Lec 5 & 6: General Chemistry - Carbohydrates
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Questions and Answers

Carbohydrates are a type of biomolecule that contains a number of hydroxyl groups or their derivatives.

True

Polysaccharides are classified as a type of monosaccharide.

False

The general structure of monosaccharides is ramified.

False

The names of all sugars end in –ose.

<p>True</p> Signup and view all the answers

Carbohydrates serve as energy stores and metabolic intermediates.

<p>True</p> Signup and view all the answers

Oligosaccharides contain 3-9 carbon atoms.

<p>False</p> Signup and view all the answers

The prefix D designates the absolute configuration of the asymmetric carbon closest to the aldehyde or ketone group.

<p>False</p> Signup and view all the answers

Glyceraldehyde has two asymmetric carbons.

<p>False</p> Signup and view all the answers

Disaccharides are polymers consisting of chains of monosaccharide units.

<p>False</p> Signup and view all the answers

The predominant forms of ribose, glucose, fructose, and many other sugars in solution are open chains.

<p>False</p> Signup and view all the answers

Study Notes

Carbohydrates

  • Carbohydrates are a group of compounds containing hydroxyl groups or their derivatives, poorly soluble in organic solvents but soluble in water.
  • They have several important functions for the organism, including serving as energy stores and metabolic intermediates.

Functions of Carbohydrates

  • Ribose and deoxyribose sugars form part of the structural framework of RNA and DNA.
  • Carbohydrates are important for tissue formation.
  • They form the basis of human blood groups.
  • Polysaccharides are structural elements in the cell walls of bacteria and plants.
  • Carbohydrates link to many proteins and lipids, mediating interactions among cells and between cells and other elements.

Classification of Carbohydrates

  • Monosaccharides: contain 3-9 carbon atoms, mostly 5 or 6, with an aldehyde or ketone group.
  • Disaccharides: condensation products of two monosaccharide units, e.g., maltose and sucrose.
  • Oligosaccharides: a few monosaccharides (3-10) covalently linked by glycosidic bonds.
  • Polysaccharides: polymers consisting of chains of monosaccharide or disaccharide units, e.g., starches and dextrins.

Monosaccharides

  • General structure is straight and not ramified.
  • Every carbon atom carries a hydroxyl group except one.
  • Contain an aldehyde or ketone group.

Nomenclature of Sugars

  • Names end in –ose.
  • Aldoses have an aldehyde group, while ketoses have a ketone group.
  • Number of carbon atoms present in the molecule determines the prefix (e.g., triose, tetrose, pentose, hexose, heptose).

D and L Isomerism

  • Isomers are molecules with the same kinds and numbers of atoms joined up in different ways.
  • Prefixes D and L designate the absolute configuration of the asymmetric carbon farthest from the aldehyde or ketone group.
  • D-isomer has the OH group on the right, while L-isomer has it on the left.

Cyclization of Monosaccharide

  • The predominant forms of ribose, glucose, fructose, and many other sugars in solution are not open chains.

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Description

This quiz covers the basics of carbohydrates, including their composition, properties, and classification as one of the four major classes of biomolecules.

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