Life and Chemistry: Small Molecules

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Questions and Answers

What is the term for atoms of the same element that have different numbers of neutrons?

  • Isotopes (correct)
  • Atoms
  • Ions
  • Molecules

Which electron shell is closest to the nucleus and contains only one s orbital?

  • Second shell
  • First shell (correct)
  • Third shell
  • Fourth shell

How many electrons can occupy a single orbital?

  • Two (correct)
  • Three
  • Four
  • One

What happens when a radioactive isotope decays?

<p>It loses energy and may lose a proton (B)</p> Signup and view all the answers

What is the maximum number of electrons the second shell can accommodate?

<p>8 (D)</p> Signup and view all the answers

Which of the following best describes the role of a radioactive isotope in medical applications?

<p>It helps in diagnosing diseases (C)</p> Signup and view all the answers

Which of the following statements is true regarding atomic structure?

<p>Atoms of an element always have the same number of protons. (C)</p> Signup and view all the answers

What determines how an atom reacts with other atoms?

<p>The electrons found in the valence shell (B)</p> Signup and view all the answers

What is the maximum number of electrons that can be found in the second shell of an atom?

<p>8 electrons (B)</p> Signup and view all the answers

Which element has a valence of four?

<p>Carbon (B)</p> Signup and view all the answers

What is the term for the number of unpaired valence electrons in an atom?

<p>Valence (D)</p> Signup and view all the answers

Which of the following statements is true regarding the octet rule?

<p>Hydrogen is not considered under the octet rule. (B), Atoms with eight electrons in their outer shell are typically stable. (C)</p> Signup and view all the answers

What kind of bond involves the sharing of a pair of electrons between two atoms?

<p>Covalent bond (C)</p> Signup and view all the answers

How many orbitals are there in the second shell of an atom?

<p>Three (A)</p> Signup and view all the answers

Which of the following elements does NOT typically follow the octet rule?

<p>Boron (A)</p> Signup and view all the answers

What causes the repulsion between atomic nuclei?

<p>Mutually repelling positive charges (B)</p> Signup and view all the answers

Which type of covalent bond results in the sharing of three pairs of electrons?

<p>Triple covalent bond (A)</p> Signup and view all the answers

How is molecular weight defined?

<p>The sum of the masses of all the atoms in a molecule (B)</p> Signup and view all the answers

What is the molarity of a solution?

<p>Number of moles of solute per liter of solution (D)</p> Signup and view all the answers

What determines an atom's electronegativity?

<p>A combination of the number of protons and the atomic radius (B)</p> Signup and view all the answers

What type of bond results from unequal sharing of electrons?

<p>Polar covalent bond (A)</p> Signup and view all the answers

What charge develops around the more electronegative atom in a polar covalent bond?

<p>Partial negative charge (B)</p> Signup and view all the answers

Which molecule would most likely contain the largest number of polar covalent bonds?

<p>C2H4O2 (acetic acid) (B)</p> Signup and view all the answers

What type of bond involves a complete transfer of electrons between atoms?

<p>Ionic bond (C)</p> Signup and view all the answers

Which of the following is true about polar molecules?

<p>They tend to be hydrophilic. (A)</p> Signup and view all the answers

What are negatively charged ions called?

<p>Anions (A)</p> Signup and view all the answers

Which force is responsible for the attractions between nonpolar molecules?

<p>Van der Waals forces (C)</p> Signup and view all the answers

What happens to ionic bonds when salt is introduced into water?

<p>They are interfered with by water's partial charges. (C)</p> Signup and view all the answers

In a chemical reaction, what are the substances called that are converted to products?

<p>Reactants (A)</p> Signup and view all the answers

What type of bond do not share electrons?

<p>Hydrogen bonds (C)</p> Signup and view all the answers

What is the primary characteristic of hydrophobic molecules?

<p>They do not dissolve in water. (A)</p> Signup and view all the answers

What must occur in a chemical equation to comply with the law of conservation of mass?

<p>The equation must balance the number of atoms on both sides. (B)</p> Signup and view all the answers

Which statement correctly defines a calorie?

<p>The amount of heat needed to raise the temperature of one gram of water from 14.5°C to 15.5°C. (D)</p> Signup and view all the answers

What characterizes a 1 molar (1 M) solution of NaCl?

<p>It is created by dissolving 58.5 grams of NaCl in one liter of water. (A)</p> Signup and view all the answers

Which of the following describes how water behaves when it freezes?

<p>Water expands upon freezing and ice is less dense than liquid water. (D)</p> Signup and view all the answers

How does the mole concept aid in quantitative analysis?

<p>It defines the amount of substance as grams equal to its molecular weight. (D)</p> Signup and view all the answers

What role does water play in living organisms?

<p>It serves as a solvent for many biochemical reactions. (B)</p> Signup and view all the answers

What property of water is primarily responsible for its ability to form hydrogen bonds?

<p>The bent shape and polarity of water molecules. (B)</p> Signup and view all the answers

Why do chemical bonds store potential energy?

<p>They create a stable and low-energy arrangement of atoms. (B)</p> Signup and view all the answers

What is the primary reason ice floats in liquid water?

<p>Ice is less dense than liquid water. (D)</p> Signup and view all the answers

What does specific heat indicate in the context of liquid water?

<p>The amount of heat required to raise the temperature of 1 gram by 1°C. (C)</p> Signup and view all the answers

What property of water contributes to its high surface tension?

<p>Cohesion due to hydrogen bonds. (C)</p> Signup and view all the answers

Which of the following statements is true regarding the specific heat of water?

<p>It is approximately 4 Joules per gram per degree Celsius. (B), It is crucial for moderating climate temperatures. (D)</p> Signup and view all the answers

How does water's cohesive strength affect its movement in trees?

<p>It enables water transport from roots to leaves. (A)</p> Signup and view all the answers

What happens to water when it freezes?

<p>It loses energy and expands. (B)</p> Signup and view all the answers

What defines an acid in terms of its behavior in water?

<p>It donates hydrogen ions. (C)</p> Signup and view all the answers

What is the relationship between the polarity of a substance and the energy required to change its temperature?

<p>Higher polarity requires more energy to change temperature. (C)</p> Signup and view all the answers

Flashcards

Atomic Number

The number of protons in an atom's nucleus, unique to each element.

Isotopes

Atoms of the same element with different numbers of neutrons.

Radioactive Isotopes

Unstable atomic nuclei that decay, releasing energy and particles.

Electron Orbital

The region around the nucleus where an electron is likely to be found.

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Electron Shells (Energy Levels)

Ordered areas around the nucleus, where electrons orbit.

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s Orbital

The first orbital in an electron shell, filling first.

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p Orbital

Orbital in electron shells beyond the first.

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Atomic nuclei

The central core of an atom containing protons and neutrons.

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Valence Shell

The outermost electron shell of an atom, determining how it reacts with other atoms.

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Valence Electrons

Electrons in the valence shell, influencing an atom's reactivity.

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Octet Rule

The tendency of atoms to have eight electrons in their outermost shell to become stable.

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Chemical Bond

An attraction force linking two or more atoms together.

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Covalent Bond

A chemical bond formed by sharing electron pairs between atoms.

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Molecule

Two or more atoms bonded together.

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Electron Shell

An energy level around the nucleus where electrons are found.

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Valence

The number of unpaired valence electrons in an atom.

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Covalent Bond Strength

Covalent bonds are very strong chemical bonds that hold atoms together by sharing electrons.

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Polar Covalent Bond

A covalent bond where electrons are unequally shared, creating partial positive and partial negative charges on atoms.

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Electronegativity

An atom's ability to attract electrons in a chemical bond.

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Molecular Weight

The sum of the masses of all atoms in a molecule.

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Mole

A unit of measurement representing 6.022 x 10^23 molecules or entities.

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Molarity

Concentration of a substance in a solution, measured as moles per liter.

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Double Covalent Bond

Atoms sharing two pairs of electrons.

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Polar Molecules

Molecules with polar covalent bonds; possessing unevenly distributed charges.

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Hydrogen Bonds

Weak attractions between molecules with polar covalent bonds. The positive part of one molecule is attracted to the negative part of another.

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Ionic Bonds

Bonds formed by the transfer of electrons, creating charged ions (cations and anions) that attract each other.

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Polar Molecules

Molecules with uneven distribution of charges, creating slightly positive and negative poles.

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Nonpolar Molecules

Molecules with an even distribution of charge, no separation of poles; don't dissolve well in water.

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Hydrophilic

Molecules attracted to water; polar molecules typically.

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Hydrophobic

Molecules repelled by water; nonpolar molecules typically.

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Chemical Reaction

Process where atoms rearrange, forming new bonds and breaking old ones.

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Reactants / Products

Reactants are substances initially present and changed into products, substances created during a reaction.

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Chemical Equation Balance

Chemical equations must balance because matter is neither created nor destroyed in a chemical reaction.

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Chemical Reaction Energy

Chemical reactions often involve changes in energy, usually related to potential energy stored in chemical bonds.

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Potential Energy

Stored energy, like that in chemical bonds, is called potential energy and can be measured using units of heat.

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Calorie Definition

A calorie is the amount of heat energy to raise one gram of pure water by 1°C.

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Water as Solvent

Water is the solvent in living organisms where many reactions take place.

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Mole Concept

A mole is a quantity of a substance equal to its molecular weight in grams and contains approximately 6.022 x 10^23 molecules.

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1 Molar Solution

A 1 molar solution contains one mole of a compound dissolved in one liter of water.

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Water's Unusual Properties

Water's bent shape, polarity, and ability to bond unusually affect its properties, like ice being less dense than liquid water.

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Ice floats

Ice is less dense than liquid water, causing it to float on top.

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Water's high specific heat

A large amount of heat is needed to change water's temperature.

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Hydrogen bonds and water

Hydrogen bonds between water molecules influence its properties.

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Cohesion in water

Water molecules stick together due to hydrogen bonds.

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Adhesion

Water molecules stick to other substances.

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High surface tension

The surface of water is resistant to external forces due to water's cohesion.

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Acids

Substances that release Hydrogen ions (H+) when dissolved in water.

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Bases

Substances that release hydroxide ions (OH-) when dissolved in water.

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Study Notes

Life and Chemistry: Small Molecules

  • Atoms are the fundamental building blocks of matter.
  • Chemical bonds connect atoms together, forming molecules.
  • Chemical reactions involve atoms changing partners.
  • Water has unique properties crucial for life.
  • Acids, bases, and the pH scale describe how acidic or basic a substance is.
  • Properties of molecules are influenced by their composition, structure, reactivity, and solubility. Functional groups and isomerism are important concepts.

Objectives (ILOs)

  • Students should be familiar with chemical terminology.
  • Understand the basics of atoms and their properties including energy levels and orbitals.
  • Develop a strong understanding of various chemical bonds (between atoms and molecules)
  • Understand the properties of water
  • Know the concept of kinetic energy and heat.
  • Ability to calculate the pH of a substance.
  • Understand the concept of isomers and apply it in context
  • Students should understand various functional groups' importance.
  • Understand the function of carbon atoms

Atoms: The Constituents of Matter

  • Matter consists of atoms.
  • Atomic structure dictates element behavior.
  • Atoms are comprised of protons, neutrons, and electrons.
  • Elements have unique atomic numbers (protons).
  • Mass numbers are the sum of protons and neutrons.
  • Atomic weight is the average mass of naturally occurring isotopes.
  • Each element has a unique symbol and is organized in a table (periodic table)
  • Electron shells or energy levels surround the nucleus.
  • Each shell has a limited number of electrons.
  • valence shell is the outermost shell and determines reactivity.
  • Valence electrons participate in bonding

Atoms: The Octet Rule

  • Atoms are typically stable when their outer shell has eight electrons (octet rule)
  • Atoms without a full octet will gain, lose, or share electrons to achieve stability.

Chemical Bonds: Linking Atoms Together

  • Molecules form when atoms bond.
  • Covalent bonds form by sharing pairs of electrons.
  • In covalent bonds atoms with different electronegativities form polar covalent bonds.
  • Hydrogen bonds form weak attractions between slightly charged portions of polar molecules.
  • Ionic bonds form by complete transfer of electrons.

Quantifying Molecules

  • Molecular weight is the sum of the atomic weights of atoms in a molecule
  • One mole equals 6.022 × 10²³ molecules
  • Molarity (M) measures concentration as the number of moles per liter

Water: Structure and Properties

  • Water is essential for life.
  • Water is a polar molecule because of unequal electron sharing.
  • Exceptional Properties:
    • High Specific heat (ability to absorb or release heat)
    • High Heat of vaporization (energy to convert water to gas).
    • Cohesion and adhesion of water molecules (important in transport).
    • Ice's density is less than liquid water.
    • Water is an excellent solvent for other polar or ionic substances.

Acids, Bases, and the pH Scale

  • Acids release H+ and bases release OH-
  • pH scale measures acidity.
  • Buffer solutions resist pH changes.

Properties of Molecules

  • Molecules are classified based on their structure, composition, reactivity, and solubility.
  • Functional groups are components responsible for the unique properties of molecules
  • Isomers exhibit same chemical formula but different atomic arrangements.

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