that produces less product = limiting reactant
  • The reactant that produce smaller theorerical yield is the limiting reactant
  • The theoretical yield amount (9.14 moles) indicates that Oâ‚‚ is the limiting reactant.

Part B: Grams of Water Produced

  • Given 30 grams of ethane and 84 grams of oxygen gas.
  • Perform Gram to Gram conversion
  • Convert 30g of ethane into grams of water
  • Convert 84g of oxygen to grams of water
  • Whichever is lest, this is the correct value and limiting reactant

Gram to Gram Conversions

  • Molar mass of ethane (Câ‚‚H₆) = (2 * 12.01) + (6 * 1.008) ≈ 30.068 g/mol
  • Molar Mass of water is 18.016 g/mol
  • Conversion from ethane to water: 30 g Câ‚‚H₆ * (1 mol Câ‚‚H₆ / 30.068 g Câ‚‚H₆) * (6 mol Hâ‚‚O / 2 mol Câ‚‚H₆) * (18.016 g Hâ‚‚O / 1 mol Hâ‚‚O) ≈ 53.93 g Hâ‚‚O
  • Molar mass of oxygen (Oâ‚‚) = 32 g/mol
  • Conversion from oxygen to water: 84 g Oâ‚‚ * (1 mol Oâ‚‚ / 32 g Oâ‚‚) * (6 mol Hâ‚‚O / 7 mol Oâ‚‚) * (18.016 g Hâ‚‚O / 1 mol Hâ‚‚O) ≈ 40.54 g Hâ‚‚O
  • The amount of water produced is the smaller of the two (40.54 g).
  • Oxygen is the limiting reactant.
  • Ethane is the excess reactant because it results in higher amount, thus not limitting.

Key Concepts

  • Theoretical Yield: The maximum amount of product that can be formed in a reaction.
  • The limiting reactant determines the theorerical yield.

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